简介：Inordertoimprovethemechanicalpropertiesofpolypyrrole,compositesweremadebyelectropolymerizingpolypyrroleinapolyurethanematrix.Polypyrrole/polyurethane（PPY/PU）compositefilmscontainingCLO4-,BF4-orCH3-C6H4-SO3-counterionsweremadeinavarietyofsolventsystemsandcharacterizedbySEM,electronicconductivity,FTIR,andmechanicalproperties.Compositefilmsshowingmuchgreaterfiexibilitythanpurepolypyrrolewereobtained,buttheirelectronicconductivitiesweresubstantiallylower.Measuredeonductivitiesrangedfrom0.001to8S/cm,tensilestrengthsfrom44to592psi,andelongationtofailurefrom3to70%.

简介：PP/claycompositeswithdifferentdispersions,namely,exfoliateddispersion,intercalateddispersionandagglomeratesandpanicle-likedispersion,werepreparedbydirectmeltintercalationorcompounding.TheeffectofclaydispersiononthecrystallizationandmorphologyofPPwasinvestigatedviaPLM,SAXSandDSC.Experimentalresultsshowthatexfoliatedclaylayersaremuchmoreefficientthanintercalatedclayandagglomeratesofclayinservingasnucleationagentduetothenano-scaledispersionofclay,resultinginadramaticdecreaseincrystalsize(lamellarthicknessandspherulites)andanincreaseofcrystallizationtemperatureandcrystallizationrate.Ontheotherhand,adecreaseofmeltingtemperatureandcrystallinitywasalsoobservedinPP/claycompositeswithexfoliateddispersion,duetothestronginteractionbetweenPPandclay.Comparedwithexfoliatedclaylayers,theintercalatedclaylayershavealessimportanteffectonthecrystallizationandcrystalmorphology.Noeffectisseenforsampleswithagglomeratesandpanicle-likedispersion,inregardtomeltingtemperature,crystallizationtemperature,crystalthicknessandcrystallinity.

简介：AnewtypeofSiO_2-MgO-CaO(SMC)whiskerwasusedtomodifyhighdensitypolyethylene(HDPE).Themeltingbehaviorandcrystallinitywereinvestigatedbydifferentialscanningcalorimetry(DSC).ThedispersionofwhiskersandinterfacialadhesioninthepreparedHDPE/SMCwhiskercompositeswereinvestigatedbyscanningelectronmicroscopy(SEM).Themechanicalpropertieswereevaluatedbymechanicaltestsanddynamicmechanicalanalysis(DMA).DSCdataindicatedthatthemeltingtemperatureandthecrystall...

简介：Chitosan/cellulosenanocrystals(CS/CNCs)composites与计算机数值控制的不同内容被准备。由于计算机数值控制和计算机数值控制的同类的分散，CS的透明性很好被保留，CS的全面机械性质显著地被改进。而且，因为CS和计算机数值控制是biocompatible材料，获得的composites潜在地是noncytotoxic和罐头的房间增长测试表演满足生物医学的应用的安全要求。这些优点在商业塑料的地里铺平CS的潜在的应用的道路并且鼓励CS同样环境友好的材料和生物医学的材料的使用。

简介：Thisstudyinvestigatedtheinfluenceofvariousorganicallymodifiedmontmorillonites(organoclays)onthestructureandpropertiesofrigidpolyurethanefoam(RPUF)nanocomposites.Theorganoclaysweremodifiedwithcetyltrimethylammoniumbromide(CTAB),methyltallowbis(2-hydroxyethyl)quaternaryammoniumchloride(MT2ETOH)andtris(hydroxymethyl)aminomethane(THMA)anddenotedasCMMT,Cloisite30BandOMMT,respectively.MT2ETOHandTHMAcontainhydroxylgroups,whileTHMAdoesnothavelongaliphatictailinitsmolecule.X-raydiffractionandtransmissionelectronmicroscopyshowthatOMMTandCloisite30BcanbepartiallyexfoliatedintheRPUFnanocompositesbecausetheirintercalatingagentsMT2ETOHandTHMAcanreactwithisocyanate.However,CMMTmodifiedwithnonreactiveCTABismainlyintercalatedintheRPUFmatrices.Atarelativelylowfillercontent,theRPUF/CMMTcompositefoamhasahigherspecificcompressivestrength(theratioofcompressivestrengthagainsttheapparentdensityofthefoams),whileatrelativelyhighfillercontents,RPUF/Cloisite30BandRPUF/OMMTcompositeshavehigherspecificcompressivestrengths,highermodulusandmoreuniformporesizethantheRPUF/CMMTcomposite.

简介：聚苯乙烯(PS)/triphenyl磷酸盐(TPP)composites被暂停聚合准备并且融化挤出，和火焰retardance和机械性质的比较研究被执行。结果比为获得PS/TPP的好dispersity融化挤出证明暂停聚合是一种更好的技术合成。TPPnanoparticles，是在尺寸的约50nm，被暂停聚合同质地并且一致地在一步舞在PS矩阵驱散。然而，PS/TPP合成部分被聚结，不规则地展出塑造了微米规模粒子由于融化挤出。与melt挤出相对照，由从21.8%增加到22.6%的暂停聚合的PS/TPPnanocomposite的有限的氧索引(LOI)，和点火(TTI)的时间增加了12.3%，山峰热版本率(PHRR)在8.5%减少了，并且全部的热版本(THR)在11.0%减少了。由暂停聚合的PS/TPPnanocomposite的机械性质也增加了。张力的力量，在裂缝的延伸，和曲折力量分别地增加了36.4%，8.5%，和108%。

简介：

简介：在这个工作，flame-retardant聚丙烯(PP)/ramie纤维(RF)合成被准备。苎麻纤维被生产经由的包含磷、包含氮的火焰retardant(FR)化学上包在situ冷凝作用反应以便压制他们的烛蕊效果。红外线的光谱学(FTIR)，X光检查光电子光谱学(XPS)和扫描电子显微镜学(SEM)表明了的Fourier变换苎麻纤维由FR(FR-RF)化学上包了，这成功地被获得。Thermogravimatric测试证明PP/FR-RF合成比PP/RF在高温度有更多的残余和更好热的稳定性合成。锥热量计(CC)结果显示热版本率(PHRR)和全部的热版本(THR)的山峰相应地与整洁的PP/RF的价值相比在23.4%和12.5%减少了。PP/FR-RF合成在燃烧以后创造了连续、紧缩的字符层。在有热传导系数的CC测试以后的字符残余的联合FTIR分析结果，RF上的FR的charring极大地削弱了RF的烛蕊效果，这能被结束，并且在RF域的更多的字符残余在整个燃烧地区便于更多的连续、紧缩的字符层的形成，因而在燃烧期间保护了PPcomposites，导致比PP/RF的合成的PP/FR-RF的更好的火焰retardancy合成。