简介:
简介:这个工作的目的是用电气化学的技术,光显微镜学,扫描电子显微镜学(SEM),和精力与氟化物离子在酸的人工的口水为牙齿的应用学习Ti-6Al-4V合金的降级行为散的spectrometry(版本)。试验性的结果证明那个氟化物离子在Ti-6Al-4V合金的降级上有重要影响,并且有氟化物离子(大约0.1wt%)的明显的批评集中。与增加氟化物离子集中,腐蚀潜力(E合金的corr)移动了向否定并且同时,合金的阻抗减少了到严重pitting腐蚀的从最小的腐蚀的显著转变在跟随TiO2的溶解的合金表面上被观察被动电影,导致合金的腐蚀抵抗的减少。TiO2的电气化学的溶解被动电影包含了氟化物原子的亲核的攻击到TiO2的钛原子。另外,在酸的口水的Ca2+和Na+可以包含表面反应并且使反应更复杂。
简介:Atomized,pre-alloyedTi—24Nb—4Zr—7.9Sn(wt%)powderwasusedtofabricatesolid,prototypecomponentsbyelectronbeammelting(EBM).Vickersmicroindentationhardnessvalueswereobservedtoaverage2GPafortheprecursorpowderand2.5GPaforthesolid,EBM-fabricatedproducts.Thepowderandsolidproductmicrostructureswereexaminedbyopticalandelectronmicroscopy.X-raydiffractionanalysesshowedthattheyhadbccβ-phasemicrostructure.However,itwasfoundbytransmissionelectronmicroscopythattheEBM-fabricatedproducthadplatemorphologywithspace~100—200nm.Althoughthecorrespondingselectedareadiffractionpatternscanbeindexedbyβ-phaseplusα'-martensitewithorthorhombiccrystalstructure,thedark-fieldanalysesfailedtoobservethea'-martensite.Suchphenomenonwasalsofoundindeformedgummetalsandexplainedbystress-induceddiffusionscatteringduetophononsoftening.
简介:AdditivelymanufacturedTi-6Al-4Vlatticestructureshavefoundimportantnicheapplications.However,theyoftenshowinsufficientcompressiveductilityorinsufficientstructuralintegrity.Inthisstudy,abatchof45octahedralTi-6Al-4Vlatticestructureswasmanufacturedinthreedifferentstrutdiameters(0.5,1.0,1.5mm)byselectiveelectronbeammelting(SEBM).Theinfluenceofpost-SEBMannealingonthecompressivedeformationcharacteristicsofthelatticestructurewasinvestigated.Theas-builtTi-6AI-4Vlatticesfragmentedwhenthecompressivestrainreached13%-23%dependingonstrutdiameter.Annealingat950℃(Ptransustemperature:995℃)onlyslightlyimprovedthecompressiveductilityofthelatticestructures.However,annealingat1050℃(p-annealing)fundamentallychangedthecompressivedeformationmodeofthelatticestructures.Theresultantcompressivestress-straincurvewasfeaturedbyalongsmoothplateauandnofactureoccurredevenaftersignificantdensificationofthelatticestructurehadtakenplace(>50%ofcompressivestrain).
简介:Bismuth-basedSillen-Aurivilliuscompoundsarebeingexploredasefficientphotocatalystmaterialsforthedegradationoforganicpollutantsduetotheiruniquelayeredstructurethatfavourseffectiveseparationofelectron-holepairs.Inthiswork,wesynthesizedSillen-Aurivillius-relatedBi2YO4CIwiththebandgapof2.5eVbyasimplesolid-statereactionandsensitizedwithrhodiumnickel(RhNi)nanoparticles(NPs)toformtheRhNi/Bi2YO4CIheterostructure.PhotocatalyticactivitiesofBiOCI,Bi2YO4CIandtheRhNi/Bi2YO4CIheterostructurewereexaminedforthedegradationofrhodamine-6Gundervisible-lightillumination.ResultsdemonstratedthatthephotocatalyticdyedegradationefficiencyofRhNi/Bi2YO4CIheterostructuresishigherthanthoseofBiOCIandBi2YO4CI,attributedtothesynergisticmolecular-scalealloyingeffectofbimetallicRhNiNPs.Theplausiblemechanismforthedegradationofrhodamine-6Gandtheeffectiveelectron-holepairutilizationmechanismwerediscussed.
简介:
简介: