简介:Inthiswork,webrieflydiscussanovelclassofmodifiedgravitylikef(T,TG)gravity.Inthisbackground,weassumethenewagegraphicversionofpilgrimdarkenergyandreconstructf(T,TG)modelsfortwospecificvaluesofs.Wealsodiscusstheequationofstateparameter,squaredspeedofsoundandwDE-wDEplaneforthesereconstructedf(T,TG)models.Theequationofstateparameterprovidesphantom-likebehavioroftheuniverse.ThewDE-wDEplanealsocorrespondstoΛCDMlimit,thawingandfreezingregionsforbothmodels.
简介:TheenergyresponsesofKaoftwotypesofcylindricalG-Mcountertubeswerecalculatedusinganelectron-photoncascadeMonteCarlocode,EGS4.OnetypeoftheG-McountertubeswasGJ4401(sensitivelength9cm,diameter1cm),theotherwasJ5(sensitivelength2cm,diameter0.3cm),therestrictedsamplingtechniqueofsourcephotonwasused.Goodtendencyagreementsbetweenthesimulationsandexperimentswereachievedforgammaradiationwithenergiesrangingfrom40keVto1.25MeV.ForGJ4401,thedifferenceofresponsebetweensimulationsandexperimentsat662keVwas34%andforJ5thedifferencewas27%.
简介:Thecreationandpropagationoflongitudinalacousticphonons(LAPs)inhighqualityhematitethinfilms(α-Fe2O3)epitaxiallygrownondifferentsubstrates(BaTiO3,SrTiO3,andLaAlO3)areinvestigatedusingthefemtosecondpump–probetechnique.Transientreflectionmeasurements(?R/R)indicatethephoto-excitedelectrondynamics,andtheinitialdecaylessthan1psandtheslowdecayof~500psareattributedtotheelectron-LOphononcouplingandelectron–holenonradiativerecombination,respectively.LAPsinα-Fe2O3filmcanbecreatedbyultrafastexcitationoftheligandfieldstate,suchastheligandfieldtransitionsunder800-nmexcitationaswellastheligandtometalcharge-transferwith400-nmexcitation.Thestrainmodulationsofthesoundvelocityandtheout-of-planeelasticpropertiesaredemonstratedinα-Fe2O3filmondifferentsubstrates.
简介:Two-dimensional(2D)graphitecarbonnitride(g-C3N4)nanosheetshavebeensuccessfullyusedasasaturableabsorber(SA)inapassivelyQ-switchedNd:LLFlaserat1.3μmforthefirsttime,tothebestofourknowledge.Underanincidentpumppowerof9.97W,theshortestpulsedurationof275nswasacquiredwithoutputpowerof0.96Wandpulserepetitionrateof154kHz,resultinginapulseenergyof6.2μJ.Inaddition,thesaturableabsorptionbehaviorsofzero-dimensional12nmg-C3N4nanoparticles(g-C3N4-NPs)andthree-dimensionalorderedmesoporousg-C3N4(mpg-C3N4)werealsoobserved,althoughtheirmorphologyandstructurewerequitedifferentfrom2Dg-C3N4.Theexperimentalresultsintroducethepotentialapplicationofg-C3N4nanomaterialsasSAsinQ-switchedlasers.
简介:Thesuppressionoftherecombinationofelectronsandholes(e–h)andtheenhancementofthelightabsorptionofsemiconductorsaretwokeypointstowardefficientphotocatalyticdegradation.Here,wereportafew-layerg-C3N4/α-MoO3nanoneedles(flg-C3N4/α-MoO3NNs)all-solid-stateZ-schememechanismphotocatalystsynthesizedviaatypicalhydrothermalmethodinacontrolledmanner.Therecombinationofthephoto-inducede–hpairscouldbeeffectivelyrestrainedbytheZ-schemepassagewaybetweentheflg-C3N4andα-MoO3NNsinthecomposite,whichcouldalsopromiseahighredoxabilitytodegradepollutants.Anditbecamepossibleforthepreparedphotocatalysttoabsorblightinawiderangeofwavelengths.Thedetailedmechanismwasstudiedbyelectronspin-resonancespectroscopy(ESR).Thelow-dimensionalnanostructureofthetwoconstituents(α-MoO3NNswithone-dimensionalstructureandflg-C3N4withtwo-dimensionalstructure)endowedthecompositewithvarietiesofexcellentphysicochemicalproperties,whichfacilitatedthetransferanddiffusionofthephotoelectronsandincreasedthespecificsurfaceareaandtheactivesites.The10wt%flg-C3N4/α-MoO3NNsshowedthebestphotocatalyticperformancetowardRhBdegradation,therateofwhichwas71.86%,~2.6timeshigherthanthatofα-MoO3NNs.
简介:QuantumdynamicscalculationsforthetitlereactionH(2S)+S2(X3-Σg)→SH(X2Π)+S(3P)areperformedbyusingagloballyaccuratedoublemany-bodyexpansionpotentialenergysurface[J.Phys.Chem.A1155274(2011)].TheChebyshevrealwavepacketpropagationmethodisemployedtoobtainthedynamicalinformation,suchasreactionprobability,initialstate-specifiedintegralcrosssection,andthermalrateconstant.Itisfoundnotonlythatthereisareactionthresholdnear0.7eVinbothreactionprobabilitiesandintegralcrosssectioncurves,butalsothatboththeprobabilityandcrosssectionincreasefirstlyandthendecreaseasthecollisionenergyincreases.Theexistenceoftheresonancestructureinboththeprobabilityandcrosssectioncurvesisascribedtothedeeppotentialwell.Thecalculationoftherateconstantrevealsthatthereactionoccurringonthepotentialenergysurfaceoftheground-stateHS2isslowtotakeplace.