简介:为它的高氧化抵抗,钇硅酸盐是为在在1600°C上面的温度的carbon-fiber-reinforcedcomposites的保护的涂层的一个重要候选人。一个新奇方法,由一起沉淀组成,弄干水花,热处理和plasma-densification,被开发准备Y2SiO5粉末为热喷洒。作文,形态学和综合Y2SiO5粉末的流动能力被XRD,SEM和霍尔流量计分别地调查。结果证明综合Y2SiO5粉末与高纯净是将近球形的。分别地,Y2SiO5粉末的明显的密度和流动能力是1.87g/cm3和37s/50g它为大气的血浆喷洒导致多达80%的高免职效率。
简介:Thetransitionbetweenregularreflection(RR)andMachreflection(MR)oftypeVshock–shockinteractiononadouble-wedgegeometrywithhightemperaturenon-equilibriumeffectsisinvestigatedbyextendedshock-polarmethodandnumericalsimulation.First,thecriticalanglesoftransitionfromdetachmentcriterionandvonNeumanncriterionaredeterminedbytheextendedshock-polarmethodconsideringthenon-equilibriumeffects.Thenwavepatternsandthetransitionprocessarenumericallyobtained.Resultsofthecriticaltransitionanglesfromshock-polarcalculationandnumericalsimulationshowevidentdisagreement,indicatingtransitionmechanismbetweenRRandMRoftypeVinteractionischanged.Bycomparingwiththefrozencounterpart,itisalsofoundthatnon-equilibriumeffectsleadtoalargercriticalwedgeangleandalargerhysteresisinterval.
简介:TheRichtmyer–Meshkovinstabilityofa‘V'shapedair/heliumgaseousinterfacesubjectedtoaweakshockwaveisexperimentallystudied.Asoapfilmtechniqueisadoptedtocreatea‘V'shapedinterfacewithaccurateinitialconditions.Fivekindsof‘V'shapedinterfaceswithdifferentvertexanglesareformedtohighlighttheeffectsofinitialconditionsontheflowcharacteristics.Theresultsshowthataspikeisgeneratedaftertheshockimpact,andgrowsconstantlywithtime.Asthevertexangleincreases,vorticesgeneratedontheinterfacebecomelessnoticeable,andthespikedevelopslesspronouncedly.Thelineargrowthrateofinterfacewidthaftercompressionphaseisestimatedbyalinearmodelandarevisedlinearmodel,andthelatterisproventobemoreeffectivefortheinterfacewithhighinitialamplitudes.Thelineargrowthrateofinterfacewidthis,forthefirsttimeinaheavy/lightinterfaceconfiguration,foundtobeanon-monotonousfunctionoftheinitialperturbationamplitude–wavelengthratio.
简介:Inthisstudy,factorsaffectingthecrystalstructureofflame-synthesizedY2O3:Euparticleswereinves-tigated,especiallytheparticlesizeeffectanditsinteractionwithEudopingconcentration.PolydisperseY2O3:Eu(sizerange200nmto3m)powdersampleswithEudopingconcentrationsfrom2.5mol%to25mol%weregeneratedineitherH2/airorH2/O2substrate-freeflames.ThecrystalstructureofthepowdersampleswasdeterminedbypowderX-raydiffraction(XRD),whichwascomplementedbypho-toluminescence(PL)measurements.Singleparticlecrystalstructurewasdeterminedbysingleparticleselectedareaelectrondiffraction(SAED),andforthefirsttime,byelectronbackscatterdiffraction(EBSD).H2/airflamesresultedincubicphaseY2O3:Euparticleswithhollowmorphologyandirregularshapes.ParticlesfromH2/O2flameshaddenseandsphericalmorphology;sampleswithlowerEudopingconcen-trationshadmixedcubic/monoclinicphases;sampleswiththehighestEudopingconcentrationswerephase-puremonoclinic.ForsamplesgeneratedfromH2/O2flames,aparticlesizeeffectanditsinteractionwithEudopingconcentrationwerefound:particlessmallerthanacriticaldiameterhadthemonoclinicphase,andthiscriticaldiameterincreasedwithincreasingEudopingconcentration.Thesefindingssug-gestthattheformationofmonoclinicY2O3:Euisinevitablewhenextremelyhotsubstrate-freeflamesareused,becausetypicalflame-synthesizedY2O3:Euparticlesizesarewellbelowthecriticaldiameter.However,itmaybepossibletogenerateparticleswithdense,sphericalmorphologyandthedesiredcubicstructurebyusingamoderatelyhighflametemperaturethatenablesfastsinteringwithoutmeltingtheparticles.
简介:阴极材料李[CoxNiyMn1?x?y]为锂的O2第二等的电池被一条新线路作为一位先锋用分层的双氢氧化物(LDH)准备了。结果有-NaFeO2结构的分层的阶段在菱形的系统结晶,与有到0.47nm的夹层间距结束的空格组R-3m。X光检查光电子光谱学(XPS)被用来测量公司,Ni和Mn的氧化状态。在结构和李的电气化学的性质上改变Co/Ni/Mn比率的效果[CoxNiyMn1?x?y]O2被X光检查衍射和电气化学的测试调查了。产品表明了相当稳定的骑车行为,与为有Co/Ni/Mn=1/1/1的分层的材料的118mAh/g的一个可逆能力。
简介:TiO2@ZrO2@Y2O3:有coremultishell结构的Eu3+合成粒子通过layer-by-layer(LBL)的联合被综合自己组装方法和一个solgel过程。获得的样品与扫描电子被描绘显微镜学(SEM),传播电子显微镜学(TEM),X光检查光电子光谱学(XPS),X光检查衍射(XRD),和荧光spectrophotometry。结果证明合成粒子有coremultishell结构,球形的形态学,和狭窄的尺寸分布。TiO2核心上的ZrO2层的存在能有效地阻止在TiO2核心和Y2O3壳之间的反应;为在在TiO2@ZrO2@Y2O3的TiO2核心和Y2O3壳之间的反应的温度:Eucoremultishell黄磷能被300提高