EFFECT OF 2—HYDROXYETHYL METHACRYLATE ON SEMIBATCH EMULSIFIER—FREE EMULSION COPOLYMERIZATION OF METHYL METHACRYLATE AND BUTYL ACRYLATE-中国期刊网

摘要 Thesemibatchemulsifier-freeemulsioncopolymerizationofmethylmethacrylate(MMA)andbutylacrylate(BA)inthepresenceof2-hydroxyethylmethacrylate(HEMA)initiatedbyK2S2O8(PSP)wasstudied.Thelatexparticlescanmaintainanappreciablestabilityduringtheemulsifier-freeemulsioncopolymerizationofMMAandBAinthepresenceofHEMA.Theaverageparticlediameterincreasewithanincreaseoftotalsolidscontent,HEMAcontent,PSPcontent,ionicstrengthofthesystemandmonomerfeedrate,anddecreasewiththemonomerfeedrationfrom3/1(MMA/BA:molarration).to1/3.ThestabilityofthisreactionsystemisimprovedbyaddingHEMAasnonioniccomonomer,Highsolidscontent(50%)latexwithmonodisperseparticlecanbeobtainedusingthisprocess.

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EFFECT OF 2—HYDROXYETHYL METHACRYLATE ON SEMIBATCH EMULSIFIER—FREE EMULSION COPOLYMERIZATION OF METHYL METHACRYLATE AND BUTYL ACRYLATE

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EFFECT OF 2—HYDROXYETHYL METHACRYLATE ON SEMIBATCH EMULSIFIER—FREE EMULSION COPOLYMERIZATION OF METHYL METHACRYLATE AND BUTYL ACRYLATE

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