摘要
Asymmetrichydrisilylationcatalyzedbypolymericthiazolidinerhodiumcatalystswasconducted.Almostthesameopticalyieldshavebeenobtainedwhencomb-shapedpolymericligandsandtheircorrespondingmonomercomplexedrhodiumcataltystswereusedtoasymmetrichydrosilylationofacetophenone.Opticalyieldofchiral1-methylbenzylalcoholreachesashighas71.5%.Temperaturedependenceofenantioselectivehydrosilylationofacetophenonewasdiscussed.
出版日期
1999年01月11日(中国期刊网平台首次上网日期,不代表论文的发表时间)