简介:Emissionquenchingof[Ru(bpy)2(4,4’-dcbpy)](PF6)2(1)bybenzenamine,4-[2-[5-[4-[4-dimethylamino]phenyl]-4,5-di-hydro-1-phenyl-1H-pyrazol-3-yl]-ethenyl]-N,N-dimetyl(2)or1,5-diphenyl-3-(2-phenothiazine)-2-pyrazoline(3)wasobserved.Measurementsoftheemissiondecayof1beforeandafteradditionof2or3bysinglephotoncountingtechniquecon-finnedtheobservations.Theemissionquenchingof1by2or3wassubmittedtoStern-Volmerequation.Itwascalculatedthatthequenchingrateconstants(kq)are5.5×109(mol/L)-1s-1for2and4.0×109(mol/L)-1s-1for3,respectively.Theseresultsindicatedacharacterofdynamicquenchingprocess.Thesinglet-stateof2or3wasalsoquenchedby1.ThequenchingbehaviorsdidnotconformtotheStern-Volmerequationandinvolvedbothstaticanddynamicquenchingprocesses.Theapparentquenchingrateconstant(kapp)wascalculatedtobe3×109(mol/L)-1fortheinteractionofexcited2with1,and1.2×109(mol/L)-1forthatofexcited3wit
简介:Therearemoreandmorecountriestoakeanefforttothestudiesofvanadiumalloyforfusionapplication.NIFSinJapanhasrecentlydevelopedan80kgheatV4Cr4Tialloy(NIFS-heat2)aftertheproductionofa500kgscaleV4Cr4TiinU.S.severalyearsago.PropertyevaluationofthealloyhasbeenputintoaninternationalcollaborationprogramunderthecoordinationofIEA(InternationalEnergyAgency).SWIPhasjoinedthecollabrationonthehydrogenembrittlementresistanceevaluationofthealloyt.
简介:让x:Mn是有非零主管弯曲的脐的免费hypersurface。然后,x与Laguerre公制的g被联系,Laguerre张肌\mathbbL\mathbb{L},Laguerre形式C,和一个Laguerre秒基础形成\mathbbB\mathbb{B}它是在Laguerre下面的x的invariants转变组。如果它的Laguerre形式消失,hypersurfacex被称为Laguerreisoparametric并且\mathbbB\mathbb的特征值{B}是不变的。在这份报纸,我们在4分类所有Laguerreisoparametrichypersurfaces。
简介:SinceitserliestyearsofR&D[1],theGEANT4simulationtoolkithasbeendevelopedfollowingsoftwareprocessstandardswhichdictatedtheoverallevolutionoftheproject.Thecomplexityofthesoftwareinvolved,thewideareasofapplicationofthesoftwareproduct,thehugeamountofcodeandCategorycomplexity,thesizeanddistributednatureoftheCollaborationitselfareallingredientswhichinvolveandcorrelatetogetherawidevarietyofsoftwareprocesses.Althoughin"production"andavailabletothepublicsinceDecember1998,theGEANT4softwareproduct[1]includesCategoryDomainswhicharestillunderactivedevelopment.Thereforetheyrequiredifferenttreatmentalsointermsofimprovementofthedevelopmentcycle,system,testingandusersupport,ThisarticleismeanttodescribesomeofthesoftwareprocessesastheyareappliedinGEANT4forbothdevelopment,testingandmaintenanceofthesoftware.
简介:Poly(4-vinylpyridine)(P4-VP)nanofiberandfluoresentpoly(4-vinylpyridine)/porphyrin(P4-VP/TPPA)nanofiberwererespectivelypreparedbyelectrospinning.TheeffectoftheconcentrationofP4-VP/dimethylformamide(DMF)electrospinningsolutionsonthemorphologyofP4-VPnanofiberwasinvestigatedanditwasfoundthattheaveragediameterofthenanofiberofP4-VP/DMFincreasedwiththeincreaseoftheconcentrationofthespinningsolution.AftertheadditionofTPPAtotheP4-VP/DMFspinningsolution,thediameterofP4-VP/TPPAnanofiberbecameevenduetotheincreaseoftheconductivityoftheP4-VP/DMF-TPPAsolution.Thephotoluminescent(PL)spectralanalysisindicatesthattheemissionpeakpositionofP4-VP/TPPAnanofiberisalmostthesameasthatofpureTPPAatabout650nmwithoutpeakshift,andwhenitwasstoredfor20days,theemissionpeakofP4-VP/TPPAnanofiberisalsoat650nm,indicatingthatthefluorescentpropertyofP4-VP/TPPAnanofiberisstable.Fourier-transforminfrared(FTIR)spectrumconfirmsthechemicalcompositionoftheresultingP4-VP/TPPAcompositenanofiber.
简介:Vanadiumalloys(V-Cr-Tiseries)areimportantcandidatematerialsforblanketcomponentsoffusionreactorsduetotheirlowactivationandhighstrengthatelevatedtemperatures.Low-temperatureirradiationembrittlementdeterminestheoperationtemperaturelimitofVanadiumalloysfortheapplicationtostructuralmaterialsoffusionreactorsirradiationresponseofvanadiumalloysneedstobeclarifiedfortheirapplication.Inthepresentstudy,specimensoftwoalloys(V-4Cr-4TiandV-5Cr-5Ti)wereirradiatedwithenergeticHeionsandheavyionstounderstandhardeningofthealloysduetoheliumaccumulationandcascadedamageproduction.