Inthispaper,theequilibriumsurfacetensionandthedynamicsurfacetensionofaqueousTritonX100solutionattemperature25℃weremeasuredbymeansofWilhelmyplatemethodandmaximalbubblepressuremethodrespectively.Thedeterminedcriticalmicellarconcentration(cmc)ofTritonX-100at25℃is2.2×10^-4mol/dm^3.TheadsorptionmechanicsofTritonX-100atair/solutionwasdetermined.Forthesubmicellarconcentrationsitisdiffusion-controlled.Thediffusioncoefficientwascalculatedfromtheexperimentaldataintherangeofshortlimit.Intherangeoflongtimeadsorption,thesubsurfaceconcentrationisfittedfromthemeasureddynamicsurfacetensions.