简介:在聚丙烯(PP)改进硅石的分散矩阵并且避免抗氧化剂的物理损失,有表面(SG-PAMAM)上的dendricpolyamidoamines的nanosilica被使用分叉的方法综合。然后使nanosilica不能调动的抗氧化剂(SG-PAMAM-AO)被从2,6-di-tert-butyl-4-phenol(AO)被导出的grafting2,6-di-tert-butyl-4-aminophenol准备。SG-PAMAM-AO被增加进PP由融化混合学习变老的性质。PP/SG-PAMAM-AO和PP/AO混合物的氧化正式就职时间被测量。SG-PAMAM-AO的抗氧化剂性质比AO的优异,这被发现。根据在相片热的老化前后的羰基吸收的变化,PP/SG-PAMAM-AO的相片热的氧化稳定性比PP,PP/SG-PAMAM和PP/AO的高得多。
简介:Anewmethacrylamidemonomer,hexylaminemethacrylamide(MAHA),wassynthesizedandusedinpolymerizations.ThehomopolymerofMAHAanditscopolymersweresynthesizedbyfreeradicalpolymerizationtechniqueswithN-isopropylacrylamide(NIPAAm)intwodifferentcompositions.Thequaternizationofthehomopolymerandcopolymerswerecarriedoutusing1-bromopropane.ThecopolymerswithNIPAAmandalowMAHAcontentshowedtemperature-responsivebehaviorinanaqueousenvironment.Thelowercriticalsolutiontemperatures(LCSTs)ofthesepolymersvariedbetween32℃and44℃.TheLCSTsofquaternizedcopolymerswerehigherthanthoseofneutralcopolymersbecausetheyweremorehydrophilic.TheobtainedhomopolymersandcopolymersweretestedforantibacterialactivitiesagainstS.aureusandE.coli.Thequaternizedwater-solublecopolymersshowedantibacterialactivitiesagainstS.aureus.Thequaternizationresultedinthesynthesisofbothantibacterialandtemperature-responsivecopolymers.
简介:Severalkindsofactivatedcarbonfiber(ACF),GranuleActivatedcarbon(AC)containingsilverionorfinesilverparticle(Ag-ACF/AC)havebeenpreparedbysoakingACForACinthesaltsolutionofsilver.Ag,AgClandAgIcompoundshavebeenloadedontothefibers:Thestuctureofthefiberswasmeasuredbyscanningelectronmicroscopy(SEM)andpowerX-raydiffraction(XRD),THeAgcontentinthefiberwasobtainedbyanAtomicabsorptionspectroscopy(AAS),TheAg^+contentinwateraftertheantibacterialtestwasmeasuredbyanInductivelyCoupledplasma(ICP)emissionspectroscopy.AntibacterialtestwascarriedoutagainstEscherichiacoli(E.coli)andStaphylococcusaureus(S.aureus).TheresultsshowthatAg-ACF/AChavestrongantibacterialactivityagainstE.ColiandS.aureus.AfterdealtwithACF/ACloadingAg,AgCl,AgI,noE.coliandS.aureusaliveinsolutioncanbedetected.TheanalysisofAgcontentinwaterafterantibacterialtestshowedthatthecontentofAgmeetthequalityrequirementoftheNationalPotableWaterStandrd,ItisindicatedthatACF/AC-Aginthisexperimentwouldbeasafeantibacterialagent.
简介:Polymersupportedalkyldimethylbenzylammoniumchlorideresindisinfectantusedforthedisinfectionofdrinkingwaterhasbeensynthesized,anditsantibacterialactivitieshavebeendetermined,comparedwiththecommerciallyusedtriiodinedisinfectantresin.Theresindisinfectantwasgeneratedsuccessfullywhenusethecombinationofsurfaceactiveagentsandultrosonic.
简介:ThispaperreportsthestudyonthepolymerprotectedcatalystCPVC-FeCl3usedinesterification,transesterification,synthesisofacetalsorketalsandrearrangementreactionofpinacol.Thecatalysthastheadvantagesofbeingsimpleinoperation,non-corrosive,easytoseparatefrommixturesandgoodreusability.
简介:Severalkindsofactivatedcarbonfibers,usingsisalfiberasprecursors,werepreparedwithsteamactivationorwithZnCl2activation.Zincoritscompoundsweredispersedinthem.Theantibacterialactivitiesoftheseactivatedcarbonfibersweredeterminedandcompared.TheresearchresultsshowedthatthesesisalbasedactivatedcarbonfiberssupportingzinchavestrongerantibacterialactivityagainstEscherichiacoliandS.aureus.Theantibacterialactivityisrelatedtotheprecursors,thepyrolysistemperature,andthezinccontent.Inaddition,smallquantityofsilversupportedonzinc-containingACFswillgreatlyenhancetheantibacterialactivityofACFs.
简介:SereralPd-SnO2/D3520andPd-PbO/D3520catalystswithPd/D3520,SnO2/D3520andPbO/D3520catalystsasreferencewerestudiedbymeansofIRandXPS.InteractionbetweenPdandthesecondmetalorbetweenmetalandsupportwasobserved.ResultsshowthatthereisastronginteractionbetweenPdandthesecondmetal,butthereisnotanobviousinteractionbetweenmetalandsupport.TheactiveconstituentisPd.HydrogenationactivityofthecatalystsisalteredbecauseoftheinteractionbetweenPdandthesecondmetal.TheactivityofthecatalysisforhydrogenationhasrelationtoouterlayervalenceelectrondensityofPd.
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简介:Asystematicstudyonthesynthesisandantibacterialactivityofthequaternary"onium"saltsgraftedonaninsoluble"gel-type"stryene-7%divinylbenzenecopolymerbypolymer-analogousreactionsisshowed.Antibacterialactivityofquaternaryammoniumand/orphosphoniumsaltsgraftedonpolymer-supportshasbeenstudiedagainststaphylococcusaureusandEscherichiacoli.Awidevarietyof"onium"saltsboundtomacromolecularsupportswithdifferentquaternarygroupsanddifferentquaternarychainlengthsubstituentswereexamined.Theantibacterialactivityofmixed"onium"saltsincreasesasaconsequenceoftheassociationofammoniumandphosphoniumsaltsgraftedonthesamepolymericsupport.