学科分类
/ 2
24 个结果
  • 简介:ThelasersystemPALS,asadriverofabroad-beamionsource,delivereddeuteronswhichgeneratedneutronswithenergieshigherthan14MeVthroughthe7Li(d,n)8Bereaction.Deuteronswithsub-MeVenergywereacceleratedfromthefrontsurfaceofamassiveCD2targetinthebackwarddirectionwithrespecttothelaserbeamvector.Simultaneously,neutronswereemittedfromtheprimaryCD2targetandasecondaryLiFcatcher.Thetotalmaximummeasuredneutronyieldfrom2D(d,n)3He,7Li(d,n)8Be,12C(d,n)13Nreactionswas~3.5(±0.5)×108neutrons/shot.

  • 标签: beam–target fusion DEUTERONS laser ion SOURCES
  • 简介:ExplicitexpressionsofMori-Tanaka’stensorforatransverselyisotropicfiberreinforcedUDcompositearepresented.Closed-formformulaefortheeffectiveelasticpropertiesofthecompositeareobtained.Ina3Dsense,theresultingcompliancetensorofthecompositeissymmetric.Nevertheless,the2DcompliancetensorbasedonadeterioratedMori-Tanaka’stensorisnotsymmetric.Noristhecompliancetensordefineduponadeteriorated2DEshelby’stensor.Thein-planeeffectiveelasticpropertiesgivenbythosethreeapproachesaredifferent.AdetailedcomparisonbetweenthepredictedresultsobtainedfromthoseapproacheswithexperimentaldataavailableforanumberofUDcompositesismade.更多还原

  • 标签: 柔度张量 注记 复合材料 横观各向同性 弹性性质 显式表达
  • 简介:QuantumdynamicscalculationsforthetitlereactionH(2S)+S2(X3-Σg)→SH(X2Π)+S(3P)areperformedbyusingagloballyaccuratedoublemany-bodyexpansionpotentialenergysurface[J.Phys.Chem.A1155274(2011)].TheChebyshevrealwavepacketpropagationmethodisemployedtoobtainthedynamicalinformation,suchasreactionprobability,initialstate-specifiedintegralcrosssection,andthermalrateconstant.Itisfoundnotonlythatthereisareactionthresholdnear0.7eVinbothreactionprobabilitiesandintegralcrosssectioncurves,butalsothatboththeprobabilityandcrosssectionincreasefirstlyandthendecreaseasthecollisionenergyincreases.Theexistenceoftheresonancestructureinboththeprobabilityandcrosssectioncurvesisascribedtothedeeppotentialwell.Thecalculationoftherateconstantrevealsthatthereactionoccurringonthepotentialenergysurfaceoftheground-stateHS2isslowtotakeplace.

  • 标签: 反应概率 动力学计算 上海 量子 表面 截面曲线
  • 简介:ThispaperpresentsaclosedformsolutionandnumericalanalysisforEshelby’sellipticinclusioninaninfiniteplate.Thecomplexvariablemethodandtheconformalmappingtechniqueareused.Thecontinuityconditionsforthetractionanddisplacementalongtheinterfaceinthephysicalplanearereducedtothesimilarconditionsalongtheunitcircleofthemappingplane.Thepropertiesofthecomplexpotentialsdefinedinthefiniteellipticregionareanalyzed.Fromthecontinuityconditions,onecanseparateandobtaintherelevantcomplexpotentialsdefinedintheinclusionandthematrix.Fromtheobtainedcomplexpotentials,thedependenceoftherealstrainsandstressesintheinclusionfromtheassumedeigenstrainsisevaluated.Inaddition,thestressdistributionontheinterfacealongthematrixsideisevaluated.Theresultsareobtainedinthepaperforthefirsttime.

  • 标签:
  • 简介:采用密度泛函理论的B3LYP方法、从头算的MP2方法和自洽反应场极化连续模型(PCM),在6-311++G(2d,2p)基组水平上研究了N,N’-二甲基-S-异苯并呋喃在气相和溶液中发生S→N烷基重排反应的机理、溶剂效应和取代基效应.结果表明:该反应通过四元环机理和双位迁移机理生成产物,在气相和溶剂水中,双位迁移途径的能垒均比四元环途径低,反应主要通过双位迁移途径生成产物.在气相,苯环上发生-Cl,-NO2和-OCH3取代时,双位迁移途径的能垒在MP2/6-311++G(2d,2p)水平上比没有取代时分别低4.18,7.61,4.96kJ/mol,反应的取代基效应不明显.而在溶剂水中,苯环上发生-Cl,-NO2和-OCH3取代时,双位迁移途径的能垒在PCM-MP2/6-311++G(2d,2p)水平上比气相时分别低37.73,39.96和37.17kJ/mol,反应的溶剂化效应非常明显.理论研究结果与实验观察结果一致.

