简介：Aseriesofpolybenzoxazoles(co)polymersbearingcrankshaftunitsinthemainchainwassynthesizedbytheconventionalsolutionpolycondensationof4,6-diaminorescinoldihydrochloride,terephthalicacid(TA)and2,6-naphthalenedicarboxylicacid(NDA).Allofthepolymersshowlyotropicliquidcrystalbehaviorinpolyphosphoricacid(PPA)andmethanesulfonicacid(MSA).Thepolybenzoxazolesexhibitanexcellentthermalresistancealthoughthecrankshaftmonomerhasbeenintroducedintothepolymerbackbone.Thetemperatureforthe5%weightlossofallthepolymersisabove600℃.TheX-raydiffractionanalysisresultsshowthattheseriesofthepolymershasahighcrystallinity.TheintroductionofNDAmakesaslightdecreaseinthethermalresistanceofthepolymers.ThemaximumabsorptionpeakintheUV-Visspectracanbeadjustedaccordingtotheamountof2,6-naphthaleneunitsinthepolymers,whichindicatesthepotentialapplicationofthepolymersasoptoelectriematerials.

简介：Theorientationalorderoftwoliquidcrystals,namely,6-［4-(4-nitrophenylazo)phenyloxy］hexyldiethanolamines(C6)and10-1-bromo［4-(nitrophenylazo)phenyloxy］alkane(B10)wasstudiedbymeansof2HNMRspectroscopywithhexamethylbenzene-d18astheprobemolecule.TheresultsshowthatthedirectorsinthesmecticAphaseofC6andthenematicphaseofB10couldbealigned,whichwasparalleltothemagneticfield.TheorientationalorderparameterofthesolutemoleculesinC6wasabout0.2,whileitisonly0.1inB10,whichisexpectedbecausethemoreorderedsmecticphasetendstoalignsolutemoleculestoahighlevel.ComparedtotheorientationalorderparameterofthesoluteintheSmCphaseof4［3,4,5-tris(4-dodecyloxybenzyloxy)-benzoyloxy］-4-(4′-dodecyloxybenzoyloxy)biphenyl(Ⅰ)(P2=0.14),itislargerinSmAphaseofC6.TherelativelyhigherorientationalorderparameterofthesoluteinC6isattributedtotheformationofintermolecularH-bondsintheSmAphaseofC6.

简介：Fe2O3/activecarbon(Fe2O3/AC)nanocompositeswerereadilyfabricatedbypyrolyzingFe3+impregnatedactivecarboninanitrogenatmosphere.Theas-preparedcompositeswerestudiedbyX-raypowderdiffraction(XRD),X-rayphotoelectronspectroscopy(XPS)andtransmissionelectronmicroscopy(TEM).Thecapacitivepropertyofthecompositeswasinvestigatedbycyclicvoltammetry(CV)andgalvanostaticcharge-dischargetest.Physicalcharacterizationsshowthattheγ-Fe2O3finegrainsdispersedintheACwell,withameansizeof21.24nm.Electrochemicaltestsin6mol/LKOHsolutionsindicatethattheas-preparednanocompositesexhibitedimprovedcapacitiveproperties.Thespecificcapacitance(SC)ofFe2O3/ACnanocompositeswasupto188.4F/gthatwasderivedfrombothelectrochemicaldouble-layercapacitanceandpseudo-capacitance,whichwas78%largerthanthatofpristineAC.AsymmetriccapacitorwithFe2O3/ACnanocompositesaselectrodeshowedanexcellentcyclingstability.TheSCwasonlyreducedbyafactorof9.2%after2000cyclesatacurrentdensityof1A/g.

简介：Aseriesofaromaticimineswerereducedtocorrespondingaminesinexcellentyieldsby2-phenyl-N,N-dimethylbenzimidazoline(PDMBI)photochemicallyinthepresenceofmagnesiumperchloride(Mg(ClO4)2).AMg2+mediatedphotoinducedelectrontransfermechanismwasproposed.

