简介：Perovskite-typeLa1-xCexMnO3（x=0-10%）catalystswerepreparedbyflamespraypyrolysisandtheiractivitiesduringthecatalyticoxidationofbenzenewereexaminedoverthetemperaturerangeof100-450℃.ThestructuralpropertiesandreducibilityofthesematerialswerealsocharacterizedbyX-raydiffraction（XRD）,N2adsorption/desorption,H2temperature-programmedreduction（H2-TPR）andX-rayphotoelectronspectroscopy（XPS）.TheincorporationofCewasfoundtoimprovethebenzeneoxidationactivity,andtheperovskiteinwhichxwas0.1exhibitedthehighestactivity.Phasecompositionandsurfaceelementalanalysesindicatedthatnon-stoichiometriccompoundswerepresent.TheincorporationofCehadanegligibleeffectonthespecificsurfaceareaoftheperovskitesandhencethisfactorhaslittleimpactonthecatalyticactivity.IntroductionofCe44+resultedinmodificationofthechemicalstatesofbothB-siteionsandoxygenspeciesandfacilitatedthereducibilityoftheperovskite.ThesurfaceMn4+/Mn3+ratiowasincreasedasaresultofCe4+substitution,whileadecreaseinthesurface-adsorbedO/latticeO(Oads/Olatt)ratiowasobserved.Therelationshipbetweenthesurfaceelementalratiosandcatalyticactivitywasestablishedtoallowabetterunderstandingoftheprocessbywhichbenzeneisoxidizedoverperovskites.

简介：针对惯导平台连续翻滚自标定中安装误差标定精度不高这一现状,提出了一种解决方案。通过对惯性器件的输出误差模型和安装误差的分析,建立了系统的姿态动力学方程和观测方程,利用输出灵敏度理论分析了系统的可观性,指出加速度计安装误差可观性较差是影响标定精度的主要原因。利用Kalman滤波中的估值方差矩阵计算了安装误差之间的相关系数,计算结果表明可观性差是由安装误差之间的线性相关性造成的,并确定了具体的不可观参数。以加速度计输入轴为基准建立平台坐标系可以减少安装误差项,使所有的安装误差的变得可观。最后的仿真结果表明在新的方案下,安装误差的估值偏差小于5＂,标定精度得到了显著提高。