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15 个结果
  • 简介:Er3+-Tm3+-Yb3+tri-dopedBaMoO4phosphorsweresynthesizedbyco-precipitationtechniqueandcharacterizedbyX-raydiffractionanalysis,absorptionstudyandfieldemissionscanningelectronmicroscopyanalysis.Upconversionaswellasdownconversionluminescencestudieswereperformedbyusingnearinfrared(980nm)andultraviolet(380nm)excitations.Energyleveldiagram,pumppowerdependenceandcolourcoordinatestudywereutilizedtodescribethemulticolorupconversionemissionproperties.Undersingle980nmdiodelaserexcitationthedualmodesensingbehaviourisrealizedviaStarksublevelsandthermallycoupledenergylevelsoftheTm3+andEr3+ionsinthepreparedtri-dopedphosphors.AcomparativefluorescenceintensityratioanalysisforintegratedemissionintensitiesarisingfromtheStarksublevels{1G4(a)and1G4(b)}andthermallycoupledenergylevels{2H11/2and4S3/2}oftheTm3+andEr3+ions,respectivelywascarriedoutinthepreparedtri-dopedBaMoO4phosphors.ThemaximumsensitivityforthermallycoupledenergylevelsoftheEr3+andStarksublevelsoftheTm3+ionwasreported.Thedevelopedphosphorscouldbeusefulinthedisplaydevicesandopticalthermometricapplications.

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  • 简介:AseriesofCeB6-dopedandCeO2-dopedCa1-xSiAlN3:xCe3+(denotedasCASN:Ce3+@CeB6andCASN:Ce3+@CeO2,respectively)weresynthesizedbyalloy-nitridationmethodunderhigh-puritynitrogenatmosphere.Themorphologies,crystalphases,andluminescencepropertieswereinvestigatedindetail.WithanincreaseintheconcentrationofCeB6,theunitcellvolumeofCASN:Ce3+@CeB6slightlyincreasesduetothesubstitutionbetweenions,whichleadstoachangeofmicrostructurearoundCe3+.CASN:Ce3+@CeB6efficientlyemitsyellow-orangelightwithamaximumemissionintensityataround550nmforthecontentxof0.01(beingincomparablesituation,CASN:Ce3+@CeO2isx=0.04)whenexcitedat460nm.ComparedwithCASN:Ce3+@CeO2,theredemissioncomponentofCe3+inCASN:Ce3+@CeB6ismuchstronger.Thisisascribedtoenergytransferofintra-Ce3+(withinoneCe3+ion)andinter-Ce3+(betweenCe3+andCe3+ions).Inaddition,thereplacementsofN3-(0.132nmforCN=4)andO2-(0.124nmforCN=4)byB2-(0.140nmforCN=4),whichcanleadtoamarkedexpansionofthehostlatticeandadecreaseoftheoxidationofsamples,arealsoresponsiblefortheincreaseofredemissioncomponent.Furthermore,CASN:Ce3+@CeB6phosphorhasanexcellentthermalstabilitybecauseofthepartialsubstitutionofCe-O(Ce-N)bondsbymorecovalentCe-B.Asaresult,theoutstandingluminescentpropertiesofCASN:Ce3+@CeB6phosphormakeitpracticaltouseinthesinglephosphor-coatedhigh-color-renderingpowerwhiteLED.

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  • 简介:丹麦议会于6月27日投票通过了该圉的新能源协议,决定到2030年再新建三座海上风电场,总容最至少为240万千瓦。协议还提出了丹麦新的能源发展目标,要求到2030年,可再生能源占能源消耗总量的55%。

  • 标签: 海上风电场 丹麦 可再生能源 能源消耗 新能源 协议
  • 简介:以莱钢3200m3高炉妒前智能润滑为对象,分析了智能润滑在使用过程中的优点。同时结合实际运行中出现的故障,指出了在恶劣环境下,尤其是在整体转动设备润滑方面,智能润滑存在的不足之处。

  • 标签: 炉前 智能润滑 制约因素 高炉
  • 简介:以Ti粉、Al-V合金粉及Mo粉为原料,通过冷等静压和真空烧结制备Ti-3Al-5Mo-4.5V(TC16)合金,并对该合金的组织与力学性能进行研究。结果表明,粉末冶金TC16合金具有由α相和β相组成的网篮组织,相对密度约为93.5%,抗拉强度、屈服强度和伸长率分别为1062MPa,973MPa和2.3%,关键性能(屈服强度)达到铸造TC16合金水平。

  • 标签: 粉末冶金 钛合金 相对密度 微观组织 力学性能