MoleculardynamicssimulationwascarriedouttoinvestigatetheliquidandamorphousmicrostructuresofbinaryAgx-Rh(100-x)(x=25,50,75inatomfraction)alloys.SegregationfeatureofhomogeneousinteratomicbindingofAg-Rhliquidwasfoundandprobed,whichcanberetainedintoamorphoussolidsuponrapidcooling.Homogeneousbindingmayoccurwhenthedifferenceintheelementalatomicsizesislessthan10%.Theicosahedrainliquidbeforetheformationofamorphousstateexistinastablestateandthenetworkformedby1551-clustersinmoltenalloyswouldinhibitthecrystallizationanddiffusionofatoms.Ahigherdegreeof1551-clusterswillbefavorabletoformmetallicglasses.
