Microstructure and Raman spectra of Ag—MgF2 cermet films

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摘要 Ag-MgF2cermetfilmswithdifferentAgfractionswerepreparedbyvacuumevaporation.Themicrostruc-tureofthefilmswasexaminedbyRamanscatteringtechnique.Thesurface-enhancedRamanspectrumforMgF2moleculesinthecermetfilmstronglysuggeststheexistenceofAgnanoparticlesdispersedinMgF2matrix.TheintensitiesoftheRamanspectraofAg-MgF2cermetfilmsincreasewithAgfraction.TheenhancementofRamanscatteringdisappearswhenAgcontentreacheswt.20%.TheanalyseswiththetransmissionelectronmicroscopyshowedthatAg-MgF2cermetfilmsaremainlycomposedofamor-phousMgF2matrixwithembeddedfaced-center-cubicAgnanoparticles.Itsuggeststhatthepercolationthresholdshouldbearoundwt.20%ofAgcontent.
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出版日期 2003年05月15日(中国期刊网平台首次上网日期,不代表论文的发表时间)