简介:Ni-Ti形状记忆合金由于有特殊的形状记忆效应和良好的机械性能成为受到很大关注的功能材料。尽管Ti-Ni合金已经被研究了很多年,至今,仍然有很多有趣的现象并没有得到很好的认识,尤其Ni-Ti合金在不同温度下的应力应变曲线的因素的研究上还有很多没有解释清楚的问题。为此笔者在文中详细介绍了Ni-Ti形状记忆合金的应力与应变关系实验的准备,实验过程,以及实验结果的获取。并对实验结果进行了分析总结,得出Ni-Ti形状记忆合金在不同应力及应变速度下的特性数据,为形状记忆合金的应用提供了必要的参考。
简介:Inthisstudy,metallographicanalysisandnanoindentationcharacterizationwereusedtoanalyzethepropertiesandmicrostructuresofas-castnitrogenalloyed27Cr-7Ni-4Mosuperduplexstainlesssteel(super-DSS).Theas-castmicrostructureofthesuper-DSSwascharacterizedbyitsferriteandisland-likeaustenitephases.Duringthesolutionannealingprocess,theaustenitevolumepercentageofthesteeldecreasedgraduallywithincreasedannealingtemperature.Asamainelement,thechromiumcontentintheferriticandausteniticphaseselevatedslightlyatfirstthendecreasedwithincreasedannealingtemperature.Thechromiumpartitioncoefficientinthesteelvariedbyaround1.0.Thecontentsofnickel,anothermainalloyelement,alsoincreasedintheferriticandausteniticphaseswithincreasedannealingtemperature,asdidthenickelpartitioncoefficientinthesteel,whichtendedtobecloseto1.0.Thenanoindentationcharacterizationresultsindicatethatthehardnessoftheaustenitephaseisslightlygreaterthanthatoftheferritephase.Theyweresimilartoeachotherwithinacertaintemperaturerangefrom1050℃to1100℃.Thistemperaturerangewasconsistentwiththetemperaturerangeinwhichthecontentratioofthetwophaseswascloseto1∶1.WefoundtheYoung'smodulusoftheferritephasetobegreaterthanthatoftheaustenitephase.Withincreasedannealingtemperature,theYoung'smodulusoftheferritephasedecreasedwhilethatoftheaustenitephaseremainedalmostunchanged.
简介:Superduplexstainlesssteels(SDSS)showcomplexprecipitationandtransformationbehaviorduringheattreatmentprocesses,whichaffectsbothmechanicalandcorrosionproperties.ThisreportpresentssomedataonthemicrostructuresthatdevelopafterfoldingandsubsequentprecipitationduringheattreatmentofUNSS32750SDSSsheetsamples.ThemicrostructuralandtexturalchangeshavebeenfollowedusingSEM/EBSDtechniques.Uponfolding,bothatextureandstraingradientforminthefolded/bentregion,subsequentheattreatmentat845℃resultsintheferritephasetotransformtosigma,austeniteandchiphases.Transformationwasfoundtobeacceleratedbystrain.Completetransformationoftheferritephaseoccurredwithinhalftheannealingtimerequiredintheunstrainedregions.Thelocalmis-orientationsintheferriteandaustenitephasesreducedduringannealing,however,thereductionintheaustenitewasnotveryhighandasignificantamountremainedevenafterthelongestannealingtime.Thetexturecomponentsthatdevelopedduringthefoldingprocessremainedunchangedevenafteronehourannealingat845℃.TheimplicationofthesefindingscouldhaveabearingontheformationofsigmaphaseduringweldingofSDSSthatmayhaveresidualstressesintroducedduringfinalprocessing.
简介:β-Ti型结构的钛基材料在生物材料领域具有广泛的应用前景。本文采用机械合金化法和放电等离子烧结制备β-Ti型Ti-Nb基合金,研究不同Nb,Fe含量对合金显微组织及力学性能的影响。利用扫描电镜(SEM)、X射线衍射仪(XRD)和透射电镜(TEM)等手段分析合金的显微组织变化情况。结果表明:机械合金化过程中,粉末的平均粒度减小,当球磨时间超过60h时粉末易发生团聚。当球磨转速为300r/min,球料比为12:1,Ti和Nb的质量分数分别为64%和24%时,球磨100h后制备的粉体材料中具有一定体积的非晶相。该粉末在1000℃下通过放电等离子烧结(SPS)制备具有均匀细小的球状晶粒组织的Ti-Nb合金,其强度、伸长率和弹性模量分别为2180MPa,6.7%和55GPa。通过控制Nb,Fe的含量,可以促进β-Ti相形成,获得高强度和低杨氏模量的Ti-Nb合金。