学科分类
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44 个结果
  • 简介:ThisstudypresentsanovelprocessofinsitusurfacemodificationofCaCChnanoparticlesusingamultipleorificedispersionmicroreactor.CO2/Ca(OH)2precipitationreactionwasemployedtoprepareCaCO3nanoparticleswithsodiumstearatesurfactant.SynthesizedCaCChproductswerecharacterizedbythermogravimetricanalysis(TGA),infra-red(IR),X-raydiffraction(XRD),transmissionelectronmicroscopy(TEM)andBrunauer-Emmet-Telleranalysis(BET).Theeffectofvariousoperationparametersonnanoparticlesandthedosageofsodiumstearateweredetermined.Theresultsshowedthatthepreparationprocesscouldbepreciselycontrolledwithefficientmasstransferprocess.Theparticleswerehighlyhydrophobicwithacontactangleof117andmonodispersewithanaveragesizeof30nm.Theadsorptionsofsodiumstearateandcalciumiononsolidparticlesduringtheinsitusurfacemodificationprocesswereinvestigated.

  • 标签: 纳米碳酸钙 原位制备 分散过程 疏水性 CA(OH)2 透射电子显微镜
  • 简介:Globallook-uptablestrategyproposedrecentlyhasbeenproventobeanefficientmethodtoacceleratetheinterpolation,whichisthemosttime-consumingpartintheiterativesub-pixeldigitalimagecorrelation(DIC)algorithms.Inthispaper,agloballook-uptablestrategywithcubicB-splineinterpolationisdevelopedfortheDICmethodbasedontheinversecompositionalGauss–Newton(IC-GN)algorithm.Theperformanceofthisstrategy,includingaccuracy,precision,andcomputationefficiency,isevaluatedthroughatheoreticalandexperimentalstudy,usingtheonewithwidelyemployedbicubicinterpolationasabenchmark.Thegloballook-uptablestrategywithcubicB-splineinterpolationimprovessignificantlytheaccuracyoftheIC-GNalgorithm-basedDICmethodcomparedwiththeoneusingthebicubicinterpolation,atatrivialpriceofcomputationefficiency.

  • 标签:
  • 简介:AnovelmethodformodelingcellularmaterialsisproposedbasedonMATLABimageprocessingandsynchrotronX-raycomputedtomographyscanningtoobtainanaccuratecalculationresultofaluminumfoambasedonfiniteelementmodel.Themaximumentropyalgorithmisemployedtoobtainthebinarizationimage,andthemedianfilteringalgorithmisusedtoreducethenoiseafterbinarization.Theexternalcontourandinternalporesboundaryisextractedbythe"edge"functioninMATLAB,andthegeometricalmodelisreconstructed.Atwo-stepmeshalgorithmisadoptedtomeshthereconstructedgeometricalmodel.Accordingly,thefiniteelementmodelofaluminumfoamisestablishedbytheproposedmethodbasedonreconstructiongeometricalmodel.Thecompressionbehaviorofaluminumfoamisobtainedat25℃,100℃,200℃byABAQUS,andgoodagreementswithexperimentsareachievedbyapplyingthepresentreconstructionalgorithmandmodelingmethod.

  • 标签: 泡沫铝 有限元建模 材料响应 重建方法 三维几何 MATLAB
  • 简介:3-degree-of-freedom(3-DOF)的一个新分析模型旋转罗盘加速表系统由一个1-DOF驱动器和2-DOF感觉模式组成被介绍。模型构造微分方程由向量分析与系统的每DOF联系了的lumped。因此建立的联合微分方程是为他们在时间和频率领域的回答的解决的经分解。就这些频率反应方程而言,新奇设备设计概念被强迫感觉阶段到零导出,它导致在结构的频率之间的某个关系,从而在系统的表演上引起抑制效果的最小化。而且,现在的旋转罗盘加速表结构的可行性在他们的事件为旋转罗盘行动和线性加速的察觉用一个唯一的差别对待的计划被学习。这个计划把旋转罗盘加速表的提出的解决的短暂解决方案与同步解调和过滤的进程相结合,它导致同相并且系统输出的照部件发信号。这二个部件能在尖运动和线性加速的察觉被利用。获得的分析结果被模拟在MATLAB/Simulink环境验证,并且结果在对对方的优秀同意,这被发现。

