简介：利用反射式光谱发射率测量装置在300K至873K之间对两种铝合金Al5052和Al6061的光谱发射率进行了测量,利用最小二乘法对测量数据进行了线性拟合。研究结果表明：在300K至873K之间,Al5052和Al6061的光谱发射率均随温度升高呈线性关系增大;在不同温度点,加热时间对光谱发射率的影响不相同,虽然Al5052与Al6061的组分非常相近,但是两者的光谱发射率却有着较大的差异,特别是在高温段,两者的差异尤其显著。本研究将进一步丰富铝合金的光谱发射率数据,同时为工业上利用辐射测温技术准确测量铝合金表面温度提供了实验依据。

简介：Anewμ3-Otriiron（Ⅲ）complex[Fe3O（OBz）6（CH3OH）3]（NO3）（CH3OH）2（HOBZ=benzoicacid）hasbeensynthesized,itsstructurehasbeendeterminedandvariabletemperaturemagneticsusceptilityhasalsobeenmeasured.Inthemolecule,threeironatomsformedanequilateraltrianglewithu3-Oincenter.ThefittingtothemagneticsusceptibilityshowedthatanintramolecularantiferromagneticexchangeinteractionoccurredbetweenironatomswithJ=-25.51cm-1,andaweakerintermolecularantiferromagneticexchangeinteractionoccurredwithzJ’=-2.30cm-1.

简介：Fouriertransformedinfraredspectrometry(FTIR)and27AlMagicAnglespinning(MAS)nuclearmagneticresonancespectroscopywereemployedtocharacterizearsenateadsorptiononamorphousAlgelswithKegginstructureatpH=4–10.Thesestudieshaveproventhat:thesurfacecomplexspeciesofarsenateshowsignificantdifferencesunderacidicandalkalineconditions,whichwasdeducedbasedontheAs-Ostretchingvibrationbandslocatedrespectivelyat774and870cm-1;poorlycrystallineAl13(orAl)-arsenateprecipitationcouldbeeasilyformedunderacidmediumconditionandhighloadinglevel,whichwassupportedbycomparingtheAs-Ovibration(at≈732cm-1)ofprecipitationtoadsorbedAlgels;arsenate(AsO43-)adsorptionhasnoeffectontheKegginstructureofAlgelswithbasicity(R)=2.6and3.0,evenathighloadinglevel,asevidencedbythesignalat≈63×10-6ofmagicanglespinning(MAS)-27AlNMR.Theadsorptionenvelopewasdeterminedbyconventionalbatchexperiments.

简介：以便获得两高电镀物品迁居(他们)在高周波的表面的可靠性和罚款维的控制声学的波浪(锯)设备，4-layeredTi/Al-Mo/Ti/Al-Mo电极电影在128°Y-XLiNbO3上被调查由劈啪作响的底层免职。结果显示4-layered电影与常规Al-0.5wt.%Cu电影相比有改进他们可靠性。他们的一生比在5×的当前的密度测试的Al-0.5wt.%Cu电影的长约三倍107A/厘米2和200°C的温度。而且，4-layered电影容易在反应离子蚀刻被蚀刻，罚款维的控制为高周波的锯设备在模式复制期间被认识到。为4-layered电影，最佳瞬间数量和劈啪作响的参数为高他们可靠性是很重要的。

简介：Thedevelopmentofthehydrogenelectrodeisvitalfortheapplicationofalkalinepolymerelectrolytefuelcells(APEFCs).Inthisstudy,aseriesofNi(OH)2decoratedNi/Ccatalysts(Ni(OH)2-Ni/C)werepreparedbyathree-stepelectrochemicaltreatmentofNi/C.TheexistenceofNi(OH)2wasdemonstratedbyX-rayphotoelectronspectroscopy(XPS),andthesurfacemolarratioofNi(OH)2/Niofthesampleswasestimatedviaanelectrochemicalmethod.TheHORcatalyticactivityofthecatalystswasevaluatedbyarotationdiskelectrode(RDE)method,anda'volcanoplot'wasestablishedbetweentheHORexchangecurrent(j0)andthesurfacemolarratioofNi(OH)2/Ni.Ontopofthe'volcano',thesurfacemolarratioofNi(OH)2/Niis1.1:1,thej0ofwhichwas6.8timesofthatofNi/C.ThestabilityofthesamplestowardHORwasevaluatedtobegood.OurstudyaddedasystematicexperimentalevidencetotheHORresearch,showingthattheHORcatalyticactivityofNicanbedeliberatelycontrolledviadecorationofNi(OH)2,whichmayhelpunderstandingtheHORmechanismonNi.