简介：Anovelflower-likehydratedmagnesiumcarbonatehydroxide,Mg_5(CO_3)_4(OH)_2·4H_2O,withmicro-structurecomposedofindividualthinnano-sheetswassynthesizedusingafacilesolutionroutewithouttheuseoftemplateororganicsurfactant.Reactiontimehasanimportanteffectonthefinalmorphologyoftheproduct.Themicro-structureandmorphologyofMg_5(CO_3)_4(OH)_2·4H_2OwerecharacterizedbymeansofX-raydiffractometry(XRD),field-emissionscanningelectronmicroscopy(FE-SEM).Brunauer-Emmett-Teller(BET)surfaceareasofthesampleswerealsomeasured.Theprobableformationmechanismofflower-likemicro-structurewasdiscussed.ItwasfoundthatMg_5(CO_3)_4(OH)_2·4H_2Owithflower-likemicro-structurewasanovelandefficientcatalystforthesynthesisofdiphenylcarbonate(DPC)bytransesterificationofdimethylcarbonate(DMC)withphenol.

简介：韩国蔚山，2007年10月11日一继本年度早些时候推出的一系列新型抗氧化剂和紫外光吸收剂后，日前，松原集团再次高兴地宣布，将进一步扩充这一关键产品范围，以满足专业的行业需求。这些新产品在2007年K展6号馆C79展台上展出，新产品包括：

简介：Quasiclassicaltrajectorycalculation(QCT)isusedfrequentlyforstudyingcollisionalenergytransferbetweenhighlyvibrationallyexcitedmoleculesandbathgases.Inthispaper,theQCToftheenergytransferbetweenhighlyvibrationallyexcitedC6F6andN2,O2andgroundstateC6F6wereperformed.TheresultsindicatethathighlyvibrationallyexcitedC6F6transferredvibrationalenergytovibrationaldistributionofN2,O2andgroundstateC6F6,sotheyareV-Venergytransfer.EspeciallyitismainlyV-VresonanceenergytransferbetweenexcitedC6F6andgroundstateC6F6,excitedC6F6transfersmorevibrationalenergytogroundstateC6F6thantoN2andO2.ThevaluesofQCT,-〈△Evib〉ofexcitedC6F6aresmallerthanthoseofexperiments.

简介：研究了考虑溶剂效应后2,1,3-苯并噻二唑衍生物中S原子被CH2—、O—和NH—取代引起的电子性质和光谱性质的变化,结果表明,与母体分子相比,O—取代引起的最高占据轨道能量(EHOMO)和最低空轨道能量(ELUMO)的变化很小,而CH2—和NH—取代引起的EHOMO和ELUMO的变化较明显,且CH2—和NH—取代后分子EHOMO的变化小于ELUMO的变化.CH2—取代导致最大吸收波长(λabs)和最大发射波长(λem)明显红移,而O—和NH—取代导致λabs和λem明显蓝移;而且取代后分子的吸收和发射光谱的振子强度都增大.

简介：利用2,3-二甲基吡嗪与硝酸铜及氯化铜合成了铜配位聚合物[Cu（Mepz）]2n＋（Mepz=2,3-二甲基吡嗪）,并通过单晶X射线衍射方法进行了表征.该晶体属于正交晶系,空间群为：Cmca,相关晶胞参数为：a=0.68617（11）nm,b=1.3652（2）nm,c=1.9533（3）nm,V=1.8297（5）nm3.该配位聚合物中的Cu原子与2个N原子、2个O原子和2个Cl原子配位,形成了一个稍微畸变的配位八面体,每相邻的2个配体之间通过Cu离子与吡嗪环上的2个N原子配位连接成无限延伸的一维链状结构,并通过分子间的氢键作用进一步将其连接成为二维的超分子网络结构.

简介：利用室温液相还原、晶种生长的方法,成功的制备了大小形貌均一、性能稳定且具有磁性的Fe3O4@Cu2O复合纳米粒子,并且对制备的Fe3O4@Cu2O纳米粒子进行了光催化性能的研究.在以紫外光为光源的照射下,合成的Fe3O4@Cu2O纳米粒子对有机染料甲基蓝溶液起到很好的降解作用.更重要的是,在外加磁场的作用下,Fe3O4@Cu2O纳米粒子容易回收,具有良好的可循环利用性能.

