Organic Composition of Sulphide Ores in the Okinawa Trough and Its Implications

(整期优先)网络出版时间:2001-02-12
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ApreliminaryorganicgeochemicalstudyshowsthatthesulphideoresfromthehydrothermaldepositoftheOkinawaTrougharegenerallylowinthetotalorganiccarbonandextremelylowinthesolubleorganicmatter.Inthealiphatichydrocarbonfraction,then-alkanesrangefromC15toC35,withusualmaximainthemiddlen-C20regionandstrongodd-carbonnumberpredominancewhenn>C25(CPI=1.2).Thedominantanaloginthearomaticfractionisphenanthrene,apolynucleararomatichydrocarbon,whichprovidesevidenceforhydrothermalactivity.Theorganicmatterderivedmainlyfrommarineplanktonicandterrigenousvascularplantsisentrappedinahigh-temperatureregimesuchasanactivechimneyandcooledquicklyinthesulphideoresontheseafloor.Organicmatterandsulphidesaredefinitelyproductsofahigh-temperaturealteration.ThebiomarkercompoundsindicatethattheoresareformedunderlowEhandpHconditions梐reducingtoanoxicenvironment,whichisfavourableforsulphatestobereducedintosulphidesbybiogenic(bacterial)orabiogenicactivity.