简介：氯化铵溶液能溶解Mg（OH）2,实为沉淀溶解平衡、氨水的电解质平衡以及水的电离平衡综合作用的结果,其本质为离子反应,是NH4＋还是H3O＋首先作用于Mg（OH）2的沉淀溶解平衡,对此学术界无统一的观点。复分解反应的活化能几乎为0,但各种离子的扩散速率不尽相同,多种离子参加反应时,到底哪种离子首先碰撞先发生反应,实难判断,事实上也不重要,但我们可以通过计算、实验得出铵盐溶解Mg（OH）2的＂功劳＂主要是NH4＋,而不是H3O＋,同时指出低浓度的铵盐难以溶解氢氧化镁的事实。

简介：一、问题的提出在人教版《必修·化学1》第60页实验3-9中，制备的Fe（OH）2和Fe（OH）3都是不溶性碱，在洗涤使用后的试管时发现，刚使用过的试管用强酸盐酸（或硫酸）很容易洗净，而放置过夜的的试管在洗涤浸泡后仍很难洗净，而使用草酸却很容易浸泡洗涤干净。且使用草酸浸泡洗涤后的溶液变为黄绿色。

简介：TheconductivitybehaviorofAl(OH)3-acrylamidehybridpolyacrylamide(hybridPAAm)indistilledwaterwasstudied.Adiscontinuityphenomenonoftheconductivity(k)versusconcentration(c)curveofthehybridPAAminacertainconcentrationregimeisfound.ThisphenomenonisdependentonthemolecularweightofthehybridPAAmandontheparticlesizeandcontentoftheAl(OH)3colloidinthehybridPAAm.ThisphenomenonwasaccountedforassumingionizationofthehybridPAAm.

简介：Anisotropicstructures,nanoneedles,andnanospindlesofrareearthhydroxychloride(RE(OH)2Cl)andoxychloride(REOCl)(rareearth=EuandTb)weresynthesized.Therareearthhydroxychloridenanostructureswereformedviaathermallyassistedhydrolysisoftherare-earthsesquioxidenanocrystals.Themorphologicalevolutionofthenanostructureswasstudiedusinghigh-resolutiontransmissionelec-tronmicroscopyandscanningelectronmicroscopy,whilethestructuralevolutionwasinvestigatedusingX-raydiffractiontechniques.Thethermalstabilityoftherareearthhydroxychlorideswasinvestigatedusingthermogravimetricanalysis.Therareearthoxychloridenanospin-dlesweresynthesizedviaasimpleheat-treatmentofrareearthhydroxychloridenanospindles.

简介：在80%Al-20%CuO（质量分数）体系中,通过原位反应法制备Al2O3p-Al复合材料。采用不同方法研究CuO颗粒粒度对复合材料合成温度和显微组织的影响。结果表明,CuO颗粒粒度对Al-CuO体系的完全反应温度有显著影响：含有粒度小于6μmCuO颗粒样品的完全反应温度比含有粒度小于100μmCuO颗粒样品的完全反应温度低200°C。当反应温度低于某一临界值时,原位Al2O3颗粒和Al基体之间不能完全结合;当温度高于某一临界值时,原位Al2O3颗粒的形貌从棒状转变成近球形。这两个临界温度受CuO颗粒粒度的影响：含有粒度小于6μmCuO颗粒样品的临界温度比含有小于100μmCuO颗粒样品的临界温度低100℃。

简介：Thispaperpresentstheprincipleofphasemodulationoftheopticalwave,thatisusingadensefringefamilytomodulateanotherfringepattern,anditsapplicationinfringemultiplication.Itisofuniversalsignificanceinopticallyexperimentalmechanics.

简介：四个参数，煤气的流动，旋转速度，精制时间，和炖的时间的效果，在7075的旋转impeller精炼上，艾尔被学习。C2精制的Cl6，精制的旋转impeller，并且7075艾尔合金的合成精制与对方相比。结果证明旋转impeller精炼的最大的影响参数是旋转速度，由煤气的流动，精制时间，和炖的时间列在后面。直角的分析获得的最佳纯化参数如下：400r/min，0.4mL/h的惰性的煤气的流动，15min的精制时间，和6min的炖的时间的转子速度。最好的排除效果能被C2Cl6和旋转impeller。C2Cl6,旋转impeller，并且合成精制分别地是34.5%，69.2%，和78%。旋转impeller精制的标本的机械性质比由C2精制的Cl6，但是比那些低由合成精制。

简介：

简介：TheweldabilityofSiCw/6061Alwasinvestigated.Fromtheresultsofexperiments,itisfoundthatthestrengthofjointismainlyinfluencedbyweldingtemperature,andhighstrengthofjointisobtainedunderweldingtemperaturebetweenliquidusandsolidusofmatrixalloy.DiffusionweldingofSiCw/6061.Alwassuccessfullyrealizedwithappropriateweldingparameters.

简介：Al-pillaredinterlayeredmontmorillonite(Al-PILM)waspreparedusingtheartificialNa-montmorillonitefromtheQingfengshanbentonitemineasastartingmaterialmixedwithAl-pillaringsolutions.ThemicrostructureofthematerialswasstndiedbyanX-raypowderdiffractometerandaFouriertransforminfrared(FTIR)spectrometer.Theresultsindicatedthatthebasalspacing[d(001)value]ofthematerialswasincreasedsignificantlyto1.9194nmrelativetoNa-montmorillonite(1.2182nm).Aftercalcinedfor2hat300℃,thebasalspacingwasstabilizedat1.8394nmandthelayeredstructureofthematerialswasnotdestroyed.Thermalanalysiswasconductedbyathermalgravimetryanddifferentialthermalanalysis(TG-DTA)instrument,itshowedthatAl-PILMlostphysicallyadsorbedwaterbelow230.6℃andwaterformedbydehydroxylationofthepillarsataround497.1℃,withapeakofthephasetransformationat903.0℃.

