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简介:用滚镀的方法在金刚石表面镀Ni层和纳米Si3N4/Ni复合镀层,用扫描电子显微镜观察金刚石镀前和镀后的表面形貌,用DKY-1型单颗粒抗压强度测定仪测量金刚石单颗粒的抗压强度。用热压烧结的方法得到铁基结合剂金刚石节块,在INSTRON-5569型万能材料试验机上测量节块的抗弯强度,在NMW-1立式万能摩擦磨损试验机上测试节块的耐磨性。结果表明:在金刚石表面镀Ni层和纳米Si3N4/Ni复合镀层后,表面镀层均匀,纳米Si3N4/Ni复合镀层比纯Ni层更致密,更平滑,晶粒更细小;纳米Si3N4/Ni复合镀层金刚石单颗粒有更高的抗压强度;纳米Si3N4/Ni复合镀层金刚石铁基结合剂节块有更高的抗弯强度和更优良的耐磨性。
简介:探讨了在大生产条件下4Cr5MoSiV1钢的脱碳层测定原则。结果表明,金相法测定结果较准确且操作简便
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简介:Whitebody-color(Y,Gd)BxV1-xO4-x:Eu3+phosphorswerepreparedbycoprecipitationreaction.UnderVUVexcitationat147nm,theredemissioncolorimetricpurityof(Y,Gd)BxV1-xO4-x:Eu3+phosphorismuchbetterthanthatofcommercialPDP(plasmadisplaypanels)phosphor(Y,Gd)BO3:Eu3+.Butitsrelativeemissionintensityisonlyabout90%ofthecommercialphosphor.
简介:ThesinglecrystalgrowthofstoichiometrichostluminescentcrystalNa5Eu(WO4)4hasbeeninvestigated.UsingNa2WO4asaflux,theoptimumconditionstogrowapuresinglecrystalbyflux-slow-coolingmethodhavebeendetermined.Ahighopticalqualitysinglecrystalofdimention4.5mmhasbeengrown,whichisthelargestoneasweknowsofar.Themicro-hardnessofNa5Eu(WO4)4singlecrystalis3.46×103MPa.Itsrefractiveindexis1.81inwhitelightwavelengthregionandthespecificgravityis5.65g/cm3.Thefluorescentandexcitationspectrahavebeendeterminedandthereasonofthefluorescentquenchof5D2and5D1to7FjofEu3+canbeexplainedasmulti-phononnon-radiationtransition.
简介:Thecrackingandaromatizationofn-hexaneoverH-ZSM-5modifiedbyvariousrareearthswereinvestigatedbymeansofcontinuousflowmicro-reactor.ThesurfacepropertiesofmodifiedH-ZSM-5catalystswereobtainedfromIR,XRDandXPS.Theresultsshowthattherareearthsenhancethearomatizingpropertiesofthecatalystswhicharepreparedbymechanicalmixturemethod.Theresultsofn-hexanecrackingandaromatizationarecorrelatedwiththeacidity.TheBrnstedacidicsitesaretheactivesitesofn-hexanearomatization,whileLewisacidsiteplaysanimportantroleinn-hexanecracking.
