Boron metallurgy of advanced ferritic power plant steels and welded joints

(整期优先)网络出版时间:2010-06-10
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Thispaperdescribesthealloydesignphilosophyfortheimprovementoflong-termcreepstrengthoftemperedmartensitic9Crsteel,includingweldedjoints.Thecreeplifetrisinverselyproportionaltotheminimumcreeprateεmintimestheincreaseincreepratebystraindlnε/dεintheaccelerationregionastr=1.5/[(εmin)(dlnε/dε)].Theparametersεminanddlnε/dεarecloselycorrelatedwiththetimetominimumcreepratetmandthestraintominimumcreeprateεm,whichcharacterizethecreepdeformationbehaviorinthetransientregion.Theboundaryandsub-boundaryhardeningisshowntobethemostimportantstrengtheningmechanismincreepof9Crsteelandisenhancedbyfinedispersionsofprecipitatesalongboundaries.TheadditionofboronreducesthecoarseningrateofM23C6carbidesalongboundariesnearprioraustenitegrainboundariesduringcreep.Theenhancementofboundaryandsub-boundaryhardeningincreasesthetmanddecreasestheεmin,whichimprovesthecreeplife.Theboundaryandsub-boundaryhardeningissignificantlyreducedinfine-grainedregionofheataffected-zone(HAZ)ofconventionalsteelP92weldedjoints,promotingTypeⅣfracture.InNIMS9Crboronsteelweldedjoints,thedistributionofcarbonitridesalongboundariesaresubstantiallythesamebetweentheHAZandbasemetal,suppressingtheTypeⅣfracture.