Synthesis and characteristics of SiC whiskers with "rosary bead" morphology

(整期优先)网络出版时间:2004-01-11
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SiCwhiskerswith'rosarybead'morphologyweresynthesizedusingsuitablesiliconsourceandcarbonsourcethroughsolidreactionatthetemperatureabove1537K.ThediameterandlengthoftheSiCwhiskerswereabout0.1-1.0μmand20-100μm,respectively.Thelargestdiameteroftheirenlargedendsofthewhiskerswasabout0.2-1.0μm,anditgraduallyandsmoothlydecreasedtothesizeoftheplainpartofthewhiskers.TheresultsofX-raydiffractionanalysisshowthatthecrystallinestructureoftheobtainedSiCwhiskersisβ-SiC.ItisconsideredthattheSiCwhiskersgrowviaavapor-solidmechanism.