简介:Themetalorganicvaporphaseepitaxy(MOVPE)growthofindiumgalliumnitride(InGaN)hasbeendiscussedindetailtowardsthefabricationofsolarcell.TheInGaNfilmwithIncontentsupto0.4aresuccessfullygrownbycontrollingthefundamentalgrowthparameterssuchastheprecursorgasflowrates,temperatureetc.TheformationofmetallicInoriginatesfromthehighervalue(0.74)oftrimethylindium/(trimethylindium+triethylgallium)(TMI/(TMI+TEG))molarratiowithlow(4100)V/Ⅲweightmolarratiowhilethelowervalue(0.2)ofTMI/(TMI+TEG)causesthephaseseparation.Itisalsonecessarytocontrolthegrowthrateandepitaxialfilmthicknesstosuppressthephaseseparationinthematerial.ThecrystallinequalityofgrownfilmsisstudiedanditisfoundtobemarkedlydeterioratedwithincreasingIncontent.ThelatticeparametersaswellasthethermalexpansioncoefficientmismatchbetweenGaNtemplateandInGaNepi-layerareprimarilyconsideredasthereasonstodeterioratethefilmqualityforhigherIncontent.ByusingIn0.16Ga0.84Nfilms,ann+-phomo-junctionstructureisfabricatedon0.65mmGaNtemplate.Forsuchadevice,theresponsetothelightillumination(AM1.5)isobservedwithanop-ncircuitvoltageof1.4Vandtheshortcircuitcurrentdensityof0.25mA/cm2.Toimprovetheperformanceaswellasincreasesolarphotoncapturing,thedeviceisfurtherfabricatedonthickGaNtemplatewithhigherIncontent.TheIn0.25Ga0.75Nn+-pjunctionsolarcellisfoundbetterperformancewithanop-ncircuitvoltageof1.5Vandtheshortcircuitcurrentdensityof0.5mA/cm2.ThisistheInGaNp-nhomo-junctionsolarcellwiththehighestIncontenteverreportedbyMOVPE.
简介:Aone-pot,solvent-thermalprocesswasusedtocreatetheultrafineZnFe2O4nanoparticlesphotocatalyst.Duringthesolvent-thermalprocess,theinsituself-formingNaClnotonlyservedasa"cage"toconfinetheiondiffusion,butalsoactedasamicroreactorfornanocrystallitegrowth.Anaverageparticlesizeof~10nmandahigh-specificsurfaceareaof~112.9m2/gwereobservedfortheultrafineZnFe2O4nanoparticlesOwingtothesynergisticeffectofultrafineparticlesize,thefullutilizationofthevisiblelightregionandhighconductionband(CB)position,ultrafineZnFe2O4photocatalystdisplayedanefficientphotocatalyticCO2reductionundervisiblelightillumination.Besides,theultrafineZnFe2O4photocatalystshowedhighproductionselectivityforCH3CHOandC2H5OHgenerationinaqueousCO2/NaHCO3solution.Thisworkmayprovideanewideaforthesynthesisofnewhigh-efficiencyphotocatalysts.
简介:以Ti(OBu)4和内蒙古杭锦2^#土为主要原料,Sr(NO3)2为掺杂剂,采用溶胶-凝胶法制备了一系列Sr元素掺杂改性的TiO2/杭锦2^#土复合光催化剂,并用X射线衍射、傅立叶红外光谱和扫描电子显微镜等对样品进行了表征。紫外光照射下,以亚甲基蓝水溶液为光降解体系,考察了Sr的掺杂量和热处理温度对光降解率的影响,结果表明,Sr的掺杂量为0.5%,焙烧温度为500℃条件下制得复合物的催化活性明显优于相同条件下的TiO2/杭锦2^#土。该复合物催化剂的优点是易于从分散体系中分离和可循环使用。
简介:Energy-storageweldingconnectioncharacteristicsofrapidlysolidifiedAZ91DMgalloyribbonswith40~70μmthicknessareinvestigatedusingamicrotypeenergy-storageweldingmachine.Themicrostructureandperformanceoftheconnectionjointsareanalyzedandstudied.Theresearchresultsindicatethatenergy-storageweldingisabletorealizethespotweldingconnectionofAZ9lDMgalloyribbons.Theweldingnuggetconsistsofdevelopedα-Mgequiaxedgrainswiththesizesof1.2~2.7μmandintergranulardistributedβ-Mg17Al12compounds.Thethicknessofbondzoneisabout4μmandthesolidificationmicrostructureischaracterizedbythefineequiaxedgrainswiththesizesof0.8~1.2μm,andgrainboundaryhasbecomecoarsening.ThecolumnarcrystalinHAZalsobecomesslightlycoarseningandthegrainboundaryhasbroadened,however,thereisnoobviouschangeinitsprimitivemorphologyandcrystallographicdirection.Whenweldingenergyisabout2.0J,theweldingjointswithhighershearstrengthandsmallerelectricalresistivityareobtained.
简介:到改善AZ91D镁合金的bioactivity和腐蚀抵抗,有新奇microstructured形态学的hydroxyapatite(幸运)涂层经由一个灵巧的热水的方法在AZ91D底层上成功地被准备。不同chelating代理人包括polyaspartic酸(PASP)和ethylenediaminetetraacetic酸(EDTA)被介绍在形态学和腐蚀上调查他们的效果涂的镁的抵抗合金。结果表明准备与的涂层PASP是许多一致像顽童的microspheres镇静,当与EDTA准备的涂层由许多象花的粒子组成了时。而且,与EDTA准备的涂层的crystallinity比的高是大部分与PASP准备的涂层。电气化学的测试表明底层的腐蚀抵抗显著地在与每涂层是涂的以后被改进。在模仿的身体液体(SBF)的涂的样品的沉浸测试证明涂层能逐渐地是biodegraded并且导致钙磷酸盐粒子的形成。
简介:thermomechanically影响的地区(TMAZ)的微结构进化特征合金在磨擦期间促使处理(FSP)thixoformed(TF),AZ91D合金被调查。同时,合成的层增强了由的表面原文如此,粒子(SiCps)被FSP在合金上准备,相应tribological性质被检验。试验性的结果显示那动态再结晶和机械分离(包括切开和主要谷物的骨折)是为TMAZ的谷物精炼的主要机制。一致地分布式的SiCps增强的合成表面在合金上被准备。与没有合成表面,扔合金和TF合金的相应永久模子相比,有合成表面的TF合金有最高穿抵抗和最低磨擦系数。
简介:CeO2稳定了ZrO2极端好nanoparticles成功地经由简单、有效的大音阶的第五音胶化被综合由把zirconylchlorideoctahydrate,铈硝酸盐hexahydrate,和柠檬性的酸用作开始材料的合成途径。一系列技术包括X光检查衍射(XRD),thermogravimetry(TG),微分扫描热量测定(DSC),Fourier变换红外线的光谱学(FTIR),传播电子显微镜学(TEM),和N2-sorption分析,被用来描绘同样准备的样品的结构和形态学。XRD研究显示同样综合的样品具有CeO2的很好使结晶的四角形的阶段有高纯净的稳定的ZrO2。TEM图象证明同样综合的样品与一种平均尺寸由很多好散nanoparticles组成大约10nm。同样综合的四角形的CeO2稳定了ZrO2样品在不同温度被加热以便评估它的热稳定性。exprimental结果表明同样综合的四角形的CeO2稳定了ZrO2样品展览没有阶段转变的出现的优秀稳定性。
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