学科分类
/ 1
4 个结果
  • 简介:本文给出任意有限维全微分方程的判定定理与求通解的一种方法。定理的条件是充要的。判断与求通解是同步进行的,方法简单,运用方便。解决了高维全微分方程的判断与求通解的困难。

  • 标签: 全微分方程 M_ndx_n=0 判定定理 有限维 求通 变元
  • 简介:本文首先给出integralfromato+∞f(x)dx收敛≠lim+∞f(x)=0的一更强的例子,然后给出一个与级数收敛的必要条件类似的,integralfromato+∞f(x)dx收敛的必要条件。在许多工科高等数学教材中,广义积分敛散性的判别,一般都在级数中讨论,因而一部分同学和个别教师往往把级数的一些重要性质,直接推广到广义积分integralfromato+∞f(x)dx上。最典型的错误是把级数收敛的必要条件推广到广义积分上,即integralfromato+∞f(x)dx收敛?lim?+∞f(x)=0.这类错误较为普遍。

  • 标签: 广义积分 to x)dx 级数收敛 敛散性 被积函数
  • 简介:Effectsofself-coilingoforganicmoleculesonintramolecularexciplexformationofcompoundI,inwhichthecarbazolechromophoreandterephthalicacidmethylesteracceptorgrouparelinkedbyone(CH2)10chain,andthedecreaseofthefluorescenceintensitiesofcompoundsⅡ,Ⅲ,andⅣ,inwhichthecarbazolechromophoreand3,5-dinitrobenzoateareconnectedbyonealiphaticchainof(CH2)10(Ⅱ),(CH2)12(Ⅲ),or(CH2)4(Ⅳ),havebeenstudiedinthedioxane(DX)-H2Obinarysystem.Theresultsshowthatself-coilingoforganicmoleculesinDX-H2OfacilitatesintramolecularexciplexformationofIandinducesthedecreaseoffluorescenceintensitiesofⅡ,bacauseoftheproximityeffectbroughtaboutbyselfcoilingoforganicmoleculesunderhydrophobic-lipophilicinteraction(HLI)betweentheexcitedcarbazolechromophoreandtheacceptor.SincethesimilareffectsareobservedevenwhentheconcentrationoftheprobesarelessthantheirCAgCs(criticalaggregateconcentrations)intheDX-H2Omixturewiththesameφvalues,formationoftheintermolecularexciplexhasbeenexcluded.Theeffectsarefoundtobestronglydependedonφvalues,indicationthattheyaremainlydrivenbyHLI.Thepropertiesoftheacceptorscanalsoaffecttheintramolecularexciplexformation.Withterephthalicacidmethylestermoietyastheacceptor,thecarbazolechromophoreexhibitsthefluorescencespectraoftheexciplex,whilewith3,5-dinitrobenzoatemoietyastheacceptor,onlythefluorescencespectraofexcitedcarbazolylchromophoreareobserved.

  • 标签: 有机分子 荧光性 自卷绕成卷 分子内激态复合物 憎水性-亲油性相互作用