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500 个结果
  • 简介:推导了考虑爆炸产物发生化学反应时,约束空间内准静态压力的计算公式.以TNT炸药发生约束爆炸为例,分析了不同药量体积比下爆炸产物的化学反应动力学过程.编写了计算TNT炸药约束爆炸后准静态压力的程序,将程序计算结果与实验测量结果和ConWep程序计算结果进行对比,验证了计算方法的准确性,证明了爆炸产物发生化学反应对约束爆炸准静态压力有重要的影响.考虑爆炸产物发生化学反应对压力的影响,利用LS-DYNA对TNT炸药在一长方体药室内的爆炸进行了数值模拟,模拟结果表明,考虑爆炸产物发生化学反应时,药室会出现局部塑性应变与应力集中现象,最大塑性应变达到0.8‰.

  • 标签: 约束爆炸 化学反应 准静态压力 TNT炸药 药量体积比 LS-DYNA
  • 简介:制备了几种CU-CO尖晶石,并用于催化CO2加氢合成碳醇反应。结果表明,Cu-Co尖晶石是一种极具潜力的催化剂前驱体,具有出色的C2+醇合成能力。但是,当在该催化剂中加入KOH时,这种能力下降。XRD表征表明,KOH的加入破坏了CU-Co合金的生成。一些结果被讨论。更多还原

  • 标签: Cu-Co催化剂 CO2加氢 低碳醇合成
  • 简介:絮凝微滤组合(简称CMF工艺)是我所开发出的含锕系元素废水处理优良工艺,并对^241Am,^238U,^235U,^239Pu废水处理中得到应用。同时开展了膜分离技术处理含裂变核素废水的实验研究。在上述研究成果及已建立的固定装置基础上,研发小型化可移动式放射性废水处理装置。可移动式废水处理系统可对含^238U,^239Pu,^241Am放废水及含裂片核素(主要为^90Sr、^137Cs)放废水(放射性总活度小于4×10^4Bq/L、总固体含量小于10mg/L)进行处理,处理能力0.5m^3/h,每次处理水量不大于100m^3,

  • 标签: 废水处理装置 工艺实验 可移动式 膜反应器 ^241AM ^239Pu
  • 简介:ThesplittingofpotentialenergylevelsforgroundstateX2ΠgofOx2(x=+1,1)underspin–orbitcoupling(SOC)hasbeencalculatedbyusingthespin–orbit(SO)multi-configurationquasi-degenerateperturbationtheory(SO-MCQDPT).TheirMurrell–Sorbie(M–S)potentialfunctionsaregained,andthenthespectroscopicconstantsforelectronicstates2Π1/2and2Π3/2arederivedfromtheM–Sfunction.TheverticalexcitationenergiesforOx2(x=+1,1)areν[O+12(2Π3/2→X2Π1/2)]=195.652cm1,andν[O12(2Π1/2→X2Π3/2)]=182.568cm1,respectively.Allthespectroscopicdataforelectronicstates2Π1/2and2Π3/2aregivenforthefirsttime.

  • 标签: 分子结构 势能函数 自旋轨道耦合 电子态
  • 简介:当堂反馈1.压强是反映——的物理量.一辆“东风牌”汽车对地面的压强是1.8×10^4Pa它所表示的物理含义是——.

  • 标签: 压强 物理量 东风牌
  • 简介:AnewlayeredCu-basedoxychalcogenideBa3Fe2O5Cu2S2hasbeensynthesizedanditsmagneticandelectronicpropertieswererevealed.Ba3Fe2O5Cu2S2isbuiltupbyalternativelystacking[Cu2S2]2-layersandironperovskiteoxide[(FeO2)(BaO)(FeO2)]2-layersalongthecaxisthatareseparatedbybariumionswithFe3+fivefoldcoordinatedbyasquare-pyramidalarrangementofoxygen.Fromthebondvalencearguments,weinferredthatinlayeredCuCh-based(Ch=S,Se,Te)compoundsthe+3cationinperovskiteoxidesheetprefersasquarepyramidalsite,whilethelowervalencecationprefersthesquareplanarsites.Thestudiesonsusceptibility,transport,andopticalreflectivityindicatethatBa3Fe2O5Cu2S2isanantiferromagneticsemiconductorwithaNe′eltemperatureof121Kandanopticalbandgapof1.03eV.Themeasurementofheatcapacityfrom10Ktoroomtemperatureshowsnoanomalyat121K.TheDebyetemperatureisdeterminedtobe113K.TheoreticalcalculationsindicatethattheconductionbandminimumispredominantlycontributedbyO2pand3dstatesofFeionsthatantiferromagneticallyarrangedinFeO2layers.TheFe3dstatesarelocatedatlowerenergyandresultinanarrowbandgapincomparisonwiththatoftheisostructuralSr3Sc2O5Cu2S2.

