简介：Inordertorealizetheco-firingwithAg/Pdelectrodesinmultilayerdevices,Pb(Zn1/3Nb2/3)1-,-yZrxTiyO3(0.25＜x＜0.35,0.25＜y＜0.35)piezoelectricceramics(hereafterdesignatedPZN-PZT)modifiedbyLa2O3hasbeenpreparedbyconventionaltechniquewithsinteringtemperaturefrom1100℃to1140℃.X-raydiffractionpatternsdemonstratedthatpureperovskitephasewasobtained.Secondaryelectronimage(SEI)showedthatcrystallinegrainsinceramicswerewellgrown.d33ofmanufacturedsamplewasashighas560×10-12C/N.kpwasabout0.61andtgδabout30×10-3.TheexistenceofliquidphaseexaminedbyelectrondiffractioninPZN-PZTsampleisbeneficialtosinteringoftheceramic.

简介：ThetransportpropertiesintheLa2/3(Ca1-xSrx)1/3MnO3(x=0,1/3,2/3)filmspreparedusingtheRFmagnetronsputteringmethodwereinvestigated.TheeffectoftheCa,Srdouble-dopingattheApositionintheLa2/3A1/3MnO3onthestructureofthetargetsandtransportofthefilmshasbeenstudied.Withtheincreaseofx,thestructuresofthetargetstransformfromtherhombohedralphasetothecubicphase;themetal-insulatorphasetransitiontemperature(Tp)ofthefilmsincreases;andthecorrespondingpeakresistivitydecreases.Allthephenomenacanbequalitativelyexplainedbythelatticeeffect.

简介：TheRamanspectraof3%(molefraction)Y2O3-ZrO2(3Y)areobtainedatdifferenttemperaturefrom77Kto853K.Theresultsshowthat260cm-1Egand460cm-1Egmodesonthespectrashifttowardlowerwavenumberwiththeincreaseoftemperature;meanwhile,thecontinuityoftheHalfWidthatHalfMaximum(HWHM)andwavenumber(frequency)ofRamanbandsarebrokenandt-phaseonlypartiallytransformstom-phaseat523K.Basedontheexperimentalresults,thispaperdiscussesthet-phaselatticevibrationof3YandpresentstheimagesofvibrationdisplacementofsixRaman-activemodesfort-phaseofZrO2.TheanalysisindicatesthattherearediversitiesexistinginthedisplacementoftheatomicvibrationofRaman-activemodesbecauseoftheirdifferentsymmetriesatvarioustemperature,whichleadstothedifferentchangetendenciesofRamanbands.Furthermore,theabruptchangesofsomeRaman-activemodesindicatingtheatomicdisplacementareassumedtobethecondensationsofphononmodesinthet→mphasetransition.

简介：(1-x)La_(0.67)Ca_(0.33)MnO_3/Cr_2O_3(LCMO)+xCr_2O_3composites被一个新液相方法综合。XRD和SEM大小表明在LCMO结构和LCMO的晶格常数可溶的很少Cr_2O_3几乎没变化，当大多数Cr_2O_3在谷物边界或在LCMO谷物的表面上是分布式的时。Inresistivity对温度大小，金属--绝缘体转变被观察什么时候x<0.20。抵抗力增加和金属--绝缘体转变温度与Cr_2O_3的增加的内容减少。一个随机的电阻器网络(KRN)模型被使用，到模仿混合样品的运输性质。模拟结果同意试验性的观察。结果证明方法为理解maganite的composites的电子运输是合理的。

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简介：SkeletalformofKNbO3crystalsgrowinginLi2B4O7solventwasin-situobservedat900CanditwasfoundthatshallowdepressionstartedtodeveloponthesurfaceofKNbO3crystalswhenthecrystalsizeexceededseveralmicron,typically7micron.BasedonthequantitativecriterionderivedbyChernov,theestimatedcriticalsizeofKNbO3crystalswas1micron,whichwasconsistentwiththeexperimentalmeasurement.Thekineticcoefficients,kcerandkc,,inthecriterionwereexperimentallyobtainedinthediffusive-convectiveanddiffusive-advectiveflowstatesrespectively.

简介：Amathematicalmodelforthethree-dimensionalsimulationoffreedendriticgrowthandmicrostructureevolutionwasdevelopedbasedonthegrowthmechanismofcrystalgrainsandbasictransferequationssuchasheat,massandmomentumtransferequations.Manyfactorsincludingconstitutionalundercooling,curvatureundercoolingandanisotropy,whichhadvitalinfluencesonthemicrostructureevolution,wereconsideredinthemodel.SimulatedresultsshowedthatfinalmicrostructuralpatternsandfreedendriticgrowthcouldbepredictedreasonablyandcalculatedresultswerecoincidentwithexperimentalThesimulatedresultsoffreedendriticgrowthindicatedthatthestrengthofanisotropyhassignificanteffectsonfreedendriticgrowth,dendriteprofile,microsoluteandtemperaturedistribution.Thedendriticgrainprofileswithfully-grownparallelsecondaryarmtendtobeformedattheintensiveanisotropy,whilenearoctahedralgrainprofileswithsmallprotuberancesofsurfaceatlowstrengthofanisotropy.Thesimulatedresultsoffreedendriticgrowthalsoindicatedthattherearesmallmoltenpoolsleftininterdendriticareas.Thisishelpfultounderstandthefundamentaloftheformationofmicrostructurerelateddefectssuchasmicrosegregationandmicroporosity.

