简介:Thepolymerizationof1-octeneinitiatedbymethylalumoxane(MAO)-activatedNi(Ⅱ)-based-α-diiminecomplexes[(2,6-i-Pr)_2C_6H_3-DAB(An)]NiBr_2wasinvestigated.Usingthiscatalyst,poly(1-octene)swithmolecularweightbetween100×10~3and400×10~3andpolydispersity(M_w/M_n)between1.3and1.5weresynthesizedsuccessfullybyvaryingreactiontimeatroomtemperature.Thepoly(1-octene)swereamorphouspolymersandcouldbewellsolubleintetrahydrofuran(THF).Afterfractionalprecipitation,poly(1-octene)swithnarrowmolecularweightdistributions(M_w/M_n≤1.12)wereobtained.Theirweight-averagemolecularweightsweremeasuredbygelpermeationchromatography(GPC)inconjunctionwithonlinemodelBI-MwAmultianglelaserlightscattering(MALLS),andtheirintrinsicviscositiesweremeasuredbyMaron'ssingle-pointmethod.ThekandavaluesinMark-Houwinkequation[η]=KM~αinTHFat40℃were0.089mL/gand0.61respectively.
简介:本文推广了文献[1]的方法,给出了定数截尾情况下两参数Weibull分布的形状参数的区间估计,并通过大量的Monte—Carlo模拟考察了优选问题。另外还讨论了两参数的联合区间估计。文章最后通过实例说明了本文方法的应用。
简介:O484.599042623用喇曼散射光谱估算纳米Ge晶粒平均尺寸=Estimationofcrystal—sizeofnano—GebyRamanscatteringspectra[刊,中]/王印月,郑树凯,杨映虎,郭永平(兰州大学物理系.甘肃,兰州(730000)),奇莉,甘润今(北京机械工业学院基础部.北京(100085))//光学学报.—1998,18(9).—1265—1268用射频共溅射技术和真空退火方法制备了埋入SiO2基底中的纳米Ge复合膜(nc—Ge/SiO2。测量了不同温度退火后该复合膜的喇曼散射光谱,其结果与晶体Ge的喇曼谱相比,纳米Ge的喇曼峰位红移峰形变宽;用喇曼谱的参数计算了纳米Ge晶粒的平均尺寸。所得
简介:O484.52003053772厚度具有线性变化的吸收平板或膜层的非相干透射率和反射率=Incoherenttransmissivityandreflectivityofanabsorbingplaneplateorlayerwithlinearvariationsinthickness[刊,中]/钟迪生(辽宁大学物理系.辽宁,沈阳(110036))//应用光学.-2002,23(1).-40-43计算了垂直入射下厚度具有线性变化的吸收平板样品的非相干透射率和反射率(正面和反面),给出了直接确定无基底样品以及透明基底上薄膜能量(强度)系数的精确表达式。图3参3(郑锦玉)