  • 标签: N N’-二甲基-S-异苯并呋喃 S→N烷基重排 溶剂化效应 反应机理 密度泛函理论
  • 简介:在吝啬地的三地点的BoseHubbard模型以内,偶极的bosonic气体与的通道动力学一周期性地,散布的s波浪的调整被调查。系统经历通道(CDT)的协调破坏转移在下邻居偶极子偶极子相互作用,所在地的相互作用和散布的调制s波浪之中源于相关效果的复杂、富有的协调通道(CT)。特别地,为产生CT(CDT)散布的调制s波浪的区域是最宽(最狭窄)什么时候所在地的相互作用和下邻居偶极子偶极子相互作用一些相关与通道精力和系统的相互作用精力有关仔细珍视,它是。为出现CDT的相关的值能理论上从通道精力和系统的相互作用精力被获得。

  • 标签: 偶极相互作用 周期性调制 玻色系统 隧道掘进 波散射 HUBBARD模型
  • 简介:Veryrecently,BelleannouncedtheirobservationofΥ(5S)!bJ!(J=0;1;2),indicatingthattheΥ(5S)!bJ!decaysalsohavelargedecaywidths,i.e.,themeasuredbranchratiosofΥ(5S)!bJ!are<3:410??3,(1:640:23+0:30??0:22)10??3,and(0:570:220:07)10??3withJ=0;1;2,respectively[1].ItshouldbenoticedthateventhoughthetreelevelcontributionstoΥ(5S)!bJ!(J=0;1;2)shouldbestronglysuppressedduetotheOkubo-Zweig-Iizuka(OZI)rule,suchlargedecaywidthsareobserved,whichagaininspiresourinterestinunderstandingsuchquantities.Inthiswork,weproposethatthecontributionfromthehadronicloopshouldbeconsideredinstudyingΥ(5S)!bJ!.

  • 标签: LOOP LOOP BE OUR IT
  • 简介:AnovelSr2CuInO3Soxysulfidep-typesemiconductorphotocatalysthasbeenpreparedbysolidstatereactionmethodanditexhibitsintriguingvisiblelightabsorptionpropertieswithabandgapof2.3eV.Thep-typesemiconductorcharacterofthesynthesizedSr2CuInO3SwasconfirmedbyHallefficientmeasurementandMott-Schottkyplotanalysis.First-principlesdensityfunctionaltheorycalculations(DFT)andelectrochemicalmeasurementswereperformedtoelucidatetheelectronicstructureandtheenergybandlocations.Itwasfoundthattheas-synthesizedSr2CuInO3Sphotocatalysthasappreciateconductionandvalencebandpositionsforhydrogenandoxygenevolution,respectively.Photocatalytichydrogenproductionexperimentsunderavisiblelightirradiation(λ>420nm)werecarriedoutbyloadingdifferentmetalandmetal-likecocatalystsonSr2CuInO3SandRhwasfoundtobethebestoneamongthetestedones.

  • 标签: 半导体光催化剂 可见光照射 Mott-Schottky图 P型 制氢 密度泛函理论
  • 简介:Thedevelopment,theunderlyingtechnologyandthecurrentstatusofthefullydiode-pumpedsolid-statelasersystemPOLARISisreviewed.Currently,thePOLARISsystemdelivers4Jenergy,144fslonglaserpulseswithanultra-hightemporalcontrastof5×1012fortheASE,whichisachievedusingaso-calleddoublechirped-pulseamplificationschemeandcross-polarizedwavegenerationpulsecleaning.Bytightlyfocusing,thepeakintensityexceeds3.5×1020Wcm-2.TheseparameterspredestinePOLARISasascientifictoolwellsuitedforsophisticatedexperiments,asexemplifiedbypresentingmeasurementsofacceleratedprotonenergies.Recently,anadditionalamplifierhasbeenaddedtothelaserchain.Intheramp-upphase,pulsesfromthisamplifierarenotyetcompressedandhavenotyetreachedtheanticipatedenergy.Nevertheless,anoutputenergyof16.6Jhasbeenachievedsofar.

  • 标签: design high power LASER LASER amplifiers
  • 简介:目前,国内没有关于半钢发热剂的国家标准检测方法,只能根据组分范围分别检测各个组分,不仅耗时而且使用的大量化学试剂对环境造成污染。故研究了X-射线荧光光谱法快速测定半钢发热剂中Si,P,S的方法。采用粉末压片制样,研究其制样条件,包括磨样时间、压样时间和压力对测定结果的影响。采用其它方法定值提供的检测样品,作为x-射线荧光光谱法内控标准样品,采用经验系数法进行基体校正,通过解谱拟合建立校准曲线,校准曲线建立后仪器建立漂移校正程序。实验结果精密度好,各元素的相对标准偏差在0.15%-1.3%。准确度满足生产需求,实验方法可用于快速检测半钢发热剂化学组分。

  • 标签: X-射线荧光光谱法 快速测定 半钢发热剂 方法研究