简介:Cadmiumzincleadsulfide[Cd0.8(Zn1-x,Pbx)0.2S]nano-powderswerepreparedbyanimprovedcoprecipitationmethod.TheeffectofPb2+concentrationat500ConthephaseandcrystallinestructureoftheCd0.8(Zn1-x,Pbx)0.2SpowderswereinvestigatedbyX-raydiffraction(XRD).Accordingtothetransmissionelectronmicroscopy(TEM)images,theparticlessizeareintherangeof58nmto72nm.Inaddition,opticalbandgapenergyandopticalconstantsofnano-powdersweredeterminedusingtheultraviolet(UV)spectrum,Fourniertransforminfraredspectroscopy(FTIR),andKramers-Kroniganalysis,respectively.Wecalculatetherefractiveindexn,extinctioncoefficientk,anddielectricfunctionεasafunctionofthewavenumber.TheexperimentresultsdemonstratethattheamountofPb+2hasbeenplayinganincreasinglyimportantroleonopticalpropertiesofCZPSnanocrystals.