  • 标签: 陀螺加速度计 三自由度 解析模型 行为模拟 MEMS 集总参数
  • 简介:有drag系数修正的Eulerian小粒的多相的模型基于精力最小化多尺度(扩展内存管理程序)模型被用来规模传播模仿半工业使流体化的床(CFB)。三维(3D),完整环的CFB的时间依赖者模拟表明跨sectionally的轴的侧面平均稳固的体积部分,和稳固的轴的速度的光线的侧面,稳固的体积部分在对试验性的数据的合理同意。基于这个协议,从还没完成的实验导出的数据库在CFB循环附近与如此的模拟,和液体政体图和压力平衡被填满因此被导出。这个工作在CFB上介绍一个综合观点并且为CFB建模展开一个新鲜范例,它能被期望帮助解决在争论长却为实验难的某些期。

  • 标签: 多相流 三维空间 方法 仿真
  • 简介:Intheunderwater-shockenvironment,cavitationoccursnearthestructuralsurface.Thedynamicresponseoffluid-structureinteractionsisinfluencedseriouslybythecavitationeffects.Itisalsothedifficultyinthefieldofunderwaterexplosion.Withthetraditionalboundaryelementmethodandthefiniteelementmethod(FEM),itisdifficulttosolvethenonlinearproblemwithcavitationeffectssubjectedtotheunderwaterexplosion.Tosolvethisproblem,undertheconsiderationofthecavitationeffectsandfluidcompressibility,withfluidvisciditybeingneglected,a3Dnumericalmodeloftransientnonlinearfluid-structureinteractionsubjectedtotheunderwaterexplosionisbuilt.Thefluidspectralelementmethod(SEM)andtheFEMareadoptedtosolvethismodel.AftercomparisonwiththeFEM,itisshownthattheSEMismoreprecisethantheFEM,andtheSEMresultsareingoodcoincidencewithbenchmarkresultsandexperimentresults.Basedonthis,combinedwithABAQUS,thetransientfluid-structureinteractionmechanismofthe3Dsubmergedsphericalshellandshipstiffenedplatessubjectedtotheunderwaterexplosionisdiscussed,andthecavitationregionanditsinfluenceonthestructuraldynamicresponsesarepresented.Thepaperaimsatprovidingreferencesforrelevantresearchontransientfluid-structureinteractionofshipstructuressubjectedtotheunderwaterexplosion.

  • 标签: 结构相互作用 三维数值模型 水下爆炸 拟流体 气蚀 有限元法
  • 简介:Thebubblesriseupandburstatthefreesurfaceisacomplextwo-phaseprocess.AfreeenergylatticeBoltzmannmethod(LBM)modelisadoptedinthispapertostudythisphenomenon.Theinterfacecapturingtechnique[Zhengetal.,2006]isusedtodealwiththehighdensityratioproblem.TheLaplacelawandtheair-waterinterfacecapturingabilityarevalidatedforthemultiphasemodel.Theinteractionbetweenthesinglebubbleormultiplebubblesandthefreesurfacearestudiedbythemultiphasemodel.Theforceactingonthebubbleandtheevolutionofthefreesurfaceisstudied.Meanwhile,effectoftheinitialdistancebetweentwoadjacentbubblesoninteractioneffectsofmultiplebubblesisinvestigatedaswell.

  • 标签: LATTICE BOLTZMANN method Free energy model
  • 简介:有从30~80nm的尺寸的Fe3O4nanoparticles被湿milling铁粉末在一家行星的球工厂综合。阶段作文和同样综合的产品的形态学被X光检查衍射(XRD)测量,扫描电子显微镜学(SEM)和传播电子显微镜学(TEM)。NanosizedFe3O4粒子被湿milling准备金属性的铁粉末(?200网孔,99%)在与不锈钢装备的一家行星的球工厂,使用的小瓶与50:1并且以300rpm的旋转速度的ball-to-powder团比率在提取的水下面熨球。在这个方法的铁球的使用在Fe3O4formation起了一个关键作用。现在的技术简单,这个过程是容易的执行。

