简介:TheNi-AlalloycontainingCr,FeadditiveswerepreparedasRaneyNiCatalystbyhighenergymilling.ThesizeandsurfacestateofNi-Alalloypowderwerestudiedbyparticlesizeanalyzerandsanningelectronmicroscopy.theStructurewasanalyzedbyXRDandMoessbauermethods.Theresultsshowedthatafterahigh-energymilling(HEM).theNi-Alalloytransformstoanano-scaleNiAlstructurewithrichAl.Byannealingthealloy,ametastableNi2Al3phasecanbeobtained.
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简介:Inordertotransfertheheatfromthearmortothecoolant,tungstenhastobeconnectedwithacopperheatsink.Thejointtechnologyisthemostcriticalissueformanufacturingplasmafacingcomponents.Consequently,thereliabilityofthejointsshouldbeverifiedbyagreatnumberofhigh-heat-flux(HHF)teststosimulatetherealloadconditions.W/CubrazedjointtechnologywithsliverfreefillermetalCuMnNihasbeendevelopedatSouthwesternInstituteofPhysics(SWIP).Screeningandthermalfatiguetestsofonesmall-scaleflattileW/CuCrZrmockupwereperformedona60kWelectron-beamMaterialtestingscenario(EMS-60)constructedrecentlyatSWIP.Themodulesuccessfullysurvivedscreeningtestwiththeabsorbedpowerdensity(Pabs)of2MW/m2to10MW/m2andthefollowing1000cyclesatPabsof7.2MW/m2withouthotspotsandoverheatingzonesduringthewholetestcampaign.MetallurgyandSEMobservationsdidnotfindanycracksatbothsidesandtheinterface,indicatingagoodbondingofWandCuCrZralloy.Inaddition,finiteelementsimulationsbyANSYS12.0underexperimentalloadconditionswereperformedandcomparedwithexperimentalresults.
简介:Inthisstudy,tungsten(W)wascoatedonacopper(Cu)substratebyusingdouble-glowdischargetechniqueusingapureWpanelasthetargetandargon(Ar)asthedischargeandsputteringgas.ThecrystalstructureoftheWcoatingwasexaminedbyX-raydiffraction(XRD).Scanningelectronmicroscopy(SEM)wasperformedwithcross-sectionimagestoinvestigatethepenetrationdepthofWintotheCubody.Additionally,thepropertiesofwearabilityresistance,corrosionresistanceandmechanicalstrengthoftheWcoatedCumatrixwerealsomeasured.Itisconcludedthatindouble-glowplasma,WcoatedCucanbefacilelyprepared.ItisnoticedthatthetreatmenttemperatureheavilydominatesthepropertiesoftheW-Cucomposite.
简介:Chemicalvapordeposition-tungsten(CVD-W)coatingcoveringthesurfaceoftheplasmafacingcomponent(PFC)isaneffectivemethodtoimplementthetungstenmaterialasplasmafacingmaterial(PFM)infusiondevices.ResidualthermalstressinCVD-Wcoatingduetothermalmismatchbetweencoatingandsubstratewassuccessfullysimulatedbyusingafiniteelementmethod(ANSYS10.0code).Thedepositionparametriceffects,i.e.,coatingthicknessanddepositiontemperature,andinterlayerwereinvestigatedtogetadescriptionoftheresidualthermalstressintheCVD-Wcoating-substratesystem.AndtheinfluenceofthesubstratematerialsonthegenerationofresidualthermalstressintheCVD-WcoatingwasanalyzedwithrespecttotheCVD-WcoatingapplicationasPFM.ThisanalysisisbeneficialforthepreparationandapplicationofCVD-Wcoating.
简介:TheaccumulationofHeonaWsurfaceduringkeV-Heionirradiationhasbeensimulatedusingclusterdynamicsmodeling.Thisisbasedmainlyonratetheoryandimprovedbyinvolvingdifferenttypesofobjects,adoptingup-to-dateparametersandcomplexreactionprocesses,aswellasconsideringthediffusionprocessalongwithdepth.Thesenewfeaturesmakethesimulatedresultscompareverywellwiththeexperimentalones.Theaccumulationanddiffusionprocessesareanalyzed,andthedepthandsizedependenceoftheHeconcentrationscontributedbydifferenttypesofHeclustersisalsodiscussed.TheexplorationofthetrappinganddiffusioneffectsoftheHeatomsishelpfulinunderstandingtheevolutionofthedamagesinthenear-surfaceofplasma-facingmaterialsunderHeionirradiation.
简介:CO2adsorptiononthesurfaceofhydrotalcite-derivedmixedoxidecatalystswasinvestigatedunderlowpressureglowdischargeplasmainopercindoconditionsviaFT-IRspectroscopy.Nickelcatalystswerepromotedwithvarioustransitionmetalspecies(Ce,Fe,La,Zr)toinfluencetheirphysico-chemicalproperties.FeandZrspeciesweresuccessfullyincorporatedintohydrotalcitebrucitelayers.AftercalcinationformedasinglephasewithNi(Mg,A1)Omixedoxide,whileLaandCespeciesformedseparatephases.ThishadaconsequenceinthedistributionofsurfacebasicsitesaswellasintheaffinitytoCOproduceduponCO2dissociationinplasma.Plasmatreatmentactivatedthesurfaceofpreparedmaterialsandchangedtheirpropertiesviathegenerationofstrongbasicsitesassociatedwithlowcoordinatedsurfaceoxygenanions.Moreover,theCO2adsorptioncapacityofpreparedmaterialsincreasedafterplasmatreatment.