  • 标签: 钙钛矿型氧化物 铁磁半导体 光学带隙 德拜温度 电子性质 阳离子
  • 简介:Inthisarticle,theSm-dopingsinglecrystalsCa1-xSmxFe2As2(x=00.2)werepreparedbytheCaAsfluxmethod,andfollowedbyarapidquenchingtreatmentafterthehightemperaturegrowth.Thesampleswerecharacterizedbystructural,resistive,andmagneticmeasurements.ThesuccessfulSm-substitutionwasrevealedbythereductionofthelatticeparameterc,duetothesmallerionicradiusofSm3+thanCa2+.SuperconductivitywasobservedinallsampleswithonsetTcvaryingfrom27Kto44KuponSm-doping.ThecoexistenceofacollapsedphasetransitionandthesuperconductingtransitionwasfoundforthelowerSm-dopingsamples.ZeroresistivityandsubstantialsuperconductingvolumefractiononlyhappeninhigherSm-dopingcrystalswiththenominalx>0.10.Thedopingdependencesofthec-axislengthandonsetTcweresummarized.Thehigh-TcobservedinthesequenchedcrystalsmaybeattributedtosimultaneoustuningofelectroncarriersdopingandstraineffectcausedbylatticereductionofSm-substitution.

  • 标签: 掺杂晶体 超导电性 SM 单晶 晶格参数 淬火温度
  • 简介:Theground-stateandthermodynamicpropertiesofquantummixed-spinchainsof1/2-1/2-1-1and3/2-3/2-1-1areinvestigatedbyaquantumMonteCarlosimulationwiththeloop-clusteralgorithm.For1/2-1/2-1-1chain,wefindithastwophasesseparatedbyanenergy-gapvanishingpointintheground-state.For3/2-3/2-1-1chain,thenumericalresultsshowtwoenergy-gapvanishingpointsisolatedbydifferentphasesinitsground-state.Ourcalculationsindicatethatallthesegroundstatephasescanbeunderstoodbymeansofvalence-bond-solidpicture,andthethermodynamicbehavioratfinitetemperaturesiscontinuousasafunctionofparameterα=J2/J1.

  • 标签: 蒙特卡罗模拟 混合自旋链 铁磁性 基态 热力学性质 能隙
  • 简介:传统的语音识别方法,信噪比较低时识别率也较低。为了使语音识别更具有环境适应性、抗噪性,从非齐次隐马尔可夫模型(nonhomogeneousHiddenMarkovModel,HMM)出发,结合自适应函数链神经元网络,训练出适应环境变化的混合语音模型,并采用该混合模型进行语音识别。实验结果表明,该模型适用于含噪语音的识别,特别是在信噪情况下,可以相对提高识别率。

  • 标签: 非齐次隐马尔可夫模型 自适应函数链神经网络 非线性音段 单层感知器
  • 简介:Thedipole-length,velocityandaecelerationabsorptionoscillatorstrengthsforthe1s^22p-ls^2nd(3_2=11to20arecalculatedusingtheenergiesandthemulticonfiguratloninteractionwavefunctionsobtainedfromafullcorepluscorrelationmethod.Theagreementbetweenthef-valuescalculatedfromthelength,velocityandaccelerationformulaeisexcellent.Ourresultsagreecloselywiththeexperimentaldataavailableintheliterature.Combiningthesediscreteoscillatorstrengthswiththesingle-channelquantumdefecttheory,thediscreteoscillatorstrengthsforthetransitionsfrom1s^22pstatetohighlyexcitedstates(n_>10)andtheoscillatorstrengthdensitiescorrespondingtothebound-freetransitionsareobtained.

  • 标签: 类锂系统 振荡器 量子缺陷 电离化原子系统 原子物理学