简介:Nd_2Zr_2O_7isbeingexploredasanalternatethermalbarriercoating(TBC)materialforoperatingabove1300°C,andgreatefforthasbeenmadetoenlargeitsthermalexpansioncoefficient(TEC)andimproveitstoughness.Inthisstudy,Sc_2O_3wasdopedtoNd_2Zr_2O_7.Thephasestructure,TECsandtoughnessof((Nd_(1-x)Scx))_2Zr_2_O7(x=0,0.025,0.05,0.075,0.1)compoundswereinvestigated.((Nd_(1-x)Scx))_2Zr_2_O7(x=0,0.025,0.05,0.075)exhibitedpyrochlorestructure,while((Nd_(0.9)Sc_(0.1)))_2Zr_2O_7consistedofpyrochloreandfluoritephases.WiththeincreaseoftheSc_2O_3content,theorderingdegreeofthepyrochloreinthecompoundsdecreased.In((Nd_(1-x)Scx))_2Zr_2O_7series,((Nd_(0.925)Sc_(0.075)))_2Zr_2O_7exhibitedthelargestTEC,whilethetoughnessofthecompoundsincreasedwithincreasingtheSc_2O_3content.Therelatedmechanismswerediscussedbasedonthecrystalstructureanalysis.ConsideringtheTECandtoughness,10mol%Sc_2O_3wassuggestedastheoptimaldopingcontentforNd_2Zr_2O_7ceramic.
简介:介绍中美两国制冷空调行业协会在容积式CO2制冷压缩机(组)标准化合作方面的进展。对中国国家标准GB/T29030—2012《容积式CO2制冷压缩机(组)》和美国AHRI571:2012标准《容积式CO2制冷压缩机(组)性能评定》进行分析,主要从适用范围、试验工况、测试方法、试验参数及性能允差、计算参数、油循环率等方面对两国标准进行详细的对比。该分析研究有助于推进容积式CO2制冷压缩机(组)标准的国际化进程。
简介:本研究对3种低黏度添加剂作为2种环氧树脂体系增韧剂的性能进行了评价,2种环氧树脂体系1种为低活性的双酚A二缩水甘油醚(DGEBA)与胺类固化剂二乙基甲苯二胺体系,另1种为四缩水甘油基亚甲基二苯胺(TGDDM)环氧树脂与脂环族二胺类固化剂体系,所评价的增韧剂分别是端环氧基脂肪族聚酯型超支化聚合物、端羧基聚丁橡胶和端氧丙基硅氧烷。研究结果表明:端环氧基超支化聚酯可有效增韧低交联度的环氧树脂体系,即DGEBA基树脂体系,其最大的特点是添加剂对树脂体系的加工参数如黏度和凝胶时间无影响,当添加剂质量分数为15%时材料的断裂性能提高54%,同时对固化物的Tg无影响,该结果应归因于相分离产生的多相微粒形态能诱发粒子气穴化,同时使残余环氧树脂基本不溶解到固化后的连续环氧树脂基体中;橡胶类添加剂也可达到相同水平的增韧效果,但却会导致Tg下降10~20℃、初始黏度上升30%;硅氧烷类添加剂不能提高DGEBA基树脂体系的韧性,因为硅氧烷在环氧基体中分散性很差;对于TGDDM基树脂体系,3种添加剂均不能起到增韧作用。因为该环氧体系交联度过高而缺乏塑性形变。
简介:TheRamanspectraof3%(molefraction)Y2O3-ZrO2(3Y)areobtainedatdifferenttemperaturefrom77Kto853K.Theresultsshowthat260cm-1Egand460cm-1Egmodesonthespectrashifttowardlowerwavenumberwiththeincreaseoftemperature;meanwhile,thecontinuityoftheHalfWidthatHalfMaximum(HWHM)andwavenumber(frequency)ofRamanbandsarebrokenandt-phaseonlypartiallytransformstom-phaseat523K.Basedontheexperimentalresults,thispaperdiscussesthet-phaselatticevibrationof3YandpresentstheimagesofvibrationdisplacementofsixRaman-activemodesfort-phaseofZrO2.TheanalysisindicatesthattherearediversitiesexistinginthedisplacementoftheatomicvibrationofRaman-activemodesbecauseoftheirdifferentsymmetriesatvarioustemperature,whichleadstothedifferentchangetendenciesofRamanbands.Furthermore,theabruptchangesofsomeRaman-activemodesindicatingtheatomicdisplacementareassumedtobethecondensationsofphononmodesinthet→mphasetransition.