简介：Thevolatilizationkineticsofantimonytrisulfideinsteamatmospherewasstudiedwiththermogravimetryattemperaturesfrom923to1123K.Atheoreticalmodelwasdevelopedtocalculatetheoverallrateconstantandthemasstransfercoefficientingasphases.Theexperimentalresultsshowthatthevolatilizationrateisenhancedwithincreasingtemperatureandsteamflowrate.Thevolatilizationrateismainlycontrolledbythemasstransportingasphases.Theapparentactivationenergyfortheprocessisfoundtobe59.93kJ/mol.ItisdemonstratedthatSb2S3isdominantlyoxidizedintoSb2O3andH2Sbywatervaporinthevolatilizationprocess.Someantimonymetalisformed.Thereactionmechanismisdiscussedinaccordancewithexperimentaldata.

简介：Throughmeasuringthecoefficientoflinearexpansion,thestructureandpropertiesoftheLi2O-Al2O3-SiO2lowexpansionglassceramicscontainingB2O3arestudiedbyJRandXRD.ItisshoutnthattheIRmethodisefficientinthestudyoftheglass-ceramicsstructure.Thereisa"Boronabnormality"inthesystemwhichhasanimportantinfluenceonthepropertiesoftheglass-ceramics.

简介：Eu(TTA)4CsHsNC16H33(TTA:1-(2-Thenoy)-3,3,3-Trifluoracetate)isencapsulatedinSi-MCM41modifiedwithN-(3-Trimethoxysilethyl)ethylenediamine.Theemissionspectrumoftheassemblyshowsonlya5D0→7F2transition.Ascomparedwiththerareearthcomplexitself,thelifetimeoftheassemblybecomeslongeranditsstabilityundertheUVradiationismuchbetter.

简介：结果证明Mg在空间在钢的张力的性质和坚硬上有更少的效果温度，而是Mg的正确数量改进影响和破裂坚韧并且减少破裂转变温度更加由于包括修正，象一样通过加强谷物边界并且修改边界碳化物戏剧性地延长槽口压力破裂生活。有一个最佳Mg内容，它在试验性的35CrNi3MoV钢是大约0.0030%。(编辑作者摘要)8个裁判员。

简介：Howtocontrolmeltcompositionisthekeyforgettinghighqualityalloymelt.Thepapermadethefollowingefforts:(1)TheactivitycoefficientsinTi-15-3melthavebeencalculated.(2)Takingadvantageoftheactivitycoefficients,theevaporationlossesofcomponentsinTi-15-3meltduringISMprocesshavebeenstudied.Thecalculatedresultsshowthatthereisacriticalvacuumdegree(about1.33Pa)duringmeltingprocess.

简介：Si3N4/TiCnanocompositeceramicshavebeenfabricatedbyhotpressingtechniquewithAl2O3andY2O3asadditives.TheresultsshowedthatwelldispersedcompositepowderwascarriedoutbyaddingdispersantandadjustingpHvaluesofsuspensions.RemarkableincreaseinflexuralstrengthatroomtemperatureswasobtainedbyaddingnanoparticlesinSi3N4matrixwith10%(wtpct)ofnano-Si3N4and15%ofnano-TiC.Theflexuralstrength,fracturetoughnessandhardnesswere1025MPa,7.5MPa·1/2and15.6GPa,respectively.Themicrostructuresofmaterialswereanalyzedbyscanningelectronmicroscopy(SEM)andtransmissionelectronmicroscopy(TEM),whichindicatedthatTiCnanoparticlesdistributeinthematrixandatthegrainboundaries.Accordingtothefractureform,lowcontentsofnanoparticlescouldrefinematrixgrainsandleadtothecrackdeflectionaswellascrackpinning.Themultiplexmicrostructurewasformedbymixingnano-Si3N4particles.Thecracktrajectoriesexhibitedcrackdeflection,rod-likegrainbridgingandpull-out.

简介：以前曾指出由3，3’，4，4’-联苯基四羧酸二酐(BPDA)和1，2-双(4-氨基苯氧基)苯(亦称三苯基醚邻苯二酚二胺(TPEC))衍生的聚酰亚胺具有优异的拉伸性能和良好的热性能。本文对由BPDA、TPEC及其它芳香族二胺制备的共聚酰亚胺的性能做了初步评价。由BPDA和各种芳香族二胺制备的均聚酰亚胺通常具有良好的机械性能和热性能。然而，它们不溶于现有的各种有机溶剂中。在某些条件下，用BPDA与等摩尔TPEC和其它芳香族二胺混合物可以制备可有机溶解的BPDA型共聚酰亚胺。这些共聚酰亚胺可以形成坚韧的薄膜，它们具有较高的模量和强度。多数情况下，也具有较高的断裂伸长率。

简介：Theinterfacialbindingcovalentbonddensity(CBD)andthelocalenvironmentaltotalbondorder(LTBO)oftheNi/Ni3Alinterfacewithdifferentlatticemisfits(δ)werecalculatedbyusingfirst-principlesdiscretevariationXαmethod.ItwasfoundthattheeffectsoflatticemisfitsontheelectronicstructuresofincoherentNi/Ni3Alinterfacewereveryobvious.Ononehand,lessthan-0.6%negativelatticemisfitcanpromotethebindingstrengthofγ/γ′interface.Ontheotherhand,thetotalbondingstrengthofγ/γ′interfacedecreaseswithincreasingδ.Therefore,themagnitudeandsignoflatticemisfitmustbecarefullycontrolledforbalancingthehightemperaturecreepstrengthofNi-basesinglecrystalsuperalloyandthestructuralstabilityofγ/γ′interfacewhenonedesignsanewNi-basesinglecrystalsuperalloy.