  • 标签: 行星球磨机 湿磨法 四氧化三铁 钠米颗粒
  • 简介:Inthisstudy,factorsaffectingthecrystalstructureofflame-synthesizedY2O3:Euparticleswereinves-tigated,especiallytheparticlesizeeffectanditsinteractionwithEudopingconcentration.PolydisperseY2O3:Eu(sizerange200nmto3m)powdersampleswithEudopingconcentrationsfrom2.5mol%to25mol%weregeneratedineitherH2/airorH2/O2substrate-freeflames.ThecrystalstructureofthepowdersampleswasdeterminedbypowderX-raydiffraction(XRD),whichwascomplementedbypho-toluminescence(PL)measurements.Singleparticlecrystalstructurewasdeterminedbysingleparticleselectedareaelectrondiffraction(SAED),andforthefirsttime,byelectronbackscatterdiffraction(EBSD).H2/airflamesresultedincubicphaseY2O3:Euparticleswithhollowmorphologyandirregularshapes.ParticlesfromH2/O2flameshaddenseandsphericalmorphology;sampleswithlowerEudopingconcen-trationshadmixedcubic/monoclinicphases;sampleswiththehighestEudopingconcentrationswerephase-puremonoclinic.ForsamplesgeneratedfromH2/O2flames,aparticlesizeeffectanditsinteractionwithEudopingconcentrationwerefound:particlessmallerthanacriticaldiameterhadthemonoclinicphase,andthiscriticaldiameterincreasedwithincreasingEudopingconcentration.Thesefindingssug-gestthattheformationofmonoclinicY2O3:Euisinevitablewhenextremelyhotsubstrate-freeflamesareused,becausetypicalflame-synthesizedY2O3:Euparticlesizesarewellbelowthecriticaldiameter.However,itmaybepossibletogenerateparticleswithdense,sphericalmorphologyandthedesiredcubicstructurebyusingamoderatelyhighflametemperaturethatenablesfastsinteringwithoutmeltingtheparticles.

  • 标签: Y2O3:Eu 无火焰 单粒子 颗粒尺寸效应 晶体结构测定 电子背散射衍射
  • 简介:Anewanalyticalmodelwasdevelopedtopredictthegravitywavedrag(GWD)inducedbyanisolated3-dimensionalmountain,overwhichastratified,non-rotatingnon-Boussinesqshearedflowisimpinged.Themodelisconfinedtosmallamplitudemotionandassumestheambientvelocityvaryingslowlywithheight.ThemodifiedTaylor-GoldsteinequationwithvariablecoefficientsissolvedwithaWentzel-Kramers-Brillouin(WKB)approximation,formallyvalidathighRichardsonnumbers.WiththisWKBsolution,genericformulaeofsecondorderaccuracy,fortheGWDandsurfacepressureperturbation(bothforhydrostaticandnon-hydrostaticflow)arepresented,enablingarigoroustreatmentontheeffectsbyverticalvariationsinwindprofiles.Inanidealtesttothecircularbell-shapedmountain,itwasfoundthatwhenthewindislinearlysheared,thattheGWDdecreasesastheRichardsonnumberdecreases.However,theGWDforaforwardshearedwind(windincreaseswithheight)decreasesalwaysfasterthanthatforthebackwardshearedwind(winddeceaseswithheight).Thisdifferenceisevidentwheneverthemodelishydrostaticornot.

  • 标签: 三维非Boussinesq剪切流 重力波阻 风廓线 垂直变异 分析模型 圆钟形山体
  • 简介:Inthepresentpaper,amultifluidmodeloftwo-phaseflowswithpulverized-coalcombustion,basedonacontinuum-trajectorymodelwithreactingparticlephase,isdevelopedandemployedtosimulatethe3-Dturbulenttwo-phaseflowsandcombustioninanewtypeofpulverized-coalcombustorwithoneprimary-airjetplacedalongthewallofthecombustor.Theresultsshowthat:(1)thiscontinuum-trajectorymodelwithreactingparticlephasecanbeusedinpracticalengineeringtoqualitativelypredicttheflamestability,concentrationsofgasspecies,possibilitiesofslagformationandsootdeposition,etc.;(2)largerecirculationzonescanbecreatedinthecombustor,whichisfavorabletotheignitionandflamestabilization.

  • 标签: NUMERICAL simulation pulverized-coal COMBUSTOR TWO-PHASE flow
  • 简介:这研究向动人的表面为三维的麦克斯韦液体集中于热和集体流动的Cattaneo-Christov理论。有可变热电导率的不可压缩的laminar流动被考虑。流动产生由于表的双向拉长。热和集体运输的联合现象被说明。热和集体散开的Cattaneo-Christov模型被用来开发精力和集体种类的表情。在集体种类方程的一阶的化学反应术语被考虑。边界层假设导致管理数学模型。homotopic模拟被采用设想无尺寸的流动方程的结果。速度,温度,和集中的图显示出不同产生参数的效果。一个数字基准被介绍设想计算结果的会聚的价值。结果证明集中和温度地为热和集体散开的Cattaneo-Christov理论被腐烂。

  • 标签: 数学模型 化学反应 热通量 三维 液体 水动力
  • 简介:Perovskite-typeLa1-xCexMnO3(x=0-10%)catalystswerepreparedbyflamespraypyrolysisandtheiractivitiesduringthecatalyticoxidationofbenzenewereexaminedoverthetemperaturerangeof100-450℃.ThestructuralpropertiesandreducibilityofthesematerialswerealsocharacterizedbyX-raydiffraction(XRD),N2adsorption/desorption,H2temperature-programmedreduction(H2-TPR)andX-rayphotoelectronspectroscopy(XPS).TheincorporationofCewasfoundtoimprovethebenzeneoxidationactivity,andtheperovskiteinwhichxwas0.1exhibitedthehighestactivity.Phasecompositionandsurfaceelementalanalysesindicatedthatnon-stoichiometriccompoundswerepresent.TheincorporationofCehadanegligibleeffectonthespecificsurfaceareaoftheperovskitesandhencethisfactorhaslittleimpactonthecatalyticactivity.IntroductionofCe44+resultedinmodificationofthechemicalstatesofbothB-siteionsandoxygenspeciesandfacilitatedthereducibilityoftheperovskite.ThesurfaceMn4+/Mn3+ratiowasincreasedasaresultofCe4+substitution,whileadecreaseinthesurface-adsorbedO/latticeO(Oads/Olatt)ratiowasobserved.Therelationshipbetweenthesurfaceelementalratiosandcatalyticactivitywasestablishedtoallowabetterunderstandingoftheprocessbywhichbenzeneisoxidizedoverperovskites.

  • 标签: 钙钛矿型 氧化铈 催化剂 掺入 火焰 X射线光电子能谱
  • 简介:Nanostructuredtransitionmetaloxidesarepromisingalternativeanodesforlithiumionbatteries.Li-ionstorageperformanceisexpectedtoimproveifhighpackingdensityenergyparticlesareavailable.Herein,Mn2O3microsphereswithaca.18μmdiameterandatappeddensityof1.33g/cm3weresynthesizedbyafacilesolvothermal-thermalcoversionroute.SphericalMnCO3precursorswereobtainedthroughsolvothermaltreatmentandtheydecomposedandconvertedintoMn2O3microspheresatanannealingtemperatureof700C.TheMn2O3microspheresconsistedofMn2O3nanoparticleswithanaverage40nmdiameter.TheseporousMn2O3microspheresallowgoodelectrolytepenetrationandprovideanionbufferreservoirtoensureaconstantelectrolytesupply.TheMn2O3microsphereshavereversiblecapacitiesof590and320mAh/gat50and400mA/g,respectively.Wethusreportanefficientrouteforthefabricationofenergyparticlesforadvancedenergystorage.

  • 标签: MN2O3 锂离子电池 溶剂热合成 负极材料 微球 过渡金属氧化物
  • 简介:Anewefficientmeshlessmethodbasedontheelement-freeGalerkinmethodisproposedtoanalyzethestaticdeformationofthinandthickplatestructuresinthispaper.Usingthenew3Dshell-likekinematicsinanalogytothesolid-shellconceptofthefiniteelementmethod,discretizationiscarriedoutbythenodeslocatedontheupperandlowersurfacesofthestructures.Theapproximationofallunknownfieldvariablesiscarriedoutbyusingthemovingleastsquares(MLS)approximationschemeinthein-planedirections,whilethelinearinterpolationisappliedthroughthethicknessdirection.Thus,differentboundaryconditionsaredefinedonlyusingdisplacementsandpenaltymethodisusedtoenforcetheessentialboundaryconditions.TheconstrainedGalerkinweakform,whichincorporatesonlydisplacementdegreesoffreedom(d.o.f.s),isderived.Amodified3Dconstitutiverelationshipisadoptedinordertoavoidoreliminatesomeself-lockingeffects.Thenumericefficiencyoftheproposedmeshlessformulationisillustratedbythenumericexamples.

  • 标签: 无网格伽辽金法 三维本构关系 厚板结构 移动最小二乘 边界条件 无网格方法
  • 简介:通过分析1维和2维线性插值可以推导出任意斜角直线坐标系下n维线性插值的一般计算公式以及有唯一解的条件,这一结论能够应用于三维温度场计算。可以将n维插值问题归结如下:已知n+1维空间中的n+1个点的坐标以及第n+2个点的n个坐标分量xn+2,1,xn+2,2,,xn+2,n,求解该点的第n+1个坐标分量xn+2,n+1。根据线性插值定义,第n+2个点位于前n+1个点所确定的n维超平面上。根据这一条件列写方程、求解方程可得到插值xn+2,n+1。n维插值问题有唯一解的条件是已知的n+1个点在n维空间中构成的多面体的体积不为0。推导过程在斜角直线坐标系中完成,因而结论具有较大普适性。

  • 标签: 线性插值 空间 高维 斜角直线坐标 温度场