学科分类
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8 个结果
  • 简介:香港创作单位sbya-la-la在平面设计,产品包装等媒体创作上享有盛名,单位中极具代表性的摄影师Wing,Shya操刀是装声国际,这次首度跟日本年青时装品牌A/T来个3-D交叉合作,由sbya-la-la负责款式和图案设计,Wing.Shya操九目录摄影,更邀请了日籍名模RilsOkazorri亲身演绎,在各方实力单位共同努力下,一只名叫Grabbitl的粉紫小兔诞生了。

  • 标签: 演绎 平面设计 产品包装 WING 时装品牌 图案设计
  • 简介:Inthispaper,MPt/C(M=La,Nd)catalystsofPEMFCweresynthesizedbymicrowaveradiationprocess.ThecrystallinityandstructureofcatalystswererespectivelyanalyzedbyXRDandnitrogenadsorptiontests.Theactivityofcatalystswasinvestigatedbyelectrochemistryexperiment.Theresultsshowedthat:1)comparedwithPt/Ccatalystpreparedbytypicalimpregnation-reductionprocess,thesizeofMPt/CcatalystparticledecreasedandtheavailablecrystalforO2reductionincreased;2)theMPt/CcatalystshadrelativelyhighBETsurfaceareas;and3)thesecrystaltransformationsoftheMPt/Ccatalystbroughthightheelectrocatalyticactivity,andasaresult,improvedthepowerofPEMFC.

  • 标签: 合成 微波辐射 聚合物电解质膜燃料电池 催化剂 X射线衍射 氮吸附试验
  • 简介:ThepartialoxidationofethanoltohydrogenwasinvestigatedoverNi/Fe/Lacatalystspreparedbytheco-precipitationmethod.TheeffectsofintroductionofLapromoterandthereactiontemperatureonthecatalyticperformancewerestudied.ItwasfoundthattheintroductionofLaintoNi/Fecatalystsishelpfultoincreasetheselectivitytohydrogenandthestabilityofthecatalysts.TheresultsofXRDandXPScharacterizationshowthatthestructureofthecatalystwaschangedduringthereaction.TheexistenceofLaFeO3speciesispossiblythemainreasonoftheincreaseofthecatalyststability.

  • 标签: 乙醇 局部氧化 镍/铁催化剂 氢转移
  • 简介:Thebilayerorganiclight-emittingdiode(OLED)withabluefluorescentlanthanumcomplex,tris(1-phenyl-3-methyl-4-isobutyryl-5-pyrazolone)-(2,2′-dipyridyl)lanthanum[La(PMIP)3(Bipy)],asalightemittingmaterialandN,N′-diphenyl-N,N′-bis(3-methylphenyl)-1,1′-biphenyl-4,4′-diamine(TPD)asaholetransportingmaterialemitsbrightgreenlightinsteadofbluelight.Thedataoftheabsorption,thephotoluminescence(PL)andthephotoluminescenceexcitation(PLE)spectraofTPD,La(PMIP)3(Bipy)andthemixtureofTPDandLa(PMIP)3(Bipy)(molarratio1∶1)provethattheelectroluminescentemissionoriginatesfromtheexciplexontheinterfacebetweenTPDandLa(PMIP)3(Bipy).Byimprovingdeviceconfigurationwithtris(8-hydroxyquinoline)aluminum(ALQ)asanelectrontransportingmaterial,amaximumluminanceof800cd/m2wasobtained.

  • 标签: 电致发光 光致发光 镧配合物 双分子层有机发光二极管 1-苯基-3-甲基-4-异丁酰-5-吡唑啉酮)- (2 2'-二吡啶基)
  • 简介:ThetemperaturedependenceofresistivityρofYSZdopingcompositeof(1-x)La0.67Ca0.33MnO3+xYSZandY2O3dopingcompositeof(1-y)La0.67MnO3+yY2O3isinvestigated,respectively,inatemperaturerange77-300K,wheretheYSZrepresentsyttria-stabilizedzirconia(8mol%Y2O3+92mol%ZrO2).ExperimentalresultsshowthattheYSZdopinglevelhasimportanteffectsonboththemetal-insulator(M-I)transitiontemperaturesandzerofieldresistivityofthecompositesof(1-x)La0.67Ca0.33MnO3+xYSZ.However,theY2O3dopinglevelhaslittleeffectontheM-Itransitiontemperaturesandthezerofieldresistivityof(1-y)La0.67Ca0.33MnO3+yY2O3onlyincreasesslightly.Thedifferencebetweenthetwotypesofcompositesmaymainlyresultsfromthedifferentdistributionofhighresistancephasesatthegrainboundariesand/orsurfacesofLa0.67Ca0.33MnO3grainsratherthanthesubstitutionofLa^3+ionswithY^3+ions.

  • 标签: LA0.67CA0.33MNO3 镧钙锰氧化物 巨磁致电阻效应 磁性材料 温度 高阻相效应
  • 简介:采用微波合成法制备了含掺杂P,Al和La元素的正极材料LiCoO2,确定了工艺条件,包括反应时间、微波功率和反应温度.采用XRD,SEM和电化学测试仪研究了添加元素对LiCoO2结构和电化学性能的影响.研究发现,微波功率和反应时间对产物的结构有比较明显的影响.充放电试验结果表明,掺加La元素正极材料LiCoO2首次充放电容量达到了130mAh·g^-1.

  • 标签: 掺杂 锂离子电池 正极材料 微波合成
  • 简介:Thetitlecomplex,[La(baec)1/2(H2btec)1/2(H2O)]n(H4btec=1,2,4,5-benzenetetracarboxylicacid)(1)wassynthesizedbythehydrothermalreactionof1,2,4,5-benzenetetracarboxylicdianhydridewithLa(NO3)3·6H2OinH2O,andcrystallizesinthetriclinicsystem,spacegroupP-1withα=0.64403(3)nm,b=0.94500(4)nm,c=0.96380(5)nm,α=88.535(2)°,β=100.314(2)°,γ=76.6470(10)°,V=1.69968(10)nm^3,Z=2,andfinalR=0.0274,Rw=0.0735.In1,eachLa(Ⅲ)ioniscoordinatedbyeightoxygenatomsfromsixcarboxylategroupsandonecoordinatedwatermolecule.TwodifferentcoordinstionmodesofH4btecwerePresentinthestructure,oneofwhichcontainstwoprotonatedcarboxylategrougpstobalancethecharge.

  • 标签: 水热合成 镧配合物 结构 1 2 4 5-苯四羧酸