摘要
Awater-compatiblephenolichydroxylmodifiedpolystyreneadsorbent(AM-1)foradsorbingandremovingphenoliccompoundsfromaqueoussolutionswaspreparedbycovalentbondingofphenolichydroxylgroupstothesurfaceofporouspolystyrene-divinylbenzenebeads,thisresincanbeuseddirectlywithoutwettingprocess.AcomparisonofthesorptionproperitesofthenewresinandAmberliteXAD-4towardfourphenoliccompounds,phenol,p-cresol,p-chlorophenol,andp-nitrophenolwasmade.ThecapacitiesofequilibriumadsorptionofAM-1forallfourphenoliccompoundsincreasedaround20%overthatofAmberliteXAD-4,whichmaybecontributedtopheonlhydroxylgrouponthesurfaceandtheunusualpoedistribution.Attheirdilutesolution,theequilibriumadsorptioncapacitiesofAM-1forphenolincreasedaout62%overthatofAmberliteXAD-4,whileequilibriumadsorptioncapacitiesoftheotherthreephenoliccompoundsincreased4-35%,suggestinganadvantageofAM-1overAmberliteXAD-4inthecollectionofphenol.FreundlichisothermequationsandisostericadsorptionenthalpiesforthefourphenoliccompundsindicateaphysicaladsorptionprocessontheAmberliteXAD-4andAM-1resins,ColumnstudiesforphenolshowthatAM-1resinhasexcellentadsorptionanddesorptionperformance.
出版日期
2001年02月12日（中国期刊网平台首次上网日期，不代表论文的发表时间）
