Fibrestressofglassfibrereinforcedpolymericcopmositesonloadisdeterminedbyusingopticalfibreasmodelfiberandbymeansoflaserinterferencemethod.Inaddition,theoriginationoffibrestressduringmouldingprocessofcompositesandtherelationbetweenfiberstressofloadedcompositesandexternalstressareexamined.Theexperimentsshowthatfibrestressisrelatedtomolecularstructureofinterfacialmaterialsandstructureofinterfaciallayers.Whenstressistransferredfrommatrixtofibre,eachinterfaciallayerhasdifferentstressgradientanddeformability.Thispropertycanbecharacterizedbyintroducinganinterfacialstresstransfercoefficientktothetwo-phasemodel.