Luminescentcoordinationcompoundswithnitrogen-containingligandshaveattractedmuchattentionduetotheirgoodperformanceinsensorandelectroluminescentdevicetechniques[1-17].Todevelopnewluminescentmaterials,alargenumberofd10metalcomplexes,especiallyzinccomplexes,withthenitrogen-containingligandshavebeensynthesizedandtheirluminescencebehaviourhavebeenstudied[1-11].Ithasbeenfoundthatforagivencomplex,thesizeoftheπ-conjugatedsystemoftheligandandtheelectroniceffectofsubstituentsattheligandareimportantfactorsformodulatingitsluminescentproperties[5,8,9].