Diffusion-Controlled Adsorption Kinetics of T dton X-100 at Air/Solution Interface

(整期优先)网络出版时间:2004-03-13
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Inthispaper,theequilibriumsurfacetensionandthedynamicsurfacetensionofaqueousTritonX100solutionattemperature25℃weremeasuredbymeansofWilhelmyplatemethodandmaximalbubblepressuremethodrespectively.Thedeterminedcriticalmicellarconcentration(cmc)ofTritonX-100at25℃is2.2×10^-4mol/dm^3.TheadsorptionmechanicsofTritonX-100atair/solutionwasdetermined.Forthesubmicellarconcentrationsitisdiffusion-controlled.Thediffusioncoefficientwascalculatedfromtheexperimentaldataintherangeofshortlimit.Intherangeoflongtimeadsorption,thesubsurfaceconcentrationisfittedfromthemeasureddynamicsurfacetensions.