简介:ThemixturemodelofAl85Y4Nd4Ni7alloyinwhichapartiallycrystallizedamorphousalloyisregardedasananocompositeofanAlnanoparticleandaremainingamorphousmatrixispresented.Itsevolutionintheprocessofcrystallizationhasbeeninvestigatedbydifferentialscanningcalorimetry(DSC),X-raydiffraction(XRD),andtransmissionelectronmicroscopy(TEM).Mainlyamorphousstructurewithα-Alnanocrystalsembeddedintheamorphousmatrixhasbeenrevealedbymeltspiningthealloy.Crystallizationisshowedtooccurinthreestages:(1)crystallizationofamorphousalloyandformationofAlNiY,AlNdNiandunknowncrystallinephases,(2)formationofAl3YandAl3Nd,and(3)formationofAl3Ni.
简介:对冷拉弹簧钢丝卷制过程中发生断裂的原因进行分析,对其卷制工艺性的影响因素进行总结.通过扫描电镜、能谱仪、光学显微镜、显微硬度测试仪、拉伸试验机等设备对多件卷制过程中发生断裂的lCrl8Ni9Ti冷拉弹簧钢丝的断口形貌、微观组织和力学性能进行对比和分析.结果表明冷拉弹簧钢丝的断裂模式为塑性断裂,断口形貌呈韧窝特征,断裂原因与材料的卷制工艺性有关;钢丝表面机械损伤会提供初始裂纹扩展源区,组织中的氮化物聚集会破坏材料的连续性,材料强度过高会降低材料的塑性余量,该3类缺陷均会加大钢丝的断裂倾向,给钢丝的卷制加工带来不利影响.因此,需要尽量避免材料表面缺陷、组织缺陷以及性能缺陷,以便提高材料的卷制工艺性.
简介:Non-stoichiometriccompoundfluoride-dopedLiFePO4/Ccathodematerialsweresynthesizedviasolid-statereactionusingMgF2andAlF3asdopant.Thefluoride-dopedLiFePO4/CsampleswerecharacterizedbyX-raydiffraction(XRD),scanningelectronmicroscopy(SEM),transmissionelectronmicroscopy(TEM),andelectrochemicaltesting.TheresultsshowthatthematerialsarewellcrystallizedandfluoridedopingcannotchangethespacestructureofLiFePO4.SlightamountsofFe2O3withnofluorideimpuritywere...
简介:Inthiswork,asimpleandfacileone-potoleylaminesolvothermalsyntheticmethodwasdevelopedtosynthesizeCu_2ZnSnS_4(CZTS)nanocrystals.AndtheCu_2ZnSn(S,Se)_4(CZTSSe)thinfilmswerepreparedbyselenizingCZTSnanocrystals.TheobtainedCZTSnanocrystalsandCZTSSefilmswerestudiedusingX-raydiffraction(XRD),transmissionelectronmicroscopy(TEM),scanningelectronmicroscopy(SEM),energy-dispersiveX-rayspectroscopy(EDX),andultraviolet–visiblespectrophotometer(UV–Vis).TEMresultsshowthatthesphere–likeCZTSnanoparticleswithdiameterbetween12and35nmarepolydispersed.XRDstudiesindicatethatthepreparedCZTSnanocrystalsformkesteritecrystalstructure,andtheCZTSSefilmswithkesteritecrystalstructurearealsoobtainedattheannealingtemperaturesof500and550°C.Inparticularafterannealingat500°Cfor20min,theCZTSSefilmexhibitsasmooth,uniform,crack-free,andlarge-grainedtopographyandpossessesCu-poorandSn-richcomposition.Moreover,itshowsstrongopticalabsorptionfromvisibletonear-infrared(IR)region,anditsopticalbandgap(Eg)isfoundtobeabout1.44eV.
简介:ToinvestigatethedegradationofcorrosionresistanceofZircaloy-4inLiOHaqueoussolution,SIMS(secondaryionmassspectrometry)analysiswasperformedtoexaminetheprofilesofLi+,K+,andOH-inoxidelayersformedinthesameconcentration(0.1mol/L)LiOHandKOHsolutions.Eventhoughtheoxidelayershaveanequalthickness,thepenetrationdepthofK+isshallowerthanthatofLi+,andthepenetrationdepthofOH-corrodedinKOHsolutionisalsoshallowerthanthatcorrodedinLiOHsolution.ItshowsthatthediffusionofOH-intooxidelayerisaccompaniedbythecorrespondingcation.ThedifferenceofdegradationeffectofLiOHandKOHsolutionsonthecorrosionresistanceofZircaloy-4wasdiscussed.
简介:在H2SO4-Fe2(SO4)3体系中研究载金黄铁矿的浸出动力学,探讨反应温度、Fe3+浓度、硫酸浓度、搅拌速度等对黄铁矿浸出的影响规律。结果表明:在H2SO4-Fe2(SO4)3体系中,在30~75°C下黄铁矿浸出过程主要受化学反应控制Fe3+浓度与黄铁矿的浸出呈正相关,通过Arrhenius经验公式求得浸出表观活化能为51.39kJ/mol。EDS与XPS分析结果表明:黄铁矿氧化过程中硫的氧化经一系列中间形态,最终被氧化成硫酸根,并伴有部分元素硫生成,符合硫代硫酸根氧化路径机理。
简介:研究析出强化AW-6016-T4金属板材的低温成形行为。利用拉伸和Nakazima测试方法获得材料在-196至25°C范围内的流变曲线和成形极限曲线。结果表明,材料的强度和伸长率随温度的降低而增大。背散射电子衍射(EBSD)研究表明变形材料在室温和低温下显微组织有细微区别。但连续加热差热分析表明析出动力学之间无明显区别。本研究结果表明低温变形可用于制造8mm深的B柱,而常温变形只能制造6mm深的B柱。