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简介：BasedonthepracticeofBaosteel's60000m3/hairseparationunit(ASU),whichisthefirstdomestically-integratedunitofsuchascale,thispaperstudiestheprinciplesoftypeselectionofthedistributioncontrolsystem(DCS).Itdiscussesthedesignoftheunit'scontrolsystem,whichinvolvesacompressorsystem,apurificationsystem(molecularsieving),aturboexpansionsystemandanairseparationsystem.ThefinalpartofthepaperdiscussesthemaintenanceandfuturedevelopmentoftheASUcontrolsystematBaosteel.

简介：Trendsintoday’ssteelproductionshowincreasingdemandsforhighly-sophisticatedsteelgrades.Therefore,thesteelindustrywilleventuallyberequiredtoinstallbestperformingtechnologiestomeetgovernmentalspecificationsdesignedtosignificantlyreduceenvironmentalemissions.Sucheffortsaresupportedbyinnovativenewsolutionsintheentiresteelmakingprocess.Oneprocessthatwillneedtobeaddressedisthecleanlinessofthesteelintheliquidsteelphase,especiallyduringtheBOF-tappingprocess.Thenewconvertergate(CG)(Fig.1)bestsupportstheslidegatetappingtechnologyforconvertersintermsofcleansteel,productivity,yieldandavailability-atreducedcosts.TheCGgateintroducesauniquefeatureforconverterslidegates:Thebottomplatecanbeexchangedwhilethegateremainsmountedontheconverter.Thisnewfeatureallowsforanincreasedutilisationoftherefractorypartsandasignificantreductionofthedowntimeoftheconverter.This'designedefficiency'isachievedwitharefractorysetconsistingofthreeidenticalplates-twobottomplatesandonesliderplate-andanozzle.AnumberofotherimprovementssuchasautomaticcylindercouplingusingtheInterstopSNAPtechnologyandatwosteptensioningsystemhavealsobeenimplemented.ThenewsystemisdesignedtomeetminimalspacerequirementsandthereforewilladapttomostBOFshops.Toperformpreparation,serviceandmaintenanceworkthemodularCGgatecanbedismountedfromtheconverterandsimultaneouslyreplacedbyaready-to-useunit.Thedegreeofautomationfordismountingandmountingaswellasforoff-linepreparationhasbeenenhancedandreducesmanualefforts.Thispaperprovidesasolutiontotheobvioustrendtowardsefficientandcontrolledproductionofcleansteel,ingeneral,andespeciallyatBOFshops.Moreover,itspecificallydescribestheoperationalresultsofthisinnovativeBOFtappingequipmentatSalzgitterFlachstahlGmbH,Germany.

简介：BulknanocrystallineSmCo6FesinteredmagnetwaspreparedbySparkPlasmaSinteringtechnique(SPS).XRDpatternsshowthatthemagnetexhibitsastableTbCu7structure.TEMobservationindicatesthatthemicrostructureofthemagnetiscomposedofSmCo6Fesinglephasegrainswithanaveragegrainsizeof30nm.Magneticmeasurementshowsthatunder9Tmagneticfield,thecoercivityofthemagnetreaches1.12T;thesaturationmagnetizationandtheremanenceare1.13and0.67T,respectively.Themagnethasa(BH)maxof75.6kJ·cm-3.

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简介：Surface-treatedMmNi3.55Co0.75Mn0.4Al0.3alloyasnegativeelectrodematerialofnickel-metalhydridebatterywasemployedtoimprovethehigh-ratedischargeability.SurfacetreatmentwasrealizedbydippingandstirringthealloyintoaHClaqueoussolutionwithvariousconcentrationsatroomtemperature.ThemicrostructureofthealloybeforeandaftersurfacetreatmentwasanalyzedbyX-raydiffraction(XRD)andscanningelectronmicroscopy(SEM).Theelectrochemicalpropertiesbeforeandaftersurfacetreatmentwerecompared,andthealloytreatedin0.025mol/LHClsolutionshowedtheoptimalhigh-ratedischargeability.

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简介：ThecompoundSm0.98Fe9.02–xGaxNδ(x=0,0.25,0.5,0.75,1)werepreparedbymelt-spunmethodandsubsequentannealingandnitriding.TheRietveldanalysisshowedthatthelatticeexpansionplayedanimportantroleinimprovingtheCurietemperature.AnobviousdevelopmentoftheCurietemperaturewasobtainedwiththeincreasedGacontentfromx=0–1(ΔTc=90oC).Theoptimumcoercivityofnitrideswasobtainedatx=0.25withthevalueHcj=652kA/m(8.15kOe)afterannealing,whichcorrespondedtoareasonabledistributionofgrainsizesofbothTbCu7-typeSmFe9Nδandα-Fe.However,anexcessofGadopingmightleadtoanabnormalgrowthofα-Fe,whichinturndeterioratedthemagneticproperties.ItwasconcludedthatamoderateGacontentwasveryeffectiveinraisingthecoercivityandCurietemperamentintheTbCu7-typeSm-Fe-N.

