Defects of Polymer-derived Si-C-O Fibers and Their Originations

(整期优先)网络出版时间:2004-01-11
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Defectsofpolymer-derivedSi-C-OfiberswereintensivelystudiedbytheSEMandTEMtechniquesandtheiroriginationswerealsodiscussedonthebasisoffactorsexperiments.Thedefectswerefoundmainlyintheformofstrumaes,pitsandsplitsonsurfacesaswellasmicroflawnetworks,porosityclustersandinclusionsinthebulk.Factorsexperimentsrevealthatanonuniformoraninsufficientcuringwouldresultinlarger-sizedstru-maesorinteriormicroflaws.Gasevolutionratesduetodifferentfiringrateshaveagreatinfluenceontheformationofinternalmicrofiawsorporosityclustersandsomeoxidation-inducedpitsorsplitsmaybeformedonsurfacesbe-causeoratraceofoxygenorwatervaporaccumulatedfromtheflowinginertatmosphereduringpyrolysis.