Calculating models of mass action concentrations for structural units or ion couples in RbC1-H2O binary system and RbC1-RbNO3-H2O ternary system-中国期刊网

摘要 ThermodynamicmodelsofcalculatingmassactionconcentrationsforstructuralunitsorioncouplesinRbCl-H2ObinaryandRbCl-RbNO3-H2Oternarystrongelectrolyteaqueoussolutionsweredevelopedbasedontheionandmoleculecoexistencetheoryat298.15K.Atransformationcoefficientisneededtocomparethecalculatedmassactionconcentrationandthereportedactivitybecausetheyareobtainedatdifferentstandardstatesandconcentrationunits.TheresultsshowthatthetransformationcoefficientsbetweenthecalculatedmassactionconcentrationsandthereportedactivitiesofthesamestructuralunitsorioncouplesinRbCl-H2ObinaryandRbCl-RbNO3-H2Oternarystrongelectrolyteaqueoussolutionschangeinaverynarrowrange.ThetransformedmassactionconcentrationsofstructuralunitsorioncouplesinRbCl-H2Obinarysystemareingoodagreementwiththereportedactivities.ThetransformedmassactionconcentrationsofRbClandRbNO3inRbCl-RbNO3-H2Oternarysolutionarealsoingoodagreementwiththereportedactivities,aRbCland3RbNOa,withdifferenttotalionicstrengthsas0.01,0.05,0.1,0.5,1.0,1.5,2.0,3.0and3.5mol/kg,respectively.AllthoseresultsmeanthedevelopedthermodynamicmodelofstrongelectrolyteaqueoussolutionscanreflectstructuralcharacteristicsofRbCl-H2ObinaryandRbCl-RbNO3-H2Oternarystrongelectrolyteaqueoussolutionsandthemassactionconcentrationalsostrictlyfollowsthemassactionlaw.

1石恒真;单永奎;何鸣元;刘煜炎;翁林红. Synthesis and Structure of the First Protonated Zincoborophosphate：（ H3O ） Zn（ H2O ） 2BP2O8·H2O.化学,2003-09.
2王明召;王淑贤;蔡冠梁. Photophysical Property of Ternary Complex Eu（DPHA）3·Phen·2H2O.有色金属冶金,2001-03.
3胡道道;苏东琴;崔亚丽;房喻;唐宗薰. Studies on the Phase Equilibrium of the System C6H12O6-（NH4）2SO4-C2H5OH-H2O（C2H5OH/H2O=0.90 by wt）at 35℃.药学,1998-04.
4ZHANG Xin;YOU Wan-sheng;ZHU Zai-ming;DANG Li-qin;SUN Zhen-gang;ZHENG Xue-fang. Syntheses, Crystal Structures and Characterization of Two Zeotype Crystals of K4[Cr30（H2O） 3（OOCH） 6] 2[ P2W18O62]· 9.5H2 O and K4[ Cr3O（ H2O）3（ OOCH）6 ]2[ H3 P2 W17Co（H2O） O61]· 20H2O.化学,2007-01.
5WANGJun ZHANGXiang-dong JIAWei-guo LIHui-fang. Syntheses and Structural Researches of Yb^3＋ Complexes with Nitrilotriacetic Acids—Nine—coordinate K3[Yb（nta）2（H2O）]·5H2O and Eight—coordinate Na3[Yb（nta）2]·6H2O complexes.化学,2003-02.
6何水样;杨锐;武望婷;史启祯;王大奇;安德荣. Crystal Structure and Bioactivity of Complex [Gd（C10H9N2O4）（C10H8N2O4）（H2O）3]2·phen·4H2O.化学,2005-09.
7TAOZuyi ZHOUHaimei 等. BINARY AND TERNARY ION EXCHANGE KINETICS SO4^2——Cl^——NO3^——201×7SYSTEM.高分子化学,1993-01.
8REN Dong-xue CAO Yun-zhu CHEN Chen XING Yong-heng. Vanadium Haloperoxidases Model Compounds： Synthesis, Structural Characterization and Mimic Catalytic Bromination Activity of [VO（C_2O_4）（2,2′-bipy）（H_2O）]·C_2H_5OH and VO（C_2O_4）（phen）（H_2O）.化学,2012-05.
9刘志宏;高世扬;胡满成;夏树屏. Synthesis and Thermodynamic Properties of MgO·B2O3·4H2O.化学,2002-12.
10孙道峰;毕文华;曹荣;李星;时茜;洪茂椿. Hydrothermal Synthesis and Structure of a New 3D Lanthanide—Carboxylate Framework,[La（btec）1／2（H2btec）1／2（H2O）]n（H4btec=1,2,4,5—Benzeneteracarboxylic acid）.化学,2003-04.

Calculating models of mass action concentrations for structural units or ion couples in RbC1-H2O binary system and RbC1-RbNO3-H2O ternary system

来源期刊

相关推荐

同分类资源更多

相关关键词

Calculating models of mass action concentrations for structural units or ion couples in RbC1-H2O binary system and RbC1-RbNO3-H2O ternary system

来源期刊

相关推荐

同分类资源 更多

相关关键词

同分类资源更多