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9 个结果
  • 简介:Hydrotalcitecanactasaco-stabilizerwithothermainstabilizerforpoly(vinylchloride)(PVC).ThethermalstabilityandfluidpropertyofPVCfilledwithhydrotalcitesurface-treatedwithtitanateandsilanewerestudiedinthiswork.OrganicSnisamainstabilizerandhydrotalciteisastabilizingassistant.ThestabilityofthePVCresinmixedwithorganicSnandhydrotalciteisbetterthanthatofthePVCresinmixedwithorganicSnalone.ItisshownthatthePVCresinfilledwithhydrotalcitepossessesabetterstaticanddynamicheatstability.Moreover,hydrotalcitecanimprovethefluidpropertyofPVC,whichisadvantageoustotheprocessingofPVC,andtheoptimumcontentofhydrotalciteisabout1%-2%(massfraction).

  • 标签: Hydrotalcite PVC Thermal stability FLUID PROPERTY
  • 简介:Inordertopredictthemechanicalperformanceofthepolyvinylchloride(PVC)atahighoperatingtemperature,aseriesofshort-termtensilecreeptests(onetenthofthephysicalagingtime)ofthePVCarecarriedoutat63Cwithasmallconstantstressbyadynamicmechanicalanalyzer(DMA).TheStruik-Kohlrausch(SK)formulaandStruikshiftingmethodsareusedtodescribethesecreepdataforvariousphysicalagingtime.AnewphenomenologicalmodelbasedonthemultiplerelaxationmechanismsofanamorphouspolymerisdevelopedtoquantitativelycharacterizetheSKparameters(theinitialcreepcompliance,thecharacteristicretardationtime,andtheshapefactor)determinedbytheagingtime.ItisshownthatthemomentarycreepcompliancecurveofthePVCat63CcanbeverywellfittedbytheSKformulaforeachagingtime.However,theSKparametersforthecreepcurvesarenotconstantduringtheagingprocessattheelevatedtemperatures,andtheevolutionoftheseparametersandthecreeprateversusagingtimecurvesatthedoublelogarithmiccoordinateshaveshownanonlinearphenomenon.Moreover,thecreepmastercurvesobtainedbythesuperpositionwiththeStruikshiftingmethodsareunsatisfactoryinsuchacase.Finally,thepredictedresultscalculatedfromthepresentmodelincorporatingwiththeSKformulaareinexcellentagreementwiththecreepexperimentaldataforthePVCisothermallyagedatthetemperaturerelativelyclosetotheglasstransitiontemperature.

  • 标签: 玻璃化转变温度 蠕变性能 时效温度 对接 老化时间 C相
  • 简介:HEATS OF INTERACTION OF ORGANIC BASES WITH POLYMER PROTECTED CATALYST PVC-AlCl_3HEATSOFINTERACTIONOFORGANICBASESWITHPOLYMERPR...

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  • 简介:通过建立机理模型,量化分析可能对式除尘系统除尘效率产生影响的因素,并分析其对除尘效率的影响随时间的变化,再以式除尘系统作为研究对象,定义1年内正常工作状态下除尘效率的变异系数(标准差/平均值)为系统稳定性合理指标,对系统运行稳定性作出评价。最后,预测垃圾焚烧厂的最大扩建规模和使用新工艺后的稳定性能提升情况,并给环保部门的检测提供相关建议。

  • 标签: 袋式除尘系统 机理模型 除尘效率 变异系数
  • 简介:ThePVCservesofmacroporoussulfoniccation-exchangeresinswerepreparedbythesulfonationofamacroporousPVCbeadwithconcentratedsulfonicacidorchlorosulfonicacid.theresultingsulfonicresinwasemployedintheinvestigationofcatalyticesterificationandsolfteningofwater,Theresultsshowthattheyieldsofestersreach60.0-84.4%accordingasdifferentfattyacidsandalcohols,therefractiveindexesofestersobtainedresemblethosereportedinthereferencesbasically,meanwhile,345Lsoftenedwaterwhichholds≤0.06mmol/Lhardnesswouldbepreparedby1Lwetsulfonicresinreusingfor4times.Theresultingsulfonicresinswouldhave1.6-2.0or2.5-3.0mmol/gexchangecapacitybyusingconcentratedsulfonicacidorchlorosulfonicacidassulfonatingagent,respectively,Thesulfonicresinhasamacroporousstructuretakingthemorphologywithagglomeratesofminutelysphericalgelparticlesascharacteristic.

  • 标签: 合成树脂 催化酯化 水处理
  • 简介:城市生活垃圾袋装化已成为我国城市生活垃圾主要的收集方式,在垃圾处理过程中,根据选择性破碎的原理,开发、研制了破破碎分选机。其工作原理是:当袋装生活垃圾由进料口进入破破碎分选机内,经过低速破破碎辊筒的第一次破后,在内垃圾分散的同时进行选择性破碎,即对大块的有机物进行破碎,对大块、硬质无机物不进行破碎;高速破破碎辊筒将低速破破碎辊筒破不充分的垃圾再次进行破,同时再次对垃圾进行选择性破碎,使大块有机物得到充分破碎,有利于后续分选:两级避让装置和破破碎刀片的自我保护功能能够使大块、硬质无机物不被破碎而直接通过。拨料辊筒中伸缩运动的拨料棒将破后的塑料、柔韧性物料和大块无机物挑走。垃圾中的有机物和无机物由不同的出料口排出。

  • 标签: 城市生活垃圾 选择性破碎 分选设备 袋装化 破袋 工作原理
  • 简介:在这研究,一新(乙烯基氯化物)(PVC)poly,为Ho3+离子的膜传感器作为ionophore基于N-phenyl-2-(thiophen-2-ylmethylene)hydrazinecarbothioamide(PHC)被准备。这个传感器与阳离子的变化比较向钬离子表明了好选择和敏感,包括碱,碱的地球,转变和重金属离子。电极的反应性质上的膜作文和pH的效果被调查。详细,建议传感器展出了Nernstian行为(与20.4的一个斜坡??洀????x

  • 标签: 膜传感器 离子测定 膜制备 钬离子 苯基 噻吩