简介:Silicawasused,asacatalystcarrier,toloadceroussulfateforcatalyzingthesynthesisofn-butylacetate.Themainpurposeofthisresearchwastoexplorethefeasibilityofsilicainimprovingthedecentralityandactivityofthecatalyst.Theeffectsofmolarratioofbutylalcoholtoaceticacid,theceroussulfateloadingsandthereactiontimeontheconversionofaceticacidwerestudiedbysinglefactorexperimentmethodandorthogonalexperimentmethodrespectively.Therefractiveindex(n20D)andmolecularstructureofthepreparedn-butylacetateweremeasuredbyAbbeRaefractometerandFourierTransformInfraredspectroscope,respectively.Thecomparisonsofthesilicaloadedandunloadedcatalystsforcatalyzingthesynthesisofn-butylacetateweremade.Theresultsshowedthatthesuitableconditionsforsynthesizingn-butylacetatewere:molarratioofbutylalcoholtoaceticacidof1.4∶1,uselevelofloadedceroussulfateof0.30gandreactiontimeof50min,respectively.Themaximumconversionofaceticacidforthesilicaloadedcatalystreached98.62%whichwas12.32%and16.43%higherthanthosefortheunloadedcatalystsreportedinliteratures,buttheuselevelofceroussulfatefortheformerwasmuchlessthanthoseforthelattersundersimilaroptimaltechnicalconditions.Thesilicawasprovedtobeagoodcatalystcarrierforenhancingdecentralityandactivityofthecatalystandincreasingtheconversionofaceticacid.Therepentanceofthesilicaloadedceroussulfatewasalsoinvestigatedintheexperiment.
简介:SeveralREEdatasetswerecollectedinCoreDD2andEC2005intheinnershelfofEastChinaSea,CoreY127inthenorthernOkinawaTrough,CoreNT1,C9247andC92169inthesouthYellowSeatochecktheapplicabilityoftheδEuN-ΣREEsmodelforquantita-tivelydistinguishingsedimentsfromtheYangtzeRiverandtheYellowRiver.Bycomparison,severalsedimentsincoresDD2,EC2005,Y127aregenerallyinaccordancewiththismodel.ThecoresNT1,C9247andC92169,whichhavebeeninfluencedbytheYangtzeRiverandtheYellowRivertogether,however,wereinconsistentwiththeδEuN-ΣREEsmodel.TheδEuN-ΣREEsplotanditscorrespondingregressionequation,whichcouldbeusedtodistinguishsediments"intuitivelyandquantitatively"fromtheYangtzeRiver,andtheYellowRivershouldbereconsideredorreassessed.
简介:二高度光的铕(III)和铽(III)的准备有succinimide(SI)和N-hydroxysuccinimide(NHSI)的建筑群被报导,它进一步通过元素的化学分析,热分析,英尺红外,粉末X光检查衍射,SEM和荧光光谱学被调查。通过这些分析收集的数据揭示了Eu(III)的形成,有上面的Tb(III)建筑群对ligand在金属提及ligands(M:L)1:3的臼齿的比率。光中心从photoluminescent系列调查被保留的关于通过lanthanide的协作地点的有效促进感受性的有趣的结论。当时,强壮的光排放在Eu(III)-SI和Tb(III)-NHSI建筑群的情况下被观察-SI建筑群展出了的相应Eu(III)-NHSI和Tb(III)没有相片光性质。最新获得的光lanthanide建筑群可能具有为在光电子的各种各样的应用的特别兴趣。
简介:ThephotoluminescencepropertiesofBiTaO4∶Pr3+andBiTaO4atroomtemperaturewerestudied,andtheinfraredtransmissionanddiffusionreflectionspectraofBiTaO4weremeasured.ThephotoluminescencespectrumofBiTaO4peaksatabout420,440and465nm.Therehasanobviousexcitationbandfrom330to370nm.ThephotoluminescencespectrumofBiTaO4∶Pr3+consistsofthecharacteristicemissionofPr3+,anditsmainpeakisat606nmfrom3P0→3H6transitionofPr3+.Itsexcitationspectrumconsistsofthewidebandwithmaximumat325nm,thewidebandintherangeof375~430nm,andthecharacteristicexcitationofPr3+.Thebandsat325nmand375~430nmmaybefromtheabsorptionofthechargetransfertransitionofthetantalategroupanddefectenergylevelsinitsforbiddenband,respectively.ThereisenergytransferfromhosttoPr3+.BecauseboththehostdensityandphotoluminescencepeakintensityofBiTaO4∶Pr3+aresuperiortoPbWO4,BiTaO4∶Pr3+maybeapotentialheavyscintillator.