简介:从有机包裹体及成岩作用研究的角度对崖21-1构造油气成藏作了初步分析。崖21-1构造上第三系砂岩储层烃类丰度高,演化程度也较高,储层经历了两期烃类运聚过程,运聚时储层温度在145-165℃,埋深在3100-3600m,时间为上新世-第四纪,油/气源来自梅山组。构造顶部下第三系砂岩储层为含烃水层,少量的烃类是崖城组烃源岩早期排烃的产物。构造顶部砂岩储层中可能存在一致密胶结带,此胶结带对向上运移的油气起了封堵作用。构造形态及沉积特征是形成胶结带的主要原因,而成岩胶结作用与油气运移的时间导致油气运聚最终与构造顶部浅层无缘。推测在胶结带下方和构造翼部可能形成油气富集。
简介:The^Siand^1Hhigh-resolutionliquid-phaseNMRhasbeenusedtoinvestigatethehydrolysisprocessofthetetraethylorthosilicate(TEOS).^1H-NMRspectroscopyshowsthatthehydrolysisofTEOSinTPAisfasterthaninTEA.TheimpactsofTPAandTEAontheTOEShydrolysisprocessanditshydrolyzedproductdistributionhavebeenobservedby^29Si-NMRrespectively.Theinfluencesofwaterandtheisopropylalcoholonhydrolysishavealsobeendiseussed.ThepresenceofTBOTmarksanevidentdifferentiationbetweenTPAandTEAforhydrolysisin^29Si-NMRspectra.
简介:Thispaperhasstudiedthevapor-liquidequilibrium(VLE)forthesalt-containingextractivedistillationofthe1-propanol/watersystem.BinaryVLEdataweremeasuredforthesystemsof1-propanol(1)/KAc(4),ethanediol(3)/KAc(4),and1-propanol(1)/ethanediol(3),withtheVLEdatacorrelatedwiththeNRTLmodelinordertoobtainthemodelparametersofthesebinarysystems.ThebinaryVLEdatacitedintechnicalliteraturewerecorrelatedtoobtainthemodelparametersforotherbinarysystems.VLEdataofternaryandquaternarysystemspredictedbytheNRTLmodelagreedwellwiththeliteraturedata.TheinfluenceofKAc,ethanediol,andtheKAc/ethanediolmixtureonvolatilitybetween1-propanolandwaterwasinvestigatedrespectively.Testresultsshowedthattheabove-mentionedmaterials(KAc,ethanediol)andtheirmixture(KAcandethanediol)havedifferentinfluenceonthevolatility.Whenx3=0.5,andx4=0.05,theazeotropicpointcanbeeliminated.TheNRTLmodelmethodofsalt-containingVLEissimpleandeffectiveforthepredictionofthesystem’sVLEdata.