简介：ＮＯＶＥＬＯＸＩＤＡＴＩＯＮＯＦＨＥＸＡＢＥＮＺＹＬＨＥＸＡＡＺＡ－ＩＳＯＷＵＲＴＺＩＴＡＮＥＢＹＭｅ２ＣＨＮＯ２／ＣｕＣｌ／Ｐｙ／Ｏ２ＸｉａｏＰｅｉＧＵＡＮ；ＨｏｎｇＹＡＮ；ＪｉａｎＧｕａｎｇＳＵＮ；ＹｏｎｇＺｈｏｎｇＹＵ(ＳｃｈｏｌｏｆＣｈｅ?..

简介：ReactionsofCuSCNwithtetramethylthiuramdisulfideinCH3CNinthepresenceofstyreneandN,N,N',N',N'-pentamethyldiethylenetriaminegaverisetoanewcopper(Ⅰ)complexofN,N'-dimethyldithio-cabamate{[Cu(S2CNMe2)]2}n.ThetitlecompoundcrystallizedinthetriclinicP-1spacegroupwithlatticeparametersα=0.7610(4)nm,b=0.8911(4)nm,c=0.9268(5)nm,α=68.66(1)°,β=83.88(2)°,γ=79.31(2)°,V=0.5748(5)nm^3,Z=2.Thecompoundhasaunique1DchainstructurecomposedofCuSCSCuSCSeight-memberedringsandapairofCu-Sbonds,thestructureofwhichhasbeendeterminedbysingle-crystalX-raycrystallography.Theisolationofthiscompoundmayprovidesomehelpfulinformationforthecauseoftheinductionperiodsofthereverseatomtransferradicalpolymerization.

简介：在有ArSSAr的THF的SmI2的反应生产了二binuclear钐thiolate建筑群[(THF)3I2-Sm(-SAr)]2[Ar=Ph(1)，4-Me2NC6H4(2)]在高收益。2的结构被单个水晶X光检查晶体学描绘。2的水晶与空格组和a=0.95705(13)一起属于三斜晶系的系统nm，b=1.22287(14)nm，c=1.26450(14)nm，=64.194(11)??匭吗？？v？？

简介：运用G98W程序,采用Lan12dz基组,对茂金属配合物[2,5-(Me3Si)2MeC5H2FeI(CO)2]进行从头算研究,探讨了配合物结构单元的稳定性、分子轨道能量、原子净电荷布居规律,以及一些前线分子轨道的组成特征等.结果表明,标题配合物在能量上可作为结构单元而稳定存在.该结构单元为茂金属配合物的合成、分子组装分析和催化活性研究提供理论依据.

简介：Inthispaperwereportachemicaloscillationcatalyzedby[Ni(Me2[14]1,3-dieneN4)]2+(Me2[14]l,3-dieneN4denotes2,3-dimethyl-l,4,8,ll-tetraazacyclotetradeca-1,3-diene)inBrO3--pyruvicacid-H2SO4system.Thedomainoftheexistenceoftheoscillationwasobtained.Theeffectsofinitialconcentrationofthecomponentsontheoscillationwerestudied.Thefeaturesoftheoscillationsweredescribedindetail.WealsoexaminedtheeffectsofAg+,Hg2+,CCl4,freeradicalinhibitors,etc.ontheosillations.