简介：基于密度泛函理论（DFT）平面波超软赝势方法，对MgF：晶体近邻F位进行双空穴调制掺杂，选择PBE泛函进行计算，对比N单掺杂MgF：晶体和N近邻双掺杂MgF。晶体的晶体结构、电子结构以及吸收光谱．通过对电子结构的比较，研究了N近邻双掺杂对MgFz光催化活性的影响，给出了离子之间的协同作用机理．通过对比可以看出，N近邻双掺杂对MgF：晶体光学性能具有较佳的调制效果，其效果优于（N，Fe）双掺杂调制．

简介：在他们的photocatalytic/photoelectro-catalytic表演之上的TiO2nanotube数组(TNA)的结构的参数的效果被把词法特征和物理化学的性质与不同试管长度从三种电解质准备了作比较学习。结果证明与试管长度的增长转移红的TNA和短TNA的紫外力的吸收边拥有更高的bandgap精力。TNA的电气化学的窗户的变化趋势是DMSO(5.5V)>市民(3.2V)>HF(1.8V)。长TNA拥有更高的photocatalytic(PC)反应建议表面粗糙因素是PC效率的主要决定因素，尽管，为长TNA有明显的再结合效果。从一样的电解质为TNA由在试管长度和photoelectrocatalytic(PEC)效率之间的积极关联证实了，试管长度的改进能导致更好的PEC反应，但是当试管长度在某个价值上时，PEC降级率不再增加，但是减少。有从市民和DMSO电解质准备的大表面粗糙因素的长TNA与从HF电解质准备的短TNA相比展出比较或平的更低的PEC性能，显示TNA的PEC表演被费用分离和光电子转移性质而非表面粗糙系数和试管长度统治。

简介：由包含微生物引起的整个房间的催化剂的RhodococcuserythropolisAJ270，nitrilehydratase和amidase催化，在10点

简介：Thecrystalstructureof[Ni（TAAB）（py）2]（BF4）2,whereTAABisthetetradentatemacrocyclicligandtetrabenzo[b,f,j,n][1,5,9,13]tetraazacyclohexadecine,hasbeendeterminedfromX-raydiffractionanalysis.Thecrys.taibeiongstomonoclinic,spacegroupP21/nwithcellparameters

简介：Anewcytotoxicpyrrolidinoindolinediketopiperazinedimer,cristatuminE(1),wasisolatedfromthefermentationbrothofthealgalfungusEurotiumherbariorumHT-2associatedwiththemarinealgae,Enteromorphaprolifera.ThestructurewasdeterminedbyspectroscopicanalysesandMarfey’saminoacidanalysis.CristatuminE(1)showedcytotoxicityagainstK562tumorcelllineandantibacterialactivityagainstEnterobacteraerogenesandEscherichiacoliwithIC50andMICvaluesof8.3,44.0and44.0mmol/L,respectively.

简介：Underdifferentreactionconditions,theexpectedandunexpectedreactionproducts(ofwhichX-raycrystallographicstructurewaspresented)ofetherificationof2-per(poly)fluoroethyl4-substitutedphenolwithβ-haloethanolcanbeobtainedrespectively.

简介：

简介：Inthiswork,viaafacilesolvothermalroute,wesynthesizedananodematerialforlithiumionbatteries(LIBs)—SnS_2nanoparticle/graphene(SnS_2NP/GNs)nanocomposite.ThenanocompositeconsistsofSnS_2nanoparticleswithanaveragediameterof4nmandgraphenenanosheetswithoutrestacking.TheSnS_2nanoparticlesarefirmlyanchoredonthegraphenenanosheets.AsananodematerialforLIBs,thenanocompositeexhibitsgoodListorageperformanceespeciallyhighrateperformance.Atthehighcurrentrateof5,10,and20A/g,thenanocompositedeliveredhighcapacitiesof525,443,and378mAh/g,respectively.ThegoodconductivityofthegraphenenanosheetsandthesmallparticlesizeofSnS_2contributetotheelectrochemicalperformanceofSnS_2NP/GNs.

简介：4,4-Dialkyl-2-oxazolin-5-onesarepreparedbyonestepreactionof2-oxazolin-5-onewiththemagnesiummethylcarbonate(MMC)andalkyIhalides.Itisanovelandconvenientmethodforsynthesisofα,Υ-disubstitutcdα-aminoacidbyhydrolysisof4,4-dialkyl-2-oxazolin-5-ones.

简介：NewrareearthvanadatesYSrQ-xCaxV3O9-y（x=0.0,0.67,1.0,1.33and2.0）havebeensynthesizedbyanewsimplemethod.X-raypowderdiffractionresultsshowthattheyaremono-phase.Theybelongtoorthorhombicstructureandtheirlatticeconstantsarecalculated.TheresultsofweightgainsinTGcurvesshowthatthelowervalentvanadiumisoxidizedtohighervalentstateathighertemperature.Theoxygencontentsofnewcompoundsarecalculatedfromtheweightgains.BothV3+andV4+coexistinYSr2-xCaxV3O9-y.Thesecompoundsexhibitlowelectricresistivityatroomtemperature.