PHASE STRUCTURE OF W-DOPED NANO-TiO2 PRODUCED BY SOL-GEL METHOD

(整期优先)网络出版时间:2005-04-14
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WithTi(OBu)4asprecursor,andHAcascomplexingagent,pureandW-dopedTiO2gelatinswerepreparedbyasol-gelmethod.Duringtheprocessofgelformation,metalionsweredispersedintheporousTiO2matrix.Then,powdersofnano-TiO2andW-dopednano-TiO2werepreparedbydrying,grindingandheattreatmentatdifferenttemperatures.Thegrainsizeandstructureofthesamples,pureTiO2andW-doped,andtreatedatdifferenttemperatures,werestudiedbyX-raydiffraction(XRD),BeckmanCoulterSorptionAnalysisandTEM.Resultsshowedthat,withincreasingtemperature,theTiO2transformedfromanatasetorutileandthegrainsizeincreased.ThistransformationandgraingrowthofTiO2couldberetardedbydopingwithW.