简介：TheLa-CosubstitutedSr_（1–x）La_xFe_（12–x）Co_xO_（19）（x=0–0.5）ferriteswithappropriateBi_2O_3additivewerepreparedbyconventionalsinteringmethodandmicrowavesinteringmethodatlowsinteringtemperaturescompatiblewithLTCC（lowtemperatureco-firedceramics）systems,andtheirsinteringbehaviorwaschieflyinvestigated,includingthecrystalstructure,saturationmagnetizationMs,magneticanisotropyfieldHa,intrinsiccoercivityHci,andCurietemperatureTC.ExperimentresultsclearlyshowedthatthepureM-typecrystalphasewassuccessfullyobtainedwhentheLa-Cosubstitutionamountxdidnotexceed0.3.However,thesingleM-typephasestructuretransformedtomultiphasestructurewithfurtherincreasedx,wheretheM-typephasecoexistedwiththenon-magneticphasesuchasα-Fe_2O_3phase,La_2O_3phase,andLaCoO_3phase.AppropriateLa-CosubstitutionimprovedtheMs（〉62emu/g）,Ha（〉1400kA/m）,andHci（〉320kA/m）fortheferriteswithxvaryingfrom0.1to0.3,buttheTCdecreasedwithincreasingsubstitutionamount.Moreover,themicrowavesinteredferritescouldprovidelargerHciandsimilarMscomparedwiththeconventionalsinteredferrites.

简介：La公司代替了M类型钡铁酸盐(欺骗)由传统的稳固的状态被准备在低温度(1173K)的方法和sintered。X光检查衍射(XRD)，扫描电子显微镜学(SEM)和颤动的样品磁强计(VSM)被采用在样品的结构和磁性上调查La公司的影响。由在为在空中的6h的1173K的sintering，有Ba(LaCo)xFe122xO19(x=0.00.5)的化学作文的单个阶段M类型钡铁酸盐被形成。M-H曲线证明钡铁酸盐的磁性被La公司替换显然完成。浸透磁化(女士)和coercivity(Hc)分别地到达了65.15Am2/kg和4165Oe的最大的价值。这行为被归因于La公司替换和粒子尺寸的地点。SEM表明铁酸盐粒子的形状被La公司替换影响。

简介：TheeffectofrapidsolidificationonstructureandelectrochemicalperformanceoftheLaNi4.5Co0.25Al0.25hydrogenstoragealloywasinvestigatedbyX-raypowderdiffractionandasimulatedbatterytest,includingmaximumcapacity,cyclingstability,self-discharge,andhigh-ratedischargeability(HRD).Allthemelt-spunalloysweresingle-phasewiththeCaCu5-typestructure(spacegroupP6/mmm).Incomparisontotheas-castalloy,therapidlyquenchedalloysmanifestedanimprovedhomogeneityofcompositionandexpandedlatticeparameters.Theelectrochemicalmeasurementsshowedthattheactivationproperty,cyclingstabilityandself-dischargeofthealloyelectrodeswerealsoimprovedfortherapidsolidifiedalloys.TheHRDoftheas-castalloywasbetterthanthoseofalltherapidlysolidifiedalloys.Asthequenchingrateincreased,theHRDandexchangecurrentdensityfirstdecreasedandthenincreased.

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简介：La15Fe77B8hydrogenstoragealloyswerepreparedusingavacuuminduction-quenchingfurnace.TheresultsofX-raydiffraction(XRD)andscanningelectronmicroscopy(SEM)suggestedthatLa15–xSmxFe2Ni76Mn5B2(x=0,2,4,6)alloyshadmultiphasestructureincludingthemainLaNi5phase,La3Ni13B2phaseand(Fe,Ni)phase.WiththeincreasingsubstitutionofSmforLa,themainphasestructureofalloysdidnotchange,whiletheunitcellvolumesdecreased,thecyclestabilitywasimprovedandthemaximumdischargecapacitydecreased,butthelowtemperaturemaximumdischargecapacityofthesamesubstitutionalloywasgraduallyapproachingthemaximumdischargecapacityatroomtemperature,whichshowedthatLa15Fe77B8hydrogenstoragealloysofthepartialsubstitutionofSmforLahadbetterlow-temperaturedischargeability(LTD).Forthesamesubstitutionalloys,self-dischargecharacteristicsandcyclestabilityatlowtemperaturewerebetterthanthatatroomtemperature.Furthermore,thehigh-ratedischargeability(HRD)andtheexchangecurrentdensityI0firstincreasedandthendecreasedwiththeincreasingofSmcontent,whereasthehydrogendiffusioncoefficientDinalloybulkdecreasedgradually,whichindicatedthatappropriatesubstitutionofSmforLaimprovedtheelectrochemicalkineticspropertiesofthealloys.TheHRDwasmainlydominatedbythecharge-transferrateonthealloysurface.