简介：AdditionofAl-5Ti-1Balloytomoltenaluminumalloyscanrefineα-Algrainseffectivelyandtherebyimprovetheirstrengthandtoughness.TiAl3andTiB2inAl-5Ti-1Balloyarethemainsecondary-phaseparticlesforrefinement,whiletheunderstandingontheeffectoftheirsizesonα-Algrainrefinementcontinuestobefragmented.Therefore,Al-5Ti-1Balloyswithvarioussizesandmorphologiesofthesecondary-phaseparticleswerepreparedbyequalchannelangularpressing(ECAP).Evolutionofthesecondary-phaseparticlesduringECAPprocessandtheirimpactonα-AlgrainrefinementwerestudiedbyX-raydiffractionandscanningelectronmicroscope(SEM).ResultsshowthatduringtheECAPprocess,micro-cracksfirstlyappearedinsideTiAl3particlesandthengraduallyexpanded,whichresultedincontinuousrefinementofTiAl3particles.Inaddition,micro-distributionuniformityofTiB2particleswasimprovedduetotheimpingementofTiAl3particlestoTiB2clustersduringdeformation.ExcessivelylargesizesofTiAl3particleswouldreducethenumberofeffectiveheterogeneousnucleusandthusresultedinpoorgrainrefinementeffectiveness.Moreover,excessivelysmallTiAl3particleswouldreduceinhibitoryfactorsforgraingrowthQandweakengrainrefinementeffectiveness.Therefore,anoptimalsizerangeof18-22μmforTiAl3particleswassuggested.

简介：Al-3B中间合金是亚共晶Al-Si合金的高效细化剂之一。实验研究了Al-3B中间合金中未溶AlB2颗粒对Al-7Si合金晶粒细化的影响。结果表明,AlB2颗粒的数目和沉降对晶粒细化效果都有重要影响。在实验结果和理论分析基础上,提出了Al-3B中间合金对亚共晶Al-Si合金晶粒细化的新机制,认为通过共晶反应形成的＂Al-AlB2＂包覆结构是导致晶粒细化的直接原因,未溶的AlB2颗粒是α（Al）相的间接行核基底。

简介：BasedontheMiedemamodelandExtendedMiedematheory,theformationenergiesofdifferentsolutecomponentsinEr-XbinarysystemandAl-Er-Xternarysystemswerecalculated.TheresultsshowthatthevariationoferbiumcontenthaslittleinfluenceonthechancerateoftheformationAl-ErcompoundintheAl-Mg-Mn-Zr-Ersystem.ThecalculatedformationenergiesintheEr-XbinarysystemandAl-Er-XternarysystemsindicatethatAl3Erphasecantakepriorityofdepositing,Al-Er-Zrternarycompoundsmayalsofoundwhichagreeswiththeexperimentalresultsinreferences.TheconsistencyofcalculationandexperimentprovesthattheintermetalliccompoundsintheAl-Mg-Mn-Zr-ErsystemcanbepredicteddirectlybycalculatingtheformationenergiesofthereactionsinEr-XbinarysystemandAl-Er-XternarysystemswiththeMiedemamodelandExtendedMiedematheory.

简介：

简介：ThecorrelationbetweenphasestructuresandsurfaceacidityofAl2O3supportscalcinedatdifferenttemperaturesandthecatalyticperformanceofNi/Al2O3catalystsintheproductionofsyntheticnaturalgas(SNG)viaCOmethanationwassystematicallyinvestigated.Aseriesof10wt%NiO/Al2O3catalystswerepreparedbytheconventionalimpregnationmethod,andthephasestructuresandsurfaceacidityofAl2O3supportswereadjustedbycalciningthecommercialγ-Al2O3atdifferenttemperatures(600–1200C).COmethanationreactionwascarriedoutinthetemperaturerangeof300–600Catdifferentweighthourlyspacevelocities(WHSV=30000and120000mL·g-1h-1)andpressures(0.1and3.0MPa).ItwasfoundthathighcalcinationtemperaturenotonlyledtothegrowthinNiparticlesize,butalsoweakenedtheinteractionbetweenNinanoparticlesandAl2O3supportsduetotherapiddecreaseofthespecificsurfaceareaandacidityofAl2O3supports.Interestingly,NicatalystssupportedonAl2O3calcinedat1200C(Ni/Al2O3-1200)exhibitedthebestcatalyticactivityforCOmethanationunderdifferentreactionconditions.LifetimereactiontestsalsoindicatedthatNi/Al2O3-1200wasthemostactiveandstablecatalystcomparedwiththeotherthreecatalysts,whosesupportswerecalcinedatlowertemperatures(600,800and1000C).ThesefindingswouldthereforebehelpfultodevelopNi/Al2O3methanationcatalystforSNGproduction.