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400 个结果
  • 简介:ReactionsofCuSCNwithtetramethylthiuramdisulfideinCH3CNinthepresenceofstyreneandN,N,N',N',N'-pentamethyldiethylenetriaminegaverisetoanewcopper(Ⅰ)complexofN,N'-dimethyldithio-cabamate{[Cu(S2CNMe2)]2}n.ThetitlecompoundcrystallizedinthetriclinicP-1spacegroupwithlatticeparametersα=0.7610(4)nm,b=0.8911(4)nm,c=0.9268(5)nm,α=68.66(1)°,β=83.88(2)°,γ=79.31(2)°,V=0.5748(5)nm^3,Z=2.Thecompoundhasaunique1DchainstructurecomposedofCuSCSCuSCSeight-memberedringsandapairofCu-Sbonds,thestructureofwhichhasbeendeterminedbysingle-crystalX-raycrystallography.Theisolationofthiscompoundmayprovidesomehelpfulinformationforthecauseoftheinductionperiodsofthereverseatomtransferradicalpolymerization.

  • 标签: 合成 晶体结构 N N'-二甲基二硫代铜 反向原子转移聚合 硫氰酸铜
  • 简介:通过比较两个图的色多项式的系数(本文使用了五独立集数)、顶点集、边集、三角形和四圈的个数,证明了K(2,2.6)是色唯一图.从而部分地回答了文[5],[7]中遗留的一个问题,并得到图K(nnn+4)(n=2或n≥4)是色唯一的.

  • 标签: 完全三部图 色多项式 色唯一性 独立集数
  • 简介:Inthispaper,wegivesomedecompositionsoftriplesofZpnorZ3pnintocyclictriplesystems.Newconstructionsofdiferencefamiliesaregiven.Someinfniteclassesofsimplecyclictriplesystemsareobtainedfromthesedecompositions.

  • 标签: 循环设计 n次方 分解 三元系 新建筑 无限类
  • 简介:ThepropertiesofPbn(n=2―30)clustersincludingbindingenergies,seconddifferencesinenergy,andHOMO-LUMOgaps,especiallyfragmentationenergiesandionizationpotentials,havebeenstudiedbyabinitiocalculation.ThemainfragmentationproductsofPbn+areshowntobePb+Pbn-1+forn≤14andtwosmallclusterfragmentsforlargeroneswithn>14.ThePb13+appearsfrequentlyastheproductsinthefragmentationsoflargeclusters.Also,thecalculatedionizationpotentialsoftheclustersareconsistentwiththeexperimentdata.

  • 标签: 电离势 碎裂 集群计算 HOMO LUMO 从头计算
  • 简介:Aseriesofaromaticimineswerereducedtocorrespondingaminesinexcellentyieldsby2-phenyl-N,N-dimethylbenzimidazoline(PDMBI)photochemicallyinthepresenceofmagnesiumperchloride(Mg(ClO4)2).AMg2+mediatedphotoinducedelectrontransfermechanismwasproposed.

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  • 简介:Thetwocompounds,2,2-dimethyl-4-S-(N,N-dimethyldithiocarbamato)-5-(1,2,4-triazol-l-yl)-propione(1)and2,2-dimethyl-4-S-(N,N-diethyldithiocarbamato)-5-(1,2,4-triazol-1-yl)-3-propione(2),werepreparedbyreactingN,N-dialkyldithiocarbamatesodiumwith2,2-dimethyl-4-bromo-5-(1,2,4-triazol-1-yl)-propione.Theirstructureswereidentifiedbyelementalanalysis,IRand^1HNMRspectroscopy.Thestructureof1hasbeendeterminedbyX-raysinglecrystalstructureanalysis.ItcrystallizesinmonoclinicsystemwithspacegroupP21/c,a=1.2315(3)nm,b=1.2057(2)nm,c=1.2532(3)nm,β=118.55(3)°,Z=4,V=1.6345(6)nm^3,Dc=1.221g/cm^3,μ=0.324mm^-1,F(000)=640,finalR1=0.0449.ThereisobviouspotentiallyweakC—H...Nintermolecularinteractioninthecrystal,whichstabilizesthecrystalstructure.Theresultofthebiologicaltestshowedthatthetwocompoundshavefungistasisandplantgrowthregulatingactivities.

  • 标签: 合成 晶体结构 生物活性 三唑化合物 N N-烷基二硫代氨基甲酸酯 杀菌剂
  • 简介:<正>WeintroducecertainCalderón-Zygmund-typeoperatorsanddiscusstheirboundednessonspacessuchasweightedLebesguespaces,weightedweakLebesguespaces,weightedHardyspacesandweightedweakHardyspaces.Thesharpnessofsomeresultsisalsoinvestigated.

  • 标签: Calderón-Zygmund operator LEBESGUE SPACE WEAK LEBESGUE
  • 简介:Anenvironmentallyfriendlyprecursor,adenosine,hasbeenusedasadualsourceofCandNtosynthesizenitrogen-dopedcarboncatalystwith/withoutFe.Ahydrothermalcarbonizationmethodhasbeenusedandwateristhecarbonizationmedia.Themorphologyofsampleswith/withoutFecomponenthasbeencomparedbyHRTEM,andtheresultshowsthatFecanpromotethegraphitizationofcarbon.Furtherelectro-chemicaltestshowsthattheoxygenreductionreaction(ORR)catalyticactivityofFe-containingsample(C–FeN)ismuchhigherthanthatoftheFe-freesample(C–N).Additionally,theintermediatesofC–FeNformedduringeachsyntheticprocedurehavebeenthoroughlycharacterizedbymultiplemethods,andthefunctionofeachprocedurehasbeendiscussed.TheC–FeNsampleexhibitshighelectro-catalyticstabilityandsuperiorelectro-catalyticactivitytowardORRinalkalinemedia,withitshalf-wavepotential20mVlowerthanthatofcommercialPt/C(40wt%).Itisfurtherincorporatedintoalkalinepolymerelectrolytefuelcell(APEFC)asthecathodematerialandledtoapowerdensityof100mW/cm~2.

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  • 简介:Thestudyofoperatorssatisfyingσja(T)=σa(T)isofsignificantinterest.Doesσja(T)=σa(T)forn-perinormaloperatorT∈B(H)ffThisquestionwasraisedbyMecheriandBraha[Oper.Matrices6(2012),725–734].Inthenoteweconstructacounterexampletothisquestionandobtainthefollowingresult:ifTisan-perinormaloperatorinB(H),thenσja(T)\{0}=σa(T)\{0}.Wealsoconsidertensorproductofn-perinormaloperators.

  • 标签: 运算符 注记 运营商 歌剧院 张量积
  • 简介:Letr,1p={f:fr-1isabs.cont.onI=[a,b],fisperiodiewithperiodH(=b-a),f(x1)=0,‖f(r)‖p≤0},wherex1isanyfixedpointin[a,b].TheauthorfindstheKolmogorov,Gel’land,linear,andBerusteinn-widthsofr,1pinLp(I)fornodd,∞>p>1.Theoptimalsubspacesandoperatorsarealsofound.

  • 标签: operators KOLMOGOROV proof hereby VALUED 加名
  • 简介:ThepresentpaperdealswithfindingofconstantoccurringintheorderofapproximationofthefunctionofLipα(O<α<1)classbyusing(N,p)operator.Obviouslythefactor1/(1-α)becomeslargewhenαiscloseto1.Wehaveshowntheroleofthisfactorintheconstantofapproximation.

  • 标签: deals operators finding INTEGRABLE proof N p)OPERATOR
  • 简介:Inthispaper,alargeclassofndimensionalorthogonalandbiorthognalwaveletfilters(lowpassandhighpass)arepresentedinexplicitexpression.Wealsocharacterizeorthogonalfilterswithlinearphaseinthiscase.Someexamplesarealsogiven,includingnonseparableorhogonalandbiorthogonalfilterswithlinearphase.

  • 标签: 有限小波滤子 显式表示 正交滤子 线性相 双正交滤子
  • 简介:Wetrytoapplyaconstituentquarkmodel(avarietychiralconstituentquarkmodel)andtheresonatinggroupapproachforthemulti-quarkproblemstocomputetheeffectivepotentialbetweentheNN-inS-wave(thequarksinthenucleonsNandN-,andthetwonucleonsrelativelyaswell,areinSwave)soastoseethepossibilityiftheremaybeatightboundstateofsixquarksasindicatedbyastrongenhancementatthresholdofpp-inJ/ψandBdecays.TheeffectivepotentialwhichweobtainintermsofthemodelandapproachshowsiftheexperimentalenhancementisreallycausedbyatightS-waveboundstateofsixquarks,thenthequantumnumberoftheboundstateisverylikelytobeI=1,JPC=0-+.

  • 标签: 核子-反核子效应 多夸克系统 夸克成分模型 BES 高能物理学