简介：

简介：Inductivelycoupledplasmamassspectrometry,inductivelycoupledplasmaopticalemissionspectroscopy,hydridegeneration-atomicfluorescencespectrometry,emissionspectrometry,Xfluorescencespectrometry,andX-raydiffractionwereemployedtostudythegeochemistryandmineralogyofcoalganguesfromNos.2,3,and8coalseamsoftheDu’erpingcoalmine,Xishancoalfield,Taiyuan,ShanxiProvince.Thestudyrevealedthatcomparedwiththesedimentarycover,uppercontinentcrust,Carboniferous-PermiancoalfromNorthChina,aswellasmostcoalinChina,coalganguesfromNos.2and3coalseamsarerichinLi,Be,Sc,Cr,Cu,Ga,Ba,Th,Nb,Cd,Pb,Taandrare-earthelements,andcoalganguesfromNo.8coalseamarerichinLi,Sc,V,Cr,Ga,U,andrare-earthelements.ComparedwiththeCarboniferous-PermiancoalfromNorthChinaandmostcoalinChina,coalganguesfromNos.2,3and8seamsarerichinRb,V,CsandSr.Therefore,TheDu’erpingcoalganguesintheXishancoalfieldarerichinmosthazardoustraceelementsandrare-earthelements,whereinthecontentsofGaandLireachtheindustrialgradeandhavesignificanceforindustrialutilization.Onthewhole,coalganguesoftheShanxiFormationfromthePermianarerichinmoretraceelementsthanthoseoftheCarboniferousTaiyuanFormation.ThedistributionsofREEshowobviouslydippingrightwardswithnegativeEuanomalies.Thecontentsofrare-earthelementsinthethreeseamsarequitedifferent.Alloftheaboveindicatethatthesourceoftherare-earthelementsisterrigenousdebris.MineralsinNo.2seamidentifiedbyX-raydiffractionmainlyincludequartz,kaolinite,inadditiontocalcite,pyrite,apatite,epidote,andepsomite.No.3seammainlycontainsquartz,kaolinite,inadditiontoasmallamountofsodiumfeldspar,calciumnitrate,ironore,gypsum,andvivianite.No.8seammainlycontainskaolinite,dickite,quartz,illite,andasmallamountofhematiteandU.Thecorrelationsbetweenmajorelementsandtraceel