简介:Thenumericalmodellingoftheinteractionsbetweenwaterwavesandfloatingstructuresissignificantfordifferentareasofthemarinesector,especiallyseakeepingandpredictionofwave-inducedloads.SeakeepinganalysisinvolvingsevereflowfluctuationsisstillquitechallengingevenfortheconventionalRANSmethod.Particlemethodhasbeenviewedasalternativeforsuchanalysisespeciallythoseinvolvingdeformableboundary,wavebreakingandfluidfragmentationaroundhullshapes.Inthispaper,theweaklycompressiblesmoothedparticlehydrodynamics(WCSPH),afullyLagrangianparticlemethod,isappliedtosimulatethesymmetricradiationproblemforastationarybargetreatedasaflexiblebody.Thisiscarriedoutbyimposingprescribedforcedsimpleharmonicoscillationsinheave,pitchandthetwo-andthree-nodedistortionmodes.Theresultant,radiationforcepredictions,namelyaddedmassandfluiddampingcoefficients,arecomparedwithresultsfrom3-Dpotentialflowboundaryelementmethodand3-DRANSCFDpredictions,inordertoverifytheadoptedmodellingtechniquesforWCSPH.WCSPHwerefoundtobeinagreementwithmostresultsandcouldpredictthefluidactionsequallywellinmostcases.
简介:应用密度泛函理论中的ω-B97XD/6-311+G(d,p)方法,对甲湛分子团簇[CH2O]n(n=1~4)的空间结构进行了优化,得到了这些团簇的基态结构,并对其红外光谱,核磁共振谱的性质进行了研究.结果表明,当甲醛分子构成稳定的多分子团簇时,团簇中的每个分子仍然为平面结构,分子间将形成氢键,并且团簇中的各个分子共面.与单分子甲醛相比,多分子团簇的红外光谱,会出现许多与分子间氢键振动有关的新的吸收峰.当甲醛分子形成团簇时,13C核和17O核的核磁共振谱线会发生劈裂现象,这与电荷分布的对称性的破缺有关;而1H的核磁共振谱中将会出现新的条纹,这是由分子间的氢键的形成引起的.本文的研究可为甲醛团簇的识别、检测及性质研究提供理论依据.