简介:Thestudyofthetriplejunctionsofthegrainboundariesinsomefccsolidsolutions,orderedalloysandintermetallicswithL12hasbeencarriedoutusingtheopticalmetallographyandTEMmethods.Two-typesofthetriplejunctionswerefoundinthealloysinvestigated(1),consistingoftheboundariesoftherandom(RT),and(2),consistingoftheRTboundaryandthespecialboundaries(ST).TherelativevaluesoftheRTandSTboundaryenergyweredeterminedonthebasisofthemeasurementsoftheanglesbetweenthegrainboundaryplanes.IthasbeenshownthattheenergyofSTboundariesincreaseswiththeincreaseofthestackingfault(SF)energy.TheenergyoftheRTboundariesdoesnotdependontheSFenergy.
简介:ThecompositenanofibersofSrTiO3/SrFe12O19withamolarratioof1:1anddiameterabout120nmwerepreparedbyelectrospinning.Effectsofcalcinationtemperatureontheformation,crystallitesize,morphologyandmagneticpropertywerestudiedbyinfraredspectroscopy,X-raydiffraction,scanningelectronmicroscopyandvibratingsamplemagnetometer.Thebinaryphaseofstrontiumferriteandtitanatewasformedafterbeingcalcinedat900℃for2handthecompositenanofiberswerefabricatedfromnanograinsofSrTiO3about24nmandSrFe12O19around33nm.ThecrystallitesizesforthenanofibersincreasewithincreasingcalcinationtemperatureandtheadditionofSrTiO3hasanobvioussuppressioneffectonSrFe12O19graingrowth.Thespecificsaturationmagnetizationandremanencetendtoincreasewiththecrystallitesize.Withincreasingcalcinationtemperaturefrom900to1050℃,thecoercivityincreasesinitially,achievingamaximumvalueof520.2kA·m-1at950℃,andthenshowsareductiontendency.
简介:在在precartilaginous干细胞(PSC)的区别上包含TGF-3基因进chondrocytes的KLD-12自我装配的肽nanofiber支架的文化的效果被学习。KLD-12被综合由固态方法。在TGF-3plasmid被装进KLD-12自我装配的肽nanofiber支架以后,DNA版本能力被调查。PSC和hTGF-3基因被装进KLD-123-D支架,并且MTT试金被执行调查房间增长,和ELASA试金被用来调查TGF-3的表示。特定的软骨矩阵被染色的量的即时PCR,immunohistochemistry和Alcian蓝色检验。与控制组相比,PSC的DNA合成水平在PSC在装载TGF-3plasmid的自我装配的肽nanofiber支架是有教养的3天以内到达了山峰,并且在2个星期以内维持了这高水平。MTT结果证明试验性的组的增长能力在控制组比那统计上高(P<0.05)。量的实时PCR建议在试验性的组的TGF-3积极PSC的百分比在控制组比那高(P<0.01)。ELISA试金证明TGF-3蛋白质水平在试验性的组PSC的上层清液增加了,在72h以后到达了山峰然后有点衰退了到高原阶段。与控制组相比,chondrocyte的特定的基因典型细胞外的矩阵显著地起来调整(P<0.01)。结果显示出在装载TGF-3plasmid的自我装配的肽nanofiber支架区分进chondrocytes的那PSC,它提供了一条新鲜途径给软骨织物工程。
简介:Nd_2Zr_2O_7isbeingexploredasanalternatethermalbarriercoating(TBC)materialforoperatingabove1300°C,andgreatefforthasbeenmadetoenlargeitsthermalexpansioncoefficient(TEC)andimproveitstoughness.Inthisstudy,Sc_2O_3wasdopedtoNd_2Zr_2O_7.Thephasestructure,TECsandtoughnessof((Nd_(1-x)Scx))_2Zr_2_O7(x=0,0.025,0.05,0.075,0.1)compoundswereinvestigated.((Nd_(1-x)Scx))_2Zr_2_O7(x=0,0.025,0.05,0.075)exhibitedpyrochlorestructure,while((Nd_(0.9)Sc_(0.1)))_2Zr_2O_7consistedofpyrochloreandfluoritephases.WiththeincreaseoftheSc_2O_3content,theorderingdegreeofthepyrochloreinthecompoundsdecreased.In((Nd_(1-x)Scx))_2Zr_2O_7series,((Nd_(0.925)Sc_(0.075)))_2Zr_2O_7exhibitedthelargestTEC,whilethetoughnessofthecompoundsincreasedwithincreasingtheSc_2O_3content.Therelatedmechanismswerediscussedbasedonthecrystalstructureanalysis.ConsideringtheTECandtoughness,10mol%Sc_2O_3wassuggestedastheoptimaldopingcontentforNd_2Zr_2O_7ceramic.
简介:Withpositronannihilationradiationonedimensionangular-correlationdevice,itismeasuredthatpositronannihilationradiationonedimensionangular-correlationcurvesofpolycrystalsodiumionconductorNa5Y1-xCrxSi4O12(NYCS)system.Afterelectronmomentumdistributioncurvesarenormalized,linearparametersarecalculated.TheparametersH,WandSshowthechangeofNa+ionvacancyconcentrationinNYCSseriessamples.TheresultsshowthatparametersH,WandSofonedimensionangular-correlationcurvesofthosesamplesvarygreatlywithCr2O3contents.WithCr2O3contentincreasing,HandSparametersincrease,butWdecreases,andreachesextremesatx=0.05;thenwithCr203addingcontinually,parametersHandSdecreasegradually,parameterWincreasesgradually.Thisshowsthat,inaddtiontoCr2O3,theconductivityhascloserelation
简介:Er^3+-dopedSrBi4Ti4O15-Bi4Ti3O12(SBT-BIT-xEr^3+,x=0.00,0.05,0.10,0.15and0.20)inter-growthceramicsweresynthesizedbythesolid-statereactionmethod.Structural,electricalandup-conversionpropertiesofSBT-BIT-xEr^3+wereinvestigated.Allsamplesshowedasinglephaseoftheorthorhombicstructure.RamanspectroscopyindicatedthattheEr^3+substitutionforBi^3+atAsitesofthepseudo-perovskitelayerincreasesthelatticedistortionofSBT-BIT-xEr^3+ceramics.ThesubstitutionofBi^3+byEr^3+leadstoadecreaseofdielectriclosstanδandanincreaseofconductivityactivationenergy.Piezoelectricconstantd33wasslightlyimproved,butdielectricconstantwasdecreasedwiththeEr^3+doping.TheSBT-BIT-xEr^3+ceramicwithx=0.15exhibitstheoptimizedelectricalbehavior(d33~17pC/N,tanδ~0.83%).Moreover,twobrightgreen(532and548nm)andonered(670nm)emissionbandswereobservedunderthe980nmexcitation.Optimizedemissionintensitywasalsoobtainedwhenx=0.15fortheSBT-BIT-xEr^3+ceramic.Therefore,thiskindofceramicsoughttobepromisingcandidatesformultifunctionaloptoelectronicapplications.