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  • 简介:Inthispaper,theeffectofaddingdifferentconcentrationsofkineticinhibitorsontheinductiontimeofhydrogensulfidehydrateformationinareactorequippedwithautomaticadjustabletemperaturecontrollerisstudied.Anovelmethodnamely"suddencooling"isusedforperformingtherelevantmeasurements,inwhichtheinductiontimeofH2Shydrateinthepresence/absenceofPVPandL-tyrosinewithdifferentconcentrations(100,500,and1000ppm)isdetermined.Asaresult,PVPwiththeconcentrationof1000ppminaqueoussolutionisdetectedasamoresuitablematerialforincreasingtheinductiontimeofH2Shydrateformationamongtheinvestigatedkinetichydrateinhibitors.

  • 标签: 水合物抑制剂 水合物形成 硫化氢 感应时间 动能 实验
  • 简介:Effectsofspacevelocity,reactiontemperatureandsupportacidityonproductdistributionandinductionperiodin1-buteneisomerizationandmetathesisoverMo/mordenite-aluminawereinvestigated.Asrevealedbythecatalyticperformanceresults,inductionperiodandobjectiveproductwerecloselyrelatedtothereactionconditions.Lowerspacevelocityledtolongerinductionperiodandhigherpropeneyield.Theoptimalreactiontemperatureforpropeneproductionisaround150Canditshiftedto100Cforetheneproduction.1-Buteneauto-metathesispredominatedinthereactionnetworkifthesupportwithlowerdegreeofsodiumexchanged.Andpropenegraduallybecamethedominantproductuponincreasingthesupportsodiumexchangedegree.6Mo/H100Na0M-30Alcatalystwithasupportoffullsodiumexchangedegreeexhibitedthehighestpropeneyield.

  • 标签: 氧化铝 产品分布 丝光沸石 诱导期 异构化