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简介：ThemetalbindingsitesinthetwoPtcontainingmetallothioneins(Pt-MTandPt14MT)wereexaminedbymeansofPt(II)L3-edgeextendedX-rayabsorptionrinestructure(EXAFS)spectroscopy.ComparisonsbetweenthephaseandamplitudefunctionsderivedfromtheisolatedshellstothoseofPt…Pt.Pt-SandPt-NmodelcomponentsshowedthateachplatinuminPt7MTwascoordinatedbyfoursulfuratomsatadistanceof2.31±0.01A.AnalysisoftheoutershelldataofplatinumatominPt7MTindicatedbackscatteringplatinumatomatapproximate4.29A.StrkinglydifferentstructuralparametershadbeenobtainedforthePt14MTspecies.fittingofthefirstshellrevealedthateachplatinumwascoordinatedbytwosulfursatthedistanceof2.3-±0.02Aandtwonitrogensat2.02±0.02A.TheresultsoftheworkprovidedthedetailedinformationconcerningthelocalenvironmentsofthecoordinatedPt(II)inthesetwoplatinothioneins.

简介：Fe2O3nanoparticlescoatedwithsodiumdodecylbenzenesulphonate(DBS)orcetyltrimethylammoniumbromide(CTAB)werepreparedbyusingamicroemulsionmethodinthesystemwater/toluene.Thenanoparticleswerecharacterizedbymeansoftransmissionelectronmicroscopyandaverageparticlesizesof5.0nmand6.0nmwerefoundforDBS-modifiedandCTAB-modifiednanoparticlesrespectively.Thelocalatomicstructuresoftheseiron(Ⅲ）oxidenanoparticleswereprobedbyusingtheextendedx-rayabsorptionfine-structuretechnique.FeKabsorptionspectrawerecollectedatbeamline4W1BofBeijingSynchrotronRadiationFacility.Astructurealmodelwasproposedfordescribingtheiratomicstructures.TheFe-ObondlengthatthesurfaceofDBS-coatedFe2O3nanoparticleswasfoundtobesimilartothatinbulkFe2O3.buttherewasabout0.04AexpansionfortheCTAB-coatedFe2O3nanoparticles.Onthebasisofthemodelproposedinthispaper,thethicknessesofthesurfacelayerswereestimatedtobe0.5nmand0.7nm.respectively,fortheDBS-coatedandCTAB-coatedFe2O3nanoparticles.Theanharmonicityoftheatomicvibrationandtheasymmetryofatom-pairdistributionwerefoundtobelargeratthesurfaceofthenanoparticlesthaninthebulkmaterial,whiletheDebye-Wallerfactorsarealmostthesameforthesurfaceandthecorepartsofthenanoparticles.Itcanbeconcludedthattheatomicstructureofthenanoparticlesurfaceisordered.buttheatom-paridistributionisasymmetric.