简介:OpticalabsorptionandemissionintensitiesofNd3+ioninKLu(WO4)2crystalwereinvestigated.BasedontheJudd-Offelttheory,wecalculatedthefollowingspectralparameters:phenomenologicalintensityparametersΩ2=5.567×10–20,Ω4=3.597×10–20,andΩ6=3.800×10–20cm2.Theradiativelifetimeoflevels4F3/2was182.58μs.Thefluorescencebranchingratioforthetransition4F3/2→4I11/2was46.98%.Inaddition,theradiativetransitionprobabilitiesAJ,J’,oscillatorstrengthsPJ,J’andthevaluesofinte...
简介:StudyonMorphologyofSurfaceofLargeAreaYBCOThinFilmsonZr(Y)O2SubstrateWangRuikun(王瑞坤),SunLihong(孙丽虹),LiuHongfei(刘鸿飞)WangXiaopi?..
简介:采用高温固相法合成尖晶石LiMn2O4,并以化学沉积方式对其进行包覆氧化钴的表面处理。通过X射线衍射(XRD)、扫描电镜(SEM)等技术对表面处理前后的LiMn2O4进行表征,分析了表面处理后LiMn2O4物理特性的变化,并结合电化学性能测试,研究了表面处理及其工艺和条件对LiMn2O4电化学容量与循环性能的影响。结果表明,表面处理后LiMn2O4循环性能显著提高。随氧化物含量的增加,循环性能提高,容量降低。未经表面包覆的LiMn2O4首次充放电容量为108.13mAh/g,50次循环充放电后容量衰减26.3%。500℃加热处理的表面包覆0.5%、2%氧化钴的LiMn2O4首次循环放电容量各为118.38mAh/g、115mAh/g,经过50次充放电循环后,容量分别降低8%、7%。
简介:DyPt2filmswerepreparedbyalternatedepositionthinDyandPtlayersonglasssubstratesbyDCmagnetocontrolledsputteringmethod.TheXRDdataindicatedthatforas-depositedDy/Ptfilms,andtheperiodiclayeredstructuresalongthicknessdirectionwereevidencedwithlowangleX-rayscattering.Withincreasingannealingtemperature,thecompoundsofDyPt,DyPt2andDyPt3wereformedsuccessivelyattemperaturerangingfrom300to400℃.ItwasfoundthatthecompositionreactionDyPt+DyPt3→2DyPt2tookplaceat500℃.Afterannealingat500℃for1h,thecompoundsDyPtandDyPt3transformedcompletelyintotheDyPt2compound.
简介:Forthegoalofsulfurrecovery,mostmethodsareaimedatthetailgaswithhigh-concentrationH2S,butfeweffectivemethodsareusedforlow-concentrationH2S.Inthiswork,Low-concentrationH2Scouldbepurifiedwellbyliquidphasecatalyticoxidation(LCO),andthesulfurresourcecouldalsoberecovered.TheabsorptionsolutionwaspreparedbyFeCl3andsulfosalicylicacid.Undertheexperimentalconditions,theconversionofH2StoScouldbemaintainedabove94%at60℃.InordertoenhancetheeconomicalefficiencyofLCOmethod,theabsorptionsolutionwasmodifiedbydopingCe,andaseriesofexperimentsweredesignedtoinvestigateitsperformance.TheresultsshowedthattheconversionofH2Shadnoobviousimprovement,butabove98%conversioncouldbegainedat60℃,andtheH2Sconversionratewasenhanced.TheoptimumadditionqualityofCe(NO3)3was0.08gto50mlFe3+solution.
简介:TheeffectsofUVAphotoirradiatedCe(Ⅳ)dopedTiO2nanoparticle(CDTP)onratcoloncarcinomacellline(C26)growth,cellcycledistribution,andmorphologywerestudiedbyMTTassay,FlowCytometry,andfluorescentstaining.Theresultsindicatethatabout64.6%cellsarekilledafter24hby180μg·ml-1CDTPwhen8minexposedtoUVA,over90%deadfor30mingroup,relativeto18.7%,41.5%ofTiO2atthesameconditionrespectively.Hoe33258stainingofthefixedcellsrevealstypicalapoptoticstructures(apoptoticbodies),andcellsarearrestedinG0/G1phase.
简介:ThemorphologyandcorrosionbehaviorofNi/Al2O3compositecoatingspreparedusingdouble-pulsedelectrodepositingtechniqueafteroxidizedunder800℃NaCldepositinairenvironmentwereanalyzedbyscanningelectricalmicroscope(SEM),X-raydiffraction(XRD)andenergydispersivespectrum(EDS).TheresultsshowedthatthecorrosionofallcompositecoatingswasacceleratedunderNaCldeposits,andthecorrosionproductswereratherporouswithpooradherencetothematrix.Al2O3particlesinthecoatingscanrefinethegrainsizeandimprovethehightemperaturecorrosionresistanceofthecoatings.Withinthetestscope,themoreAl2O3particlesinthecoatings,thelowercorrosionratescouldbeobtained,andthecorrosionmechanismwasalsodiscussed.
简介:SinglephaseofBa1-xMgAl10O17:xEu2+(0.02≤x≤0.14)phosphorswasfirstsuccessfullypreparedbyco-precipitationinaqueousmediumwitha'reversestrike'method,usingoxalicacidandammoniatogetherasprecipitants.Completelycrystallizedphosphorswereobtainedat1300℃,whichis300℃lowerthanthetemperatureofsolid-statereaction.TheirphotoluminescencewasinvestigatedunderUVandVUVregion,respectively.TheemissionspectraofBa1-xMgAl10O17:xEu2+samplesexcitedby254or147nmshowedacharacteristicwidebandwiththepeakcentredatabout450~454nm.Optimumemissionintensityreachedatx=0.1andthenconcentrationquenchingoccurred.Thesynthesizedphosphorshows10%higheremissionintensitythanthatpreparedbysolid-statereaction.