简介:我们证明认识到量重叠是可能的切换上并且离开在一个单个量点的强壮的轻事的相互作用--半导体microcavity系统。如此的重叠启用有条件的动力学完成的违反直觉的量的观察。状况是可能的象emitter光一样的洞光子显示指数的腐烂的地方,但是他们的联合察觉概率展出真空Rabi摆动。显著地,这些量关联也是在nonequilibrium的现在如此的协调地驾驶的消散的量系统的稳定的州的系列。
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简介:在在热退火之上的低精力和高剂量他植入6H-SiC的水泡进化被学习。面向的6H-SiC晶片在房间温度在11017厘米2的剂量与15个keV氦离子被植入。样品与培植以后为30min在1073,1173,1273,和1473K的温度被退火。他在晶片起泡经由代表性的传播被检验电子显微镜学(XTEM)分析。nanoscale水泡在同样植入的样品的损坏的层是几乎同类地分布式的在场的结果,和没有重要变化在退火的1073K以后在他植入样品被观察。在退火的1193K之上,在6H-SiC的He-implantation-inducedamorphization的几乎完整的再结晶被观察。另外,直径他起泡显然增加。与不断地增加温度到1273K和1473K,直径他起泡增加和格子缺点的数字密度减少。生长在退火的高温度接受成熟的Ostwald以后,他起泡机制。吝啬的直径他作为退火的一个函数在120-135nm的深度定位的水泡温度被装入产出1.914+0.236eV的一个激活精力的热激活的进程的术语。
简介:Theabinitiogeneralizedgradientapproximation(GGA)+Ustudyofmultiferroic(La0.5Bi0.5)2FeCrO6inpnmastructureandferri-magneticorder,includingHubbardcorrections(U-4.1eV)fortransitionmetal/rareearthd-electronswith20atomscell,showsoptimumlocalmagneticmomentsof(Cr^3+,Fe^3+)equalto(-2.56,4.14)#Bandanidealspin-downbandgapof1.54eV.Tuned-bandgapLa-substituteddoubleoxideperovskitesBFCOshouldexhibitenhancedvisible-lightabsorptionandcarriermobility,thuscouldbeconvenientlightabsorbersandthenefficientalternativestowide-gapchalcopyriteabsorber-basedsolarcellsfailingtoachievehighestpowerconversionefficiencies,andevencompetewiththeirmetal-organichalideperovskitescounterparts.
简介:Theneworganic-inorganiccompound,[C_6H_7N_2O_2]_3TeCl_5·2Clwassynthesizedanditsstructurewasdeterminedatroomtemperatureinthetriclinicsystem(P~-1)withthefollowingparameters:a=10.5330(11)?,b=10.6663(11)?,c=15.9751(16)?,α=82.090(2)°,β=71.193(2)°,γ=68.284(2)°andZ=2.ThefinalcycleofrefinementledtoR=0.057andRw=0.149.ThecrystalstructurewasstabilizedbyanextensivenetworkofN--H···Clandnon-classicalC--H···Clhydrogenbondsbetweenthecationandtheanionicgroup.Severalthermalanalysistechniquessuchasthermogravimetricanalysis,differentialscanningcalorimetricanalysisandevolvedgasanalysiswereused.Weusedisoconversionalkineticsmethodstodeterminethekineticsparameters.Weobservethatthedecompositionof[C_6H_7N_2O_2]_3TeCl_5·2Clentailstheformationhydrochloricacidofnitroanilineasvolatiles.Theinfraredspectrawererecordedinthe4000–400cm~(-1)frequencyregion.TheRamanspectrawererecordedintheexternalregionoftheanionicsublatticevibration50–1500cm~(-1).TheopticalbandgapwascalculatedfromtheUV-VisabsorbancespectrausingclassicalTaucrelationwhichwasfoundtobe